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Citation: FENG Zong-Cai, LI Lin, GUO Si-Yuan, HU Song-Qing. Solid-phase Synthesis of Oligosaccharides[J]. Chinese Journal of Applied Chemistry, ;2006, 23(6): 659-662. shu

Solid-phase Synthesis of Oligosaccharides

FENG Zong-Cai ^a,b,, ,
LI Lin ^b ,
GUO Si-Yuan ^b ,
HU Song-Qing ^b

1.
a Department of Chemistry, Zhanjiang Normal College, Zhanjiang 524048;
2.
b Research Institute of Light Chemical Engineering, South China University of Technology, Guangzhou 510640

Corresponding author: FENG Zong-Cai,
Received Date: 10 July 2005
Available Online: 16 December 2005
Fund Project: 中国博士后基金资助项目(中博基[2002]11号2002031284) (中博基[2002]11号2002031284)

In the solid-phase synthesis of oligosaccharides,1,2-isopropyl-5,6-dehydrate-α,d-furan glucose was linked to the carriers styrene-diphenyl ethylene with sizes of 100~200 nm by dimethyldichlorosilane coupling agent.The saccharide chains were prolonged by the linkage of 1,2-isopropyl-5,6-dehydrate-α,d-furan glucose.In principle,the epoxy of the glucose unit on the carrier could react with the hydroxyl of another 1,2-isopropyl-5,6-dehydrate-α,d-furan glucose to make the target oligosaccharide.The resulant oligosaccharides were deattached from the carrier by tetrabutylammonium fluoride(TBAF) buffered with acetic acid and their structure was confirmed based on the results of UV,FT-IR,NMR and MS.
- solid-phase carrier synthesis,
- oligosaccharide,
- coupling agent,
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