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Citation: XIE Guang-Liang, LIAO Gui-Hong, WU Fang-Juan, SONG Cai-Sheng. Synthesis and Adsorption Properties of Poly(Aryl Ether Sulfone Ether Ketone Ketone) with Side Carboxyl[J]. Chinese Journal of Applied Chemistry, ;2008, 25(3): 295-299. shu

Synthesis and Adsorption Properties of Poly(Aryl Ether Sulfone Ether Ketone Ketone) with Side Carboxyl

1.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330027

Corresponding author: SONG Cai-Sheng,
Received Date: 8 April 2007
Available Online: 17 September 2007
Fund Project: 国家科技部科技型中小企业技术创新基金资助项目(06C26213601342) (06C26213601342)

Poly(aryl ether sulfone ether ketone ketone) with side carboxyl(PESEKK-A) attached to the main chain was synthesized by Friedel-Crafts polycondensation of 4,4'-diphenyoxyl diphenyl sulfone(DPODPS) with trimellitic anhydride chloride(TMAC).The structure was determined by ¹H NMR and FT-IR.PESEKK-A could only be dissovled in several solvents,such as,concentrated sulfuric acid(98%),dichloroacetic acid,and trifluoroacetic acid,showing high solvent-resistant and corrosion-resistant properties.Adsorptions of Cu²⁺,Ag⁺,Cd²⁺ onto PESEKK-Na were studied.Sodium salt of the resin(PESEKK-Na) exhibited better adsorption ability than PESEKK-A.The optimum pH for the adsorption of Cu²⁺,Ag⁺,Cd²⁺ onto PESEKK-Na were 4.7,4.5 and 5.7,respectively.The adsorption capacities for Cu²⁺,Ag⁺,Cd²⁺ were 1.03 mmol/g,0.815 3 mmol/g,and 0.558 6 mmol/g,respectively.The amount of Cu²⁺ adsorbed in 2 h was 80.4% that adsorbed in 48 h.90% of the adsorbed Cu²⁺ desorbed within 1 h in 1 mol/L HCl.From 12℃ to 45℃,the amount of adsorption increased with temperature,and reached 1.049 mmol/g at 45℃.The resin can be reused without loss of its adsorption ability.These results show that PESEKK-Na has potential in the fields of separating valuable metals and environmental protection.
- poly (aryl ether sulfone ether ketone ketone),
- side carboxyl,
- synthesis,
- characterization,
- ion exchange,
- adsorption
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