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Citation: HU Rui-Jue, LI Bao-Guo, BAI Shu-Zhen, ZHANG Hai-Bo. Synthesis of Dialkyldiferrocenylmethoxyethylamine[J]. Chinese Journal of Applied Chemistry, ;2008, 25(3): 286-289. shu

Synthesis of Dialkyldiferrocenylmethoxyethylamine

1.
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021

Corresponding author: LI Bao-Guo,
Received Date: 24 March 2007
Available Online: 1 June 2007
Fund Project: 国家自然科学基金资助项目(20362007) (20362007)

The reaction of six dialkyldiferrocenylmethanols(1a~1f) with BF₃ in CH₂Cl₂ gave stable dialkyldiferrocenylmethyl caboniums(2a~2f),which futher reacted with diethanolamine without separation from the reaction solution,and afforded six novel correspongding compounds of dialkyldiferrocenylmethoxyethylamines Fc(R₂Fc')CHOCH₂CH₂NH₂(3a~3f),in the yields of 81%~87%.The structures of the title compounds were characterized by elemental analysis,IR,and ¹H NMR.
- diferrocenylmethoxyethylamine,
- diferrocenylmethyl caboniums,
- diethanolamine,
- synthesis
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