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Citation: WANG Sen-Lin, ZHANG Yan. Electrodeposition of Pb-Sb Alloy in Methylsulfonic Acid and Its Electrochemical Performance[J]. Chinese Journal of Applied Chemistry, ;2008, 25(11): 1324-1329. shu

Electrodeposition of Pb-Sb Alloy in Methylsulfonic Acid and Its Electrochemical Performance

WANG Sen-Lin ^a,, ,
ZHANG Yan ^a,b

1.
a Departrnent of Applied Chemistry, College of Materials Science and Engineering, Huaqiao University, Key Laboratory for Functional Materials of Fujian Higher Education, Quanzhou 362021;
2.
b Fujian Jomoo Group Limited Company, Quanzhou

Corresponding author: WANG Sen-Lin,
Received Date: 29 October 2007
Available Online: 22 March 2008
Fund Project: 福建省自然科学基金资助项目(E0640004) (E0640004)

Pb-Sb alloys were plated from methylsulfonic acid bath.The cyclic voltammetry experiments show that the initial co-deposition potential of the Pb-Sb alloy was about-0.924 V(vs.Hg-Hg₂SO₄,saturated K₂SO₄),and the reduction co-deposition was controlled by diffusion.The effect of the cathodic current density on the structure of the Pb-Sb deposit was studied by X-ray diffraction,scanning electron microscopy and energy dispersive X-ray,respectively.As a result,with the increase of the cathodic current density from 5×10^-3 to 2.0×10^-2 A/cm²,the Pb molar ratio in the deposit increased from 33.6% to 82.4%.Further increasing the cathodic current density reduced the Pb content.The coating was a Pb-Sb solid solution with face centered lattice structure(F_m3m).The electrochemical performance of the Pb-Sb deposit in sulphate acid was analyzed with electrochemical experiments.The results indicate that the Pb-Sb deposit is more suitable for lead-acid battery grid material than lead.
- methylsulfonic acid,
- Pb-Sb alloy,
- electrodeposition,
- electrochemical performance,
- lead-acid battery
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