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Citation: LIN Mei-Juan, WANG Wen, ZHANG Wen-Gong, WEN Gui-An. Synthesis of Photoluminescent Organic Glass Containing Re(OPrⁱ)(TTA)₂ by Coordination Linkage[J]. Chinese Journal of Applied Chemistry, ;2006, 23(8): 845-849. shu

Synthesis of Photoluminescent Organic Glass Containing Re(OPrⁱ)(TTA)₂ by Coordination Linkage

1.
College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007

Corresponding author: LIN Mei-Juan,
Received Date: 17 August 2005
Available Online: 25 December 2005
Fund Project: 福建省科技厅(2005K014) (2005K014)福建省自然科学基金(E0510017)资助项目 (E0510017)

Complexes Eu(OPrⁱ)(TTA)₂,Tb(OPrⁱ)(TTA)₂ and Sm (OPrⁱ)(TTA)₂ were synthesized by replacing partial isopropoxyl group with thenoyltrifluoroacetone(TTA) under the protection of N₂.The photoluminescent organic glass materials containing these complexes were prepared via the bulk polymerization of methyl methacrylate(MMA)/complex blends.The polymers containing these complexes were characterized by means of elemental analysis,FT-IR,XRD and FS.There existed interaction between the rare earth ions and the carboxyl group of MMA monomer.The organic glass materials containing Eu(OPrⁱ)-(TTA)₂,Tb(OPrⁱ)(TTA)₂ or Sm (OPrⁱ)(TTA)₂ exhibited strong characteristic luminescence of Eu³⁺(613 nm),Tb³⁺(544 nm) or Sm³⁺(644 nm) under excitation at the most suitable wavelength for each compound, respectively.Their luminescent intensities were as high as that of PMMA containing Re(TTA)₃.In addition,the organic glass materials were amorphous and exhibited high solubility and transparence.
- Re(OPrⁱ)(TTA)₂ complex,
- organic glass,
- luminescence
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Synthesis of Photoluminescent Organic Glass Containing Re(OPrⁱ)(TTA)₂ by Coordination Linkage