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Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2655-2659. shu

Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid

  • 1.

    1. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;

  • Corresponding author: GAO Zhu-Qing,  GU Jin-Zhong, 
  • Received Date: 1 December 2012
    Available Online: 3 June 2012

    Fund Project:

  • A coordination polymer, namely [Cd(3-CPOA)(phen)]n (1) has been constructed hydrothermally using 3-H2CPOA (3-H2CPOA=3-carboxyphenoxyacetatic acid), phen (phen=1,10-phenanthroline) and Cd(OAc)2·2H2O. The complex crystallizes in the monoclinic system, space group C2 with a=1.575 3(7) nm, b=1.035 4(5) nm, c=1.133 9(5) nm, β=97.806(4)°, V=1.832 3(15) nm3, Dc=1.764 g·cm-3, Z=4, R=0.020 4 and wR=0.039 7 (I>2σ(I)). Two Cd(Ⅱ) atoms, two CPOA2- ligands and two phen ligands form a [Cd2(CPOA)2(phen)2] ring. The rings are connected by the coordination interactions of CPOA2- ligands and Cd(Ⅱ) ions to generate a 1D double-chain, which are further extended into a 3D metal-organic supramolecular framework by C-H…O hydrogen bond interactions. Luminescent studies show that complex 1 displays strong blue emission at room temperature. CCDC: 853932.
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