Citation:
QIU Li-Gan, WANG Mao-Yuan, SUN Yu-Feng, WANG Ting-Mei. Chemical Stability and Electrical Properties of Ba1.03Ce0.9-xZrxTm0.1O3-α Solid Electrolytes[J]. Chinese Journal of Inorganic Chemistry,
;2012, 28(12): 2643-2649.
-
Ba1.03Ce0.9-xZrxTm0.1O3-α(x=0.2, 0.4) solid electrolytes with nonstoichiometric composition were prepared by high temperature solid-state reaction. Phase composition and fracture morphologies of the two materials were characterized by using XRD and SEM, respectively. Chemical stability against carbon dioxide and water steam at 900 ℃ was tested. Ionic conduction was studied by using gas concentration cell and ac impedance spectroscopy methods, and the performances of the hydrogen-air fuel cells using the two materials as solid electrolytes were evaluated in the temperature range of 500~900 ℃. The results indicate that the material with x of 0.2 is a single-phase perovskite-type orthorhombic system, and the material with x of 0.4 is a single-phase perovskite-type cubic system. They both have high density and good chemical stability. In wet hydrogen, Ba1.03Ce0.7Zr0.2Tm0.1O3-α shows a pure ionic conduction, but Ba1.03Ce0.5Zr0.4Tm0.1O3-α shows a mixed conduction of ion and electron from 500 to 900 ℃. The two materials both show a mixed conduction of proton, oxide ion and electronic hole in wet air, and a mixed conduction of proton, oxide ion and electron in hydrogen-air fuel cell. The fuel cells using the two materials as solid electrolytes can both work stably. The ionic conduction and performance of the hydrogen-air fuel cell of Ba1.03Ce0.7Zr0.2Tm0.1O3-α are superior to those of Ba1.03Ce0.5Zr0.4Tm0.1O3-α under the same experimental conditions.
-
-
-
[1]
[1] Iwahara H, Uchida H, Ono K, et al. J. Electrochem. Soc., 1988,135:529-533
-
[2]
[2] Hibino T, Hashimoto A, Suzuki M, et al. J. Phys. Chem. B, 2001,105:11399-11401
-
[3]
[3] Iwahara H, Asakura Y, Katahira K, et al. Solid State Ionics, 2004,168:299-310
-
[4]
[4] Peng R R, Wu Y, Yang L Z, et al. Solid State Ionics, 2006, 177:389-393
-
[5]
[5] Cai M Y, Liu S, Efimov K, et al. J. Membrane Science, 2009, 343:90-96
-
[6]
[6] Barison S, Battagliarin M, Cavallin T, et al. J. Mater. Chem., 2008,18:5120-5128
-
[7]
[7] Katahira K, Kohchi Y, Shimura T, et al. Solid State Ionics, 2000,138:91-98
-
[8]
[8] Kreuer K D. Solid State Ionics, 1997,97:1-15
-
[9]
[9] Ma G L, Matsumoto H, Iwahara H. Solid State Ionics, 1999, 122:237-247
-
[10]
[10] MA Gui-Lin(马桂林), QIU Li-Gan(仇立干), CHEN Rong (陈蓉). Acta Chim. Sinica (Huaxue Xuebao), 2002,60:2135-2140
-
[11]
[11] Qiu L G, Ma G L, Wen D J. J. Rare Earths, 2004,22:678-682
-
[12]
[12] WANG Mao-Yuan(王茂元), QIU Li-Gan(仇立干). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25:339-344
-
[13]
[13] Wang X W, Yin J L, Xu J H, et al. Chin. J. Chem., 2011, 29:1114-1118
-
[14]
[14] Wang M Y, Qiu L G, Cao X. J. Rare Earths, 2011,29:678-682
-
[15]
[15] QIU Li-Gan(仇立干), WANG Mao-Yuan(王茂元). Acta Chim. Sinica (Huaxue Xuebao), 2010,68:276-282
-
[16]
[16] Qiu L G, Ma G L, Wen D J. Chin. J. Chem., 2005,23:1641-1645
-
[1]
-
-
-
[1]
Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
-
[2]
Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
-
[3]
Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
-
[4]
Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
-
[5]
Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
-
[6]
Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
-
[7]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[8]
Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
-
[9]
Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO2/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
-
[10]
Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
-
[11]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[12]
Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
-
[13]
Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO4 Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
-
[14]
Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
-
[15]
Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
-
[16]
Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
-
[17]
Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
-
[18]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[19]
Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
-
[20]
Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(385)
- HTML views(29)