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Citation: LI Wei, LI Chang-Hong, YANG Ying-Qun, LI Chu-Xin, XU Wei-Jian. Structure and Electrochemical Properties of a one Dimensional Chain Cobalt Coordination Polymer Co(α-Furoic acid)₂(4,4'-bipy)₂(H₂O)₂[J]. Chinese Journal of Applied Chemistry, ;2006, 23(7): 794-797. shu

Structure and Electrochemical Properties of a one Dimensional Chain Cobalt Coordination Polymer Co(α-Furoic acid)₂(4,4'-bipy)₂(H₂O)₂

LI Wei ^a,c,, ,
LI Chang-Hong ^b ,
YANG Ying-Qun ^a,c ,
LI Chu-Xin ^d ,
XU Wei-Jian ^c

1.
a Department of Chemistry and materials Science, Hengyang Normal University, Hengyang 421008;
2.
b Department of Chemical Engineering, Hunan University Hengyang Branch, Hengyang;
3.
c College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
4.
d Research and Technology Department Baling PetrocheMical Co.ltd Yunxi District of YueyangCity Hunan Province, Yueyang

Corresponding author: LI Wei,
Received Date: 15 September 2005
Available Online: 30 November 2005
Fund Project: 教育部高校骨干教师基金资助项目(2000K52141) (2000K52141)湖南省教育厅一般项目(05c001) (05c001)衡阳师范学院青年项目(2003C16) (2003C16)

One dimensional chain cobalt coordination polymer with α-Furoic acid,4,4'-bipyridine and cobalt carbonate was synthesized and characterized in the solvent mixture of water and methanol.It crystallized in a triclinic space group P1 with a=1.138 4(4) nm,b=1.138 4(4) nm,c=1.302 9(9) nm,γ=120.0°,V=1.462 3(12) nm³),D_c=1.612 g/cm³,Z=3,F(000)=729.R₁=0.049 0,wR₂=0.143 6. The crystal structure shows that the cobalt(Ⅲ) atom was coordinated with two nitrogen atoms from the two 4,4-bipys,two oxygen atoms from two α-Furoic acid molecules and two oxygen atoms from two water molecules,forming a distorted octahedral geometry.The cyclic voltametric behavior of the complex was also studied.The results showed that it was a stable complex,and there was a quasi-reversible redox process for the complex and the complex was stabilized.
- cobalt(Ⅲ) complex,
- crystal structure,
- electrochemical property
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Structure and Electrochemical Properties of a one Dimensional Chain Cobalt Coordination Polymer Co(α-Furoic acid)2(4,4'-bipy)2(H2O)2

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Structure and Electrochemical Properties of a one Dimensional Chain Cobalt Coordination Polymer Co(α-Furoic acid)₂(4,4'-bipy)₂(H₂O)₂