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Citation: ZHAO Jun-Wei, WANG Jing-Ping, NIU Jing-Yang. Synthesis and Crystal Structure of a B-Anderson-type Polyoxometalate [Co(2,2-'bipy)₃]H-[Al(OH)₆(Mo₆O₁₈)]·5H₂O[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 289-293. shu

Synthesis and Crystal Structure of a B-Anderson-type Polyoxometalate [Co(2,2-'bipy)₃]H-[Al(OH)₆(Mo₆O₁₈)]·5H₂O

1.
Institute of Molecule and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001

Corresponding author: WANG Jing-Ping,
Received Date: 8 May 2005
Available Online: 3 July 2005
Fund Project:

A B-Anderson-type polyoxometalate[Co(2,2-'bipy)₃]H-[Al(OH)₆(Mo₆O₁₈)]·5H₂O has been synthesized from AlCl₃·H₂O,Na₂MoO₄·2H₂O,CoCl₂·6H₂O and 2,2'-bipydine and characterized by means of IR,UV spectra,thermogravimetric analysis and Xray diffraction.The X-ray crystallography indicates that the title compound crystallizes in a triclinic lattice,P1 space group,with a=1.216 0(2),b=1.221 5(2),c=1.780 0(4) nm,α=86.83(3)°,β=88.76(3)°, γ=89.82(3)°,V=2.639 4(9) nm³,Z=2,R₁=0.079 4,wR₂=0.176 6.Structural analysis reveals that the molecule of the title compound is composed of one[Co(2,2'-bipy)₃]²⁺coordination cation,one H⁺ ion,two crystallographically independent "one-half" polyoxoanions[Al(OH)₆(Mo₆O₁₈)]^3- and five hydration water molecules.Under the participation of water and coordinated metal ions,the[Al(OH)₆(Mo₆O₁₈)]^3- polyoxoanions form a two-dimensional network structure by means of supramolecular interaction.The adjacent network structures interact with each other,generating a three-dimensional structure infinitely extended via supramolecular interaction.Thermogravimetric analysis elucidates that the process of weight loss of the title compound is divided into two stages and also reveals that the backbone of heteropolyoxoanion decomposes at 547.5℃.
- Anderson structure,
- bipyridine,
- polyoxometalate,
- supramolecular structure
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Synthesis and Crystal Structure of a B-Anderson-type Polyoxometalate [Co(2,2-'bipy)3]H-[Al(OH)6(Mo6O18)]·5H2O

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of a B-Anderson-type Polyoxometalate [Co(2,2-'bipy)₃]H-[Al(OH)₆(Mo₆O₁₈)]·5H₂O