Citation:
WANG Jian, TAN Ke-Jun, HUANG Cheng-Zhi. Determination of Trace Amount of Barium in Ternary System of Ba2+-PEG-TPB by Light Scatterin[J]. Chinese Journal of Applied Chemistry,
;2007, 24(11): 1337-1339.
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In a HAc-NaAc buffer solution of pH=5.2, the light scattering signals of barium and sodium tetraphenylboron at 287 nm could be enhanced obviously in the presence of polyethylene glycol 600, and on the basis of this, a sensitive and simple method is presented here to provide a way to detect trace amount of barium. The enhanced light scattering signals were proportional to the concentration of Ba2+ in the range of 3.00×10-8~3.43×10-6 g/mL, and the limit of detection was 2.80×10-9 g/mL. Additionally, the recovery of trace amount of barium in the synthetic samples was between 97.8% and 103.6%.
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