Citation:
LI Chao-Qun, JIANG Zhi-Wei, WANG Yu-Rong, TANG Tao. Preparation and Properties of Thermoplastic Polyolefin/montmorillonite Nanocomposite[J]. Chinese Journal of Applied Chemistry,
;2008, 25(2): 132-136.
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Thermoplastic vulcanizate(TPV)/montmorillonite nanocomposite based on polypropylene(PP),ethylene-propylene rubber(EPDM),and organically modified montmorillonite(OMMT) was prepared via dynamic vulcanization.XRD and TEM measurements showed that the TPV/montmorillonite nanocomposite(TPVOMMT) was a nanocomposite with intercalated structure.The increase in the tensile strength of the TPVOMMT nanocomposite was 55% vs TPV,and 33% vs the dynamic vulcanizate that based on PP/EPDM/Na-MMT(TPVNMMT).Dynamic mechanical analysis showed that the storage modulus of the TPVOMMT nanocomposite increased by 35% compared with that of TPV,while Tg of TPVOMMT increased by 8℃.Complex viscosity decreased with the addtion of OMMT.Moreover,the tensile strength of the vulcanizate with different rubber/resin ratios was discussed.
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