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Citation: ZHANG Zhi-Hua, LIU Hui-Min, SHI Xiao-Xia, HAN Shi-Tian. Synthesis and Application of New Porphyrin Pyridine Quaternary Ammonium Salts[J]. Chinese Journal of Applied Chemistry, ;2008, 25(3): 330-333. shu

Synthesis and Application of New Porphyrin Pyridine Quaternary Ammonium Salts

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a College of chemistry, Hebei normal university, Shijiazhuang 050016;
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b Xingtai Medical college, Xingtai;
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c College of science, Agricultural University of Hebei, Baoding

Corresponding author: HAN Shi-Tian,
Received Date: 11 May 2007
Available Online: 10 September 2007
Fund Project: 河北省科学技术研究与发展指导计划资助项目(07215684) (07215684)河北省自然科学基金资助项目(203147) (203147)

Three new porphyrin quaternary ammonium salts which had never been reported preriously were synthesized:5-[4-(P-nitro) benzyl ammonium pyridinium]-10,15,20-tris(4-N-pyridinium) porphyrin bromide;5-[4-(P-methoxy) benzyl ammonium pyridinium]-10,15,20-tris(4-N-pyridinium) porphyrin chloro;5-[4-(P-chloro)benzyl ammonium pyridinium]-10,15,20-tris(4-N-pyridinium) porphyrin chloro.Their structures were demonstrated by IR,UV,MS,¹H NMR and elementary analysis.During the determination of trace copper in water with the method of spectrophotometry experiments,the apparent molar absorption coefficients of the complexes are more than 1×10⁵ L/(mol·cm).With the double function of colour reagent and surfactant active agent,the new type porphyrins are good colour sensitive reagent.This method has been used in the determination of trace copper(Ⅱ) of enviormenal water sample,and satisfied feedback was obtained.
- porphyrin,
- pyridine quaternary ammonium salt,
- microwave,
- synthesis
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