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Citation: HAN Ping-Fang, WANG Jing, XIAO Wen-Jing, LUE Xiao-Ping. Synthesis of Dichlorophenylphosphine Under Ultrasound Irradiation[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 332-336. shu

Synthesis of Dichlorophenylphosphine Under Ultrasound Irradiation

1.
Institute of Sonochemical Engineering, Nanjing University of Technology, Nanjing 210009

Corresponding author: HAN Ping-Fang,
Received Date: 20 May 2005
Available Online: 29 September 2005

Dichlorophenylphosphine(DCPP) was synthesized from benzene and phosphorus trichloride with aluminum chloride anhydrous as catalyst.The reactor was irradiated in the 40 kHz ultrasound field at an acoustic pressure of 159 kPa.After the reaction,0.076~0.09 mm NaCl powder was added to the reactor as a complexant to remove the catalyst.Petroleum ether was used to extract DCPP from the solid above- mentioned.Petroleum ether was distilled by an atmospheric distillation process,then DCPP was distilled at a reduced pressure of 1.33×10³ Pa(absolute pressure),the boiling point of which is 90℃.The yield(92.3%) was increased by 6.6% with ultrasound over that(85%) without ultrasound for the same reaction time and the purity was 99.7%.
- dichlorophenylphosphine(DCPP),
- synthesis,
- ultrasound,
- complexant
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