Home

Citation: YU Lan-Lan, ZHENG Kai, SU Li-Hong, YU Hong-Wei. Preparation of Adsorbent of Flue Gas Desulfurization Made from Surplus Sludge of Sewage[J]. Chinese Journal of Applied Chemistry, ;2007, 24(9): 1045-1049. shu

Preparation of Adsorbent of Flue Gas Desulfurization Made from Surplus Sludge of Sewage

1.
a School of Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing 163318;
2.
b The No.2 Petroleum Production of Daqing Oil Field, Daqing;
3.
c College of Physical, Northwestern polytechnical University, Xi'an

Corresponding author: YU Lan-Lan,
Received Date: 12 October 2006
Available Online: 7 March 2007
Fund Project: 江苏省建设系统科技计划项目(JS200310) (JS200310)

Adsorbent for flue gas desulfurization was prepared from surplus sludge of sewage by modifation method of loading metal oxides, and its properties were studied by means of pore characteristics, SEM and elemental analysis. The adsorption mechanism of system of the adsorbent for SO₂-O₂-H₂O(g)-N₂ was studied by FTIR and thermal analysis. The results show that the performance of the adsorbent with loaded(mass fraction) both 5% MnO₂ and 5% MgO is the best. The pore structure mainly consists of intermediate and large pores, the corresponding specific surface area is lower. Under the adsorption conditions of inlet concentration of SO₂ 2 021.38 mg/m³, mass fractions of O₂ 12% and H₂O(g) 12%, flue gas velocity 2.13 m/min, temperature 60℃, the desulfurization efficiency and adsorption capacity of sludge-derived adsorbent are 93.7% and 99.3 mg/g respectively, and those decrease to 93% and 84.4 mg/g after renovation by washing twice with ammonia, indicating that the renovation effect is better. In the presence of water vapour, the synergistic action of the complex oxides accelerates the chemical adsorption of sludge-derived adsorbent for SO₂. The isothermal adsorption process can be described by Freundlich Model, and the adsorption heat value is 78.4 kJ/mol. Predictable values via stationary adsorption bed model are in agreement with experimental values.
- sludge,
- adsorbent,
- desulfurization,
- mechanism,
- model
1. [1]
  Kun JIANG , Yutong XUE , Kelin LIU , Miao WANG , Tongming SUN , Yanfeng TANG . CeVO₄ hollow microspheres: Fabrication and adsorption performance for dyes. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2229-2236. doi: 10.11862/CJIC.20250223
2. [2]
  Weifeng Yu , Junqiao Zhuo . Stereoisomeric Analysis of Adamantane and Hexamethylenetetramine. University Chemistry, 2026, 41(6): 434-440. doi: 10.12461/PKU.DXHX202503125
3. [3]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
4. [4]
  Jiahong WANG , Zekun XU , Tianjiao LU , Jinming HUANG . Performance of N, Mn doped semi-coke activated carbon catalyzed ozone oxidation for the degradation of tetracycline hydrochloride in water. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2549-2560. doi: 10.11862/CJIC.20250120
5. [5]
  Qin′ai FENG , Jianjun LI , Lili ZHANG , Linxin WU , Huiling WANG , Wenjing HOU , Lei WANG , Mingjie REN . Amphiphilic surface modification of magnetic adsorbents and its adsorption properties of two microplastics. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 789-807. doi: 10.11862/CJIC.20250208
6. [6]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
7. [7]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
8. [8]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
9. [9]
  Ying Ma , Heng Zhang . Molecular simulation study on the color-changing mechanism of phenolphthalein indicator. University Chemistry, 2026, 41(6): 335-342. doi: 10.12461/PKU.DXHX202504074
10. [10]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
11. [11]
  Siyu ZU , Jianhui LUO , Qingfa SU , Jianchun WANG , Yizhen CHENG , Zhihang GUO , Jinhong BI . Preparation and degrading formaldehyde properties of TiO₂/flue gas desulfurization ash photocatalytic composites. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1437-1452. doi: 10.11862/CJIC.20260043
12. [12]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
13. [13]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154
14. [14]
  Baoshun Zhu , Xinyan Wang , Weipeng Mu , Xuanpeng Sun , Yubo Wang , Hongyu Wei , Pangyu Shi , Huilan Hao , Dashuang Wang , Guomin Li , Guizhen Wang . 回收造纸污泥制备低成本Ni改性碳/硅复合材料用于高效微波吸收. Acta Physico-Chimica Sinica, 2026, 42(11): 100417-. doi: 10.1016/j.actphy.2026.100417
15. [15]
  Shichen Xu , Tongliang Lü , Wei Wei , Yanqing Xu , Hui Li . 原子模型的松紧规律及其应用. University Chemistry, 2026, 41(9): 412-420. doi: 10.12461/PKU.DXHX202509036
16. [16]
  Weilai Yu , Chuanbiao Bie . Unveiling S-Scheme Charge Transfer Mechanism. Acta Physico-Chimica Sinica, 2024, 40(4): 2307022-0. doi: 10.3866/PKU.WHXB202307022
17. [17]
  Hongyu Cheng , Ruiyao Wang , Xingwen Sun . Mechanistic Study of the Classic Hofmann Elimination Reaction. University Chemistry, 2025, 40(12): 187-191. doi: 10.12461/PKU.DXHX202510104
18. [18]
  Chi Zhang , Yi Xu , Xiaopeng Guo , Zian Jie , Ling Li . 五彩斑斓的秘密——物质显色机理. University Chemistry, 2025, 40(6): 266-275. doi: 10.12461/PKU.DXHX202407061
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(991)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return