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Citation: ZHANG Li, YANG Zheng, JIANG Zhi-Wei, SHI Jun, CAO Shao-Kui. Synthesis of Cyclotriphosphazene-based Molecular Glass Containing Carbazole Chromophores[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 238-241. shu

Synthesis of Cyclotriphosphazene-based Molecular Glass Containing Carbazole Chromophores

1.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450052

Corresponding author: CAO Shao-Kui,
Received Date: 22 April 2005
Available Online: 20 July 2005
Fund Project: 国家自然科学基金资助项目(20274042) (20274042)

Two cyclotriphosphazenes containing carbazole chromophores were prepared via a post-azo-coupling reaction.These two molecules were characterized by using ¹H NMR,³¹P NMR,IR,UV-Vis and DSC.The single resonance in the ³¹P NMR spectra of compounds 3~5 show that the chloro-groups on the cyclotriphos-phazene was completely substituted by the carbazolyl group.Results of ¹H NMR,IR and UV-Vis demonstrate that the azo group was linked to the 3-position of the carbazole ring with different contents.DSC measurement results indicate that these molecules are amorphous in nature and the glass transition temperature increases with increasing the content of chromophores.
- cyclotriphosphazene,
- post-azo-coupling,
- carbazole,
- photorefractive molecular glass
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