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Citation: HUANG Feng, ZHAN Hu, ZHOU Yun-Hong, YI De-Lian. Electrochemical Study of Nano-SnO₂ Anode[J]. Chinese Journal of Applied Chemistry, ;2007, 24(3): 268-272. shu

Electrochemical Study of Nano-SnO₂ Anode

1.
a College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan, 430081;
2.
b College of Chemical & Molecular Science, Wuhan University, Wuhan

Corresponding author: HUANG Feng,
Received Date: 23 March 2006
Available Online: 5 July 2006
Fund Project: 国家自然科学基金(29833090)资助项目 (29833090)湖北省教育厅重点项目(Z200511004) (Z200511004)

Slow scanning cyclic voltammetry was employed to study stainless steel electrode in different electrolytes, solvents and lithium-salt. The impedance diagrams of nano-SnO₂ anode/electrolyte interphase at different discharge states were analyzed with alternative current impedance spectroscopy. The results suggest that nonaqueous electrolyte reacts also on the surface of a nano-SnO₂ anode as in lithium rechargeable batteries during the initial charge/discharge cycles, and results in the partial irreversible capacity loss. The electrochemical reaction of nano-SnO₂ anode for lithium rechargeable batteries can be deduced as follows:a passivating film forms on the surface of nano-SnO₂ particles first, then Li⁺ ions pass through the surface film and react with nano-SnO₂ to produce amorphous Li₂O and to form fine grains of Li-Sn alloys in the core region underneath the passivation film.
- lithium rechargeable battery,
- nano-SnO₂ anode,
- slow scanning cyclic voltammetry,
- alternative current impedance spectroscopy
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Electrochemical Study of Nano-SnO₂ Anode