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Citation: ZHANG Yi, GAO Xiang. Progress in Research on Water-soluble Supramolecular Complexes of Cyclodextrin and Fullerene[60][J]. Chinese Journal of Applied Chemistry, ;2007, 24(1): 1-7. shu

Progress in Research on Water-soluble Supramolecular Complexes of Cyclodextrin and Fullerene[60]

ZHANG Yi ,
GAO Xiang ^,

1.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Changchun 130022

Corresponding author: GAO Xiang,
Received Date: 26 October 2006
Available Online: 28 November 2006
Fund Project: 国家自然科学基金国际合作项目(00550110367,00650110171) (00550110367,00650110171)

The study on the supramolecular inclusion complex of cyclodextrin and C₆₀ has drawn a lot of attention, not only because the formation of the complex increases the solubility of C₆₀ in aqueous solution for possible applications in biology and medicinal chemistry, but also because the complex has displayed some interesting catalytic reduction properties such as dinitrogen fixation and reducing ability toward C=O, C=C and N-N⁺ bonds under mild conditions.Several methods have been developed for the preparation of CD/C₆₀ complex, including refluxing, stirring and solid state ball/high-speed vibration milling.However, the methods are limited to the preparation of C₆₀ inclusion complex withγ-cyclodextrin, while they are not successful in preparing C₆₀ inclusion complex with cyclodextrins having smaller cavity dimension such as α- and β-cyclodextrin.Recently, we have developed a novel method to prepare the supramolecular complexes of CDs/C₆₀ using monoanionic C₆₀, which has been show to be effective in preparing inclusion complexes of α-,β- andγ-cyclodextrin with C₆₀.Herein, the recent development on the preparation of cyclodextrin/fullerene supramolecular complexes is reviewed.
- fullerenes,
- C₆₀,
- cyclodextrin,
- supramolecular chemistry,
- synthesis
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