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Citation: WEN Hui-Liang, ZHOU Xiao-Ying, HU Xiao-Bo, ZHANG Jin-Bing. Solid Phase Synthesis of 2-Nitro-4-chloro-2'-hydroxy-3'-t-butyl-5'-methyl-azobenzene[J]. Chinese Journal of Applied Chemistry, ;2006, 23(5): 579-580. shu

Solid Phase Synthesis of 2-Nitro-4-chloro-2'-hydroxy-3'-t-butyl-5'-methyl-azobenzene

1.
a MOE Key Laboratory of Food Science, Nanchang University, Nanchang 330047;
2.
b Department of Chemistry, Nanchang University, Nanchang

Corresponding author: WEN Hui-Liang,
Received Date: 25 June 2005
Available Online: 27 September 2005

2-Nitro-4-chloro-2'-hydroxy-3'-t-butyl-5'-methyl-azobenzene was synthesized via diazo coupling reaction in solid phase with 4-chlor-2-nitroaniline,2-t-butyl-4-methyl phenol and sodium nitrite at room temperature.The reaction was completed through one-step method within 15 min in a yield of 93% with a higher than 99% purity(by HPLC),and the structure of the compound was comfirmed by IR and UV.
- nitro-chloro-hydroxy-t-butyl-methyl-azobenzene,
- solid phase synthesis,
- diazo coupling reaction
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