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Citation: ZHAO LI-Fang, WANG Hong-She, MIAO Jian-Ying. Preparation of New Organotin Compounds and Their Application to Esterification Reaction[J]. Chinese Journal of Applied Chemistry, ;2006, 23(11): 1273-1277. shu

Preparation of New Organotin Compounds and Their Application to Esterification Reaction

1.
Department of Chemistry & Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007

Corresponding author: ZHAO LI-Fang,
Received Date: 31 October 2005
Available Online: 1 February 2006
Fund Project: 陕西省教育厅专项科研计划(02JK054)资助项目 (02JK054)

Two new organotin compounds have been synthesized and characterized by means of IR,¹H NMR and elemental analysis.They were used as efficient Lewis acid catalysts for esterification reactions of carbo-xylic acids with alcohols to afford corresponding saturated esters with 87%~98% yields and unsaturated and tertiary ones with 90%~94% and 54%~68% yields,respectively.The catalysts could be easily filtrated from the reaction mixture and reused.
- esterification reaction,
- organotin compound,
- catalysis
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