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Citation: YANG Fa-Fu, ZHENG Lin-Lu, JI Yan-Qing, LIN Jian-Rong, PENG Qi. Syntheses and Cations' Extraction Properties of Poly(aza) Calix[4] arenes and Bis-calix[4] arene[J]. Chinese Journal of Applied Chemistry, ;2006, 23(6): 691-693. shu

Syntheses and Cations' Extraction Properties of Poly(aza) Calix[4] arenes and Bis-calix[4] arene

1.
a College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007;
2.
b Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou

Corresponding author: YANG Fa-Fu,
Received Date: 6 August 2005
Available Online: 22 November 2005
Fund Project: 国家自然科学基金(20402002) (20402002)福建省自然科学重点基金(E0220002)资助项目 (E0220002)

New calix[4]arene poly(aza) derivatives 3,4 and bis-calix[4]arene 5 containing azo-groups,amido groups and Schiff-base groups were synthesized in yields of 87%,89%,84%,respectively.Their structures were confirmed by ¹H NMR,ESI-MS and elemental analysis.Liquid-liquid extraction experiments showed they possessed excellent extraction capabilities for cations and their extraction percentages were higher than those of similar calix[4]arene derivatives containing amido and Schiff-base groups.
- calix[4]arene,
- bis-calix[4]arene,
- poly(aza),
- extraction
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