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Citation: ZHANG Gang-Shen, QIU Bo, CHEN Zu-Xing, LI Yan. Synthesis of Queen Honeybee Pheromones[J]. Chinese Journal of Applied Chemistry, ;2008, 25(7): 871-873. shu

Synthesis of Queen Honeybee Pheromones

1.
MOE Key Laboratory of Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062

Corresponding author: LI Yan,
Received Date: 3 July 2007
Available Online: 27 October 2007
Fund Project: 湖北省自然科学基金资助项目(2005ABA057) (2005ABA057)

9-Hydroxyl-(E)-2-decenoic acid and 9-carbonyl-(E)-2-decenoic acid are the main components of queen honeybee pheromones.9-Carbonyl-(E)-2-decenoic acid was synthesized from 1-(phenylsulfonyl)-2-acetone and 5-bromo-ethyl valerate in five steps,which was enzymatic reduced with bakers' yeast to give S-9-hydroxyl-(E)-2-decenoic acid.The total yield was about 28%.The materials used were easy to obtain,and the reaction conditions were mild,and the yield satisfactory.
- queen honeybee pheromone,
- bakers' yeast,
- hydroxyl-(E)-decenoic acid,
- carbonyl-(E)-decenoic acid
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