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Citation: Niu Xiao-Yu, WU Yi-Qun, CHEN Nai-Sheng, HUANG Jin-Ling. Spectra and Photostability of Axially Alkoxy Substituted Naphthalocyanine Silicon Coordination Compounds[J]. Chinese Journal of Applied Chemistry, ;2006, 23(2): 153-156. shu

Spectra and Photostability of Axially Alkoxy Substituted Naphthalocyanine Silicon Coordination Compounds

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a Institute of Functional Materials, Fuzhou University, Fuzhou 350002;
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b College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin;
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c Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai

Corresponding author: CHEN Nai-Sheng,
Received Date: 16 April 2005
Available Online: 16 June 2005
Fund Project: 国家自然科学基金(20141001) (20141001)黑龙江省自然科学基金(B01-07)资助项目 (B01-07)

The UV spectra,photo-degradation kinetics,and photostability of four axially alkoxy substituted naphthalocyanine silicon compounds(Sinc(OR)₂,R=CH₃),C₂H₅,C₃H₇ and C₄H₉) were investigated in DMSO,DMF and CH₂Cl₂,respectively.The results indicate that the maximal absorption bands of the compounds increase with increased carbon number of the axially alkoxy substituted groups in the same solvent.Moreover,the photostability also gradually increase with increased carbon number of the axially alkoxy substituted groups in DMSO and CH₂Cl₂.The photostability order for the same Sinc(OR)₂ compound in different solvent is:DMSO >CH₂Cl₂ >DMF.
- naphthalocyanine silicon,
- axially alkoxy substitution,
- spectra and photostability,
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