Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2655-2659. shu

Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid

1.
1. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;

Corresponding author: GAO Zhu-Qing, GU Jin-Zhong,
Received Date: 1 December 2012
Available Online: 3 June 2012
Fund Project:

A coordination polymer, namely [Cd(3-CPOA)(phen)]_n (1) has been constructed hydrothermally using 3-H₂CPOA (3-H₂CPOA=3-carboxyphenoxyacetatic acid), phen (phen=1,10-phenanthroline) and Cd(OAc)₂·2H₂O. The complex crystallizes in the monoclinic system, space group C2 with a=1.575 3(7) nm, b=1.035 4(5) nm, c=1.133 9(5) nm, β=97.806(4)°, V=1.832 3(15) nm³, D_c=1.764 g·cm^-3, Z=4, R=0.020 4 and wR=0.039 7 (I>2σ(I)). Two Cd(Ⅱ) atoms, two CPOA^2- ligands and two phen ligands form a [Cd₂(CPOA)₂(phen)₂] ring. The rings are connected by the coordination interactions of CPOA^2- ligands and Cd(Ⅱ) ions to generate a 1D double-chain, which are further extended into a 3D metal-organic supramolecular framework by C-H…O hydrogen bond interactions. Luminescent studies show that complex 1 displays strong blue emission at room temperature. CCDC: 853932.
- coordination polymer;cadmium(Ⅱ) complex;hydrogen bond;luminescent properties
1. [1]
  [1] Li L N, Luo J H, Wang S Y, et al. Cryst. Growth Des., 2011, 11:3744-3747
2. [2]
  [2] Song Y S, Yan B, Chen Z X. Inorg. Chem. Commun., 2005, 8:1165-1168
3. [3]
  [3] Wang H L, Zhang D P, Sun D F, et al. Cryst. Growth Des., 2009,9:5273-5282
4. [4]
  [4] Corma A, Iglesias M, Xamena F X L, et al. Chem. Eur. J., 2010,16:9789-9795
5. [5]
  [5] Jiang G Y, Wu T, Zheng S T, et al. Cryst. Growth Des., 2011,11:3713-3716
6. [6]
  [6] GU Jin-Zhong(顾金忠), GAO Zhu-Qing(高竹青), DOU Wei (窦伟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(9):1663-1667
7. [7]
  [7] Li J G, Zang S Q, Tian Z F, et al. CrystEngComm, 2007,9: 915-921
8. [8]
  [8] Chu Q, Su Z, Fan J, et al. Cryst. Growth Des., 2011,11:3885-3894
9. [9]
  [9] Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010,49: 3776-3788
10. [10]
  [10] Wang H L, Zhang D P, Sun D F, et al. CrystEngComm, 2010,12:1096-1102
11. [11]
  [11] Chen S C, Zhang Z H, Zhou Y S, et al. Cryst. Growth Des., 2011,11:4190-4197
12. [12]
  [12] Schnobrich J K, Lebel O, Cychosz K A, et al. J. Am. Chem. Soc., 2010,132:13941-13948
13. [13]
  [13] Xu C Y, Li L K, Wang Y P, et al. Cryst. Growth Des., 2011, 11:4667-4675
14. [14]
  [14] Gu J Z, Lü D Y, Gao Z Q, et al. J. Solid State Chem., 2011, 184:675-683
15. [15]
  [15] NIE Xue(聂雪), QU Jing-Nian(屈景年), CHEN Man-Sheng (陈满生). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(11):2267-2270
16. [16]
  [16] Cao X Y, Li Z J, Zhang J, et al. CrystEngComm, 2008,10: 1345-1349
17. [17]
  [17] Deng Z P, Huo L H, Gao S, et al. Z. Anorg. Allg. Chem., 2010,636:835-839
18. [18]
  [18] GAO Shan(高山), GU Chang-Sheng(谷长生), ZHAO Hui(赵辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(12):1437-1440
19. [19]
  [19] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of G?öttingen, Germany, 1997.
20. [20]
  [20] Li C, Li J, Sun Z G, et al. Inorg. Chem. Commun., 2011,14: 1715-1718
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沈阳化工大学材料科学与工程学院沈阳 110142