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Citation: LIU Chun-Ping, GUAN Ruo-Fei, WANG Ni. Synthesis of Magnetic Functional Phenolic Resins and Their Adsorption Properties for Metal Ions[J]. Chinese Journal of Applied Chemistry, ;2006, 23(9): 1037-1041. shu

Synthesis of Magnetic Functional Phenolic Resins and Their Adsorption Properties for Metal Ions

1.
School of Chemistry and Material Science, Ludong University, Yantai 264025

Corresponding author: LIU Chun-Ping,
Received Date: 26 October 2005
Available Online: 12 March 2006

Magnetic amino phenolic resin(F₅₃-NH) was synthesized by the reaction between epoxy phenolic resin and tetraethylene pentamine,and dithiocarboxylic sodium formate phenolic resin(F₅₃-CSSNa).Toluene diisocyanate phenolic resin(F₅₃-TDI) and thiosemicarbazide phenolic resin(F₅₃-CSNH₂) were synthesized respectively through the reactions between F₅₃-NH and each of CS₂,TDI,NH₂NHCSNH₂.The adsorption and swelling properties of the resins for metal ions Cu²⁺,Pb²⁺,Co²⁺,Ni²⁺,Ag⁺,Zn²⁺,Cd²⁺ were studied.The results show that the swelling properties of the synthetic resins in polar solvents are better than those in nonpolar solvents.F₅₃-NH resin has preferable adsorption properties for all of the determined metal ions, however,the other three kinds of resins have obviously selectivity for determined metal ions,and adsorption capacities of the synthesized resins for Zn²⁺ are 2.821,3.481,3.400 and 3.622 mmol/g respectively,especially higher than those for other metal ions.
- epoxy phenolic resin,
- chelating,
- metal ion,
- swelling,
- adsorption capacity,
- adsorption kinetics
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