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Citation: ZHENG Mina, LIU Wei, GAO Xianga. Progress in the Chemistry of Fullerene Anions[J]. Chinese Journal of Applied Chemistry, ;2008, 25(3): 257-265. shu

Progress in the Chemistry of Fullerene Anions

ZHENG Mina ^a,b ,
LIU Wei ^a ,
GAO Xianga ^a,,

1.
a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b Graduate School of Chinese Academy of Sciences, Beijing

Corresponding author: GAO Xianga,
Received Date: 18 November 2007
Available Online: 16 January 2008
Fund Project: 国家自然科学基金国际合作资助项目(00550110367,00650110171) (00550110367,00650110171)

Unlike neutral C₆₀,which is an electron-deficient molecule and reactive towards nucleophiles,C₆₀ anions are electron-rich species and reactive towards electrophiles.Owing to the different electronic structures between the C₆₀ anion and neutral C₆₀,it is likely that C₆₀ anions may undergo a different reaction mechanism compared with neutral C₆₀ during the reactions,which may lead to the formation of novel fullerene derivatives.Herein,the progress of the chemistry of C₆₀ anions is reviewed in order to get a better understanding of fullerene anions and fullerene chemistry.As the review indicates,it is necessary to further investigate the chemistry of fullerene anions since many aspects of it are not well understood at the current stage.
- fullerene,
- C₆₀,
- anions,
- fullerene derivative
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