Citation: QIU Li-Gan, WANG Mao-Yuan, SUN Yu-Feng, WANG Ting-Mei. Chemical Stability and Electrical Properties of Ba_1.03Ce_0.9-xZr_xTm_0.1O_3-α Solid Electrolytes[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2643-2649. shu

Chemical Stability and Electrical Properties of Ba_1.03Ce_0.9-xZr_xTm_0.1O_3-α Solid Electrolytes

1.
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China

Corresponding author: QIU Li-Gan,
Received Date: 2 January 2012
Available Online: 11 June 2012
Fund Project: 江苏省高校“青蓝工程”和江苏省高校自然科学基金(No.07KJB150126)资助项目. (No.07KJB150126)

Ba_1.03Ce_0.9-xZr_xTm_0.1O_3-α(x=0.2, 0.4) solid electrolytes with nonstoichiometric composition were prepared by high temperature solid-state reaction. Phase composition and fracture morphologies of the two materials were characterized by using XRD and SEM, respectively. Chemical stability against carbon dioxide and water steam at 900 ℃ was tested. Ionic conduction was studied by using gas concentration cell and ac impedance spectroscopy methods, and the performances of the hydrogen-air fuel cells using the two materials as solid electrolytes were evaluated in the temperature range of 500~900 ℃. The results indicate that the material with x of 0.2 is a single-phase perovskite-type orthorhombic system, and the material with x of 0.4 is a single-phase perovskite-type cubic system. They both have high density and good chemical stability. In wet hydrogen, Ba_1.03Ce_0.7Zr_0.2Tm_0.1O_3-α shows a pure ionic conduction, but Ba_1.03Ce_0.5Zr_0.4Tm_0.1O_3-α shows a mixed conduction of ion and electron from 500 to 900 ℃. The two materials both show a mixed conduction of proton, oxide ion and electronic hole in wet air, and a mixed conduction of proton, oxide ion and electron in hydrogen-air fuel cell. The fuel cells using the two materials as solid electrolytes can both work stably. The ionic conduction and performance of the hydrogen-air fuel cell of Ba_1.03Ce_0.7Zr_0.2Tm_0.1O_3-α are superior to those of Ba_1.03Ce_0.5Zr_0.4Tm_0.1O_3-α under the same experimental conditions.
- Ba_1.03Ce_0.9-xZr_xTm_0.1O_3-α;chemical stability;ionic conduction;fuel cell
1. [1]
  [1] Iwahara H, Uchida H, Ono K, et al. J. Electrochem. Soc., 1988,135:529-533
2. [2]
  [2] Hibino T, Hashimoto A, Suzuki M, et al. J. Phys. Chem. B, 2001,105:11399-11401
3. [3]
  [3] Iwahara H, Asakura Y, Katahira K, et al. Solid State Ionics, 2004,168:299-310
4. [4]
  [4] Peng R R, Wu Y, Yang L Z, et al. Solid State Ionics, 2006, 177:389-393
5. [5]
  [5] Cai M Y, Liu S, Efimov K, et al. J. Membrane Science, 2009, 343:90-96
6. [6]
  [6] Barison S, Battagliarin M, Cavallin T, et al. J. Mater. Chem., 2008,18:5120-5128
7. [7]
  [7] Katahira K, Kohchi Y, Shimura T, et al. Solid State Ionics, 2000,138:91-98
8. [8]
  [8] Kreuer K D. Solid State Ionics, 1997,97:1-15
9. [9]
  [9] Ma G L, Matsumoto H, Iwahara H. Solid State Ionics, 1999, 122:237-247
10. [10]
  [10] MA Gui-Lin(马桂林), QIU Li-Gan(仇立干), CHEN Rong (陈蓉). Acta Chim. Sinica (Huaxue Xuebao), 2002,60:2135-2140
11. [11]
  [11] Qiu L G, Ma G L, Wen D J. J. Rare Earths, 2004,22:678-682
12. [12]
  [12] WANG Mao-Yuan(王茂元), QIU Li-Gan(仇立干). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25:339-344
13. [13]
  [13] Wang X W, Yin J L, Xu J H, et al. Chin. J. Chem., 2011, 29:1114-1118
14. [14]
  [14] Wang M Y, Qiu L G, Cao X. J. Rare Earths, 2011,29:678-682
15. [15]
  [15] QIU Li-Gan(仇立干), WANG Mao-Yuan(王茂元). Acta Chim. Sinica (Huaxue Xuebao), 2010,68:276-282
16. [16]
  [16] Qiu L G, Ma G L, Wen D J. Chin. J. Chem., 2005,23:1641-1645
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Chemical Stability and Electrical Properties of Ba1.03Ce0.9-xZrxTm0.1O3-α Solid Electrolytes

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通讯作者: 陈斌, bchen63@163.com

Chemical Stability and Electrical Properties of Ba_1.03Ce_0.9-xZr_xTm_0.1O_3-α Solid Electrolytes