Citation: TAO Zhao-Lin, CUI Jie-Hu, QIN Ling, ZHENG He-Gen. Synthesis, Crystal Structure and Fluorescence Property of Zinc(Ⅱ) Coordination Polymer with 4,4′-Bis(benzimidazol-1-ylmethy1)biphenyl and Phthalate[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2633-2637. shu

Synthesis, Crystal Structure and Fluorescence Property of Zinc(Ⅱ) Coordination Polymer with 4,4′-Bis(benzimidazol-1-ylmethy1)biphenyl and Phthalate

1.
1. Bengbu Medical College, Bengbu, Anhui 233030, China;

Corresponding author: ZHENG He-Gen,
Received Date: 8 May 2012
Available Online: 5 August 2012
Fund Project: 国家自然科学基金(No.20971065,91022011) (No.20971065,91022011)国家重点基础研究发展计划(No.2010CB923303)资助项目. (No.2010CB923303)

A new zinc(Ⅱ) coordination polymer [Zn(bbmb)(Pht)]_n (bbmb=4,4′-bis(benzimidazol-1-ylmethy1)biphenyl, H2Pht=phthalic acid) has been prepared by hydrothermal method and structurally characterized by elemental analysis, IR, PXRD, TGA and single-crystal X-ray diffraction. The title compound crystallizes in monoclinic, space group P2_1/c with a=1.085 28(10) nm, b=2.286 7(2) nm, c=1.218 53(12) nm, β=102.589(3)°, V=2.951 3(5) nm³, Z=4, and exhibits a 2D network. Fluorescence spectrum studies reveals that the zinc(Ⅱ) complex exhibits strong fluorescence absorption at 416 nm (λ_max) in the solid state at room temperature. CCDC: 880548.
- hydrothermal synthesis;crystal structure;zinc(Ⅱ) complex
1. [1]
  [1] Murray L J, Dinc M, Long J R. Chem. Soc. Rev., 2009,38: 1294-1314
2. [2]
  [2] ZHANG Zhong(张众), LIU Ji-Zhong(刘积中), GAO Peng(高鹏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):195-200
3. [3]
  [3] Lee J H, Park H M, Jang S P, et al. Inorg. Chem. Commun., 2012,15:212-215
4. [4]
  [4] LIN Pei-Xi(林培喜), KANG Xin-Ping(康新平), AN Zhe(安哲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1446-1450
5. [5]
  [5] Cheng L, Hu H Y, Zhang L M, et al. Inorg. Chem. Commun., 2012,15:202-207
6. [6]
  [6] Plabst M, McCusker L B, Bein T. J. Am. Chem. Soc., 2009, 131:18112
7. [7]
  [7] Huang M H, Liu P, Wang J, et al. Inorg. Chem. Commun., 2006,9:952-954
8. [8]
  [8] CHEN Li-Juan(陈丽娟), GAO Yong(高勇), XU Hui-Hong(徐慧红), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1564-1568
9. [9]
  [9] Wang J J, Yan L F, Li Z X, et al. Inorg. Chim. Acta, 2009, 362:31473154
10. [10]
  [10] Poyraz M, Sari M, Demirci F, et al. Polyhedron, 2008,27:2091
11. [11]
  [11] CAO Da-Peng(曹大鹏), YAO Xiao-Qiang(姚小强), ZHENG He-Gen(郑和根). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(5):903-906
12. [12]
  [12] Chang Y S, Xu H, Xie S P, et al. Inorg. Chem. Commun., 2010,13:959-963
13. [13]
  [13] Ji C C, Qin L, Li Y Z, et al. Cryst. Growth Des., 2011,11: 480-487
14. [14]
  [14] Qin L, Hu J S, Huang L F, et al. Cryst. Growth Des., 2010, 10(9):4176-4183
15. [15]
  [15] Zhang X, Cheng J K, Chen F, et al. Inorg. Chem. Commun., 2011,14:358-361
16. [16]
  [16] Liu C S, Ma S T, Guo L Q, et al. Transition Met. Chem., 2009,34:507-512
17. [17]
  [17] Dobrzańska L, Lloyd G O, Jacobs T, et al. J. Mol. Struct., 2006,796:107-113
18. [18]
  [18] Bruker 2000, SMART (Version 5.0), SAINT-plus (Version 6), SHELXTL (Version 6.1).
19. [19]
  [19] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 6th Ed. New York: John Wiley & Sons, 2009:64-65
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
5. [5]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
8. [8]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
11. [11]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
12. [12]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
15. [15]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
16. [16]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
17. [17]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
18. [18]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
19. [19]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
20. [20]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(428)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142