Home

Citation: CHEN Lin, HU Zhi-Yong, ZHU Hai-Lin, XUE Zhuan-Ru. Synthesis and Surface Activity of Cleavable Aryl Sulfonate Anionic Surfactants[J]. Chinese Journal of Applied Chemistry, ;2008, 25(11): 1345-1350. shu

Synthesis and Surface Activity of Cleavable Aryl Sulfonate Anionic Surfactants

1.
School of Chemical Engineering and Environment, North China University, Taiyuan 030051

Corresponding author: HU Zhi-Yong,
Received Date: 12 October 2007
Available Online: 16 January 2008

A series of cleavable aryl sulfonate anionic surfactants with different carbon chains were synthesized from cyanuric chloride,aliphatic amine,and H acid mono sodium salt.Their structures were identified by ¹H NMR,IR,and elemental analysis.Their critical micell concentrations(CMC) in aqueous solutions at 25℃ were determined by steady-state fluorescence probe method and surface-tension method,respectively.With increased length of the carbon chain,the values of their CMC and surface tensions under CMC(γ_CMC) first decreased and reached minima(1.5×10^-5 mol/L and 28.29 mN/m respectively) when the carbon number was 10.Then the CMC and γ_CMC increased when the carbon number was 12.Compared with sodium dodecyl benzene sulfonate(SDBS),such kinds of surfactants have much lower surface adsorption amounts and greater molecular areas on the aqueous surface.Stability test results demonstrate that these surfactants are cleavable.
- cyanuric chloride,
- cleavable surfactant,
- surface tension,
- steady-state fluorescence probe method
1. [1]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
2. [2]
  Yiqi Zhang , Xinle Zhang , Yilin Liao , Tao Zeng , Junhao Ai , Ran Niu , Jiang Gong , Yuping Zhang . Fantastic voyage in a foam raft: droplet motor driven by surface tension and Marangoni flow. University Chemistry, 2026, 41(7): 126-133. doi: 10.12461/PKU.DXHX202506108
3. [3]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
4. [4]
  Meng Lin , Heng Zhang , Shiling Yuan . Exploring a Combined Theory-Practice-Simulation Teaching Model in Physical Chemistry: A Case Study of Surface Tension. University Chemistry, 2025, 40(4): 189-194. doi: 10.12461/PKU.DXHX202407053
5. [5]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
6. [6]
  Yuxin Bai , Haiying Jiang . The Physical Chemistry behind Culinary Delights. University Chemistry, 2026, 41(2): 286-294. doi: 10.12461/PKU.DXHX202503082
7. [7]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
8. [8]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
9. [9]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
10. [10]
  Ziyao Liu , Xiaoli Ji , Wenwen Fu , Minhao Tang , Qian Zhao , Yahan Yang , Ying Ma , Hongguang Li . Surfactant-mediated sol preparation: an innovative design and teaching practice in physical chemistry experiments. University Chemistry, 2026, 41(6): 343-352. doi: 10.12461/PKU.DXHX202504006
11. [11]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073
12. [12]
  Mi Wen , Baoshuo Jia , Yongqi Chai , Tong Wang , Jianbo Liu , Hailong Wu . Improvement of Fluorescence Quantitative Analysis Experiment: Simultaneous Determination of Rhodamine 6G and Rhodamine 123 in Food Using Chemometrics-Assisted Three-Dimensional Fluorescence Method. University Chemistry, 2025, 40(4): 390-398. doi: 10.12461/PKU.DXHX202405147
13. [13]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
14. [14]
  Jing Yan , Zenan Zhang , Dongwei Ma , Xinyi Zhang , Zhuodong Ye , Xuefang Chen . 三聚氰胺辅助MOFs拓扑定向转化为针状α-MoC/β-Mo₂C用于高性能电磁波吸收与耐腐蚀性研究. Acta Physico-Chimica Sinica, 2026, 42(9): 100328-. doi: 10.1016/j.actphy.2026.100328
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
17. [17]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . High-Precision and Reliable Thermal Conductivity Measurement for Graphene Films Based on an Improved Steady-State Electric Heating Method. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-0. doi: 10.1016/j.actphy.2025.100045
18. [18]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
19. [19]
  Qin′ai FENG , Jianjun LI , Lili ZHANG , Linxin WU , Huiling WANG , Wenjing HOU , Lei WANG , Mingjie REN . Amphiphilic surface modification of magnetic adsorbents and its adsorption properties of two microplastics. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 789-807. doi: 10.11862/CJIC.20250208
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(681)
HTML views(59)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return