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Citation: ZHANG Xue-Jian, ZHANG Kai-Lin, FENG Ying, ZHAO Ji-Ruo, WANG Yu-Ling. Synthesis of PVC-g-PMMA by Atom Transfer Radical Suspension Polymerization[J]. Chinese Journal of Applied Chemistry, ;2006, 23(5): 543-547. shu

Synthesis of PVC-g-PMMA by Atom Transfer Radical Suspension Polymerization

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a MOE Key laboratory of Rubber-Plastic, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042;
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b State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun

Corresponding author: FENG Ying,
Received Date: 22 June 2005
Available Online: 29 September 2005

The atom transfer radical suspension polymerization(ATRP) of methyl methacrylate(MMA) initiated by poly(vinyl chloride)(PVC) and catalyzed by iron dichloride tetrahydrate/triphenyl phosphine complexes was studied in different suspension systems at 80℃.The systems included ethanol,toluene/ethanol,toluene/H₂O,H₂O,H₂O/Poly(vinyl alcohol)(PVA),and H₂O/PVA/Dioctyl phthalate(DOP).A linear dependence of ln [M₀]/[M] on reaction time was observed for only two suspension systems,toluene/ethanol and H₂O/PVA/DOP,and a linear increase with reaction time of the number average molecular weight of copolymer PVC-g-PMMA was observed.The structures of the copolymers were characterized by IR, ¹H NMR,GPC.The grafting efficiency of MMA were 6.7%,17.8%,26.0%,35.1%,respectively after polymerization of 6,15,21,27 h.
- poly(vinyl chloride),
- methyl methacrylate,
- atom transfer radical suspension polymerization
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