Citation: TAO Zhao-Lin, CUI Jie-Hu, QIN Ling, ZHENG He-Gen. Synthesis, Crystal Structure and Fluorescence Property of Zinc(Ⅱ) Coordination Polymer with 4,4′-Bis(benzimidazol-1-ylmethy1)biphenyl and Phthalate[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2633-2637. shu

Synthesis, Crystal Structure and Fluorescence Property of Zinc(Ⅱ) Coordination Polymer with 4,4′-Bis(benzimidazol-1-ylmethy1)biphenyl and Phthalate

1.
1. Bengbu Medical College, Bengbu, Anhui 233030, China;

Corresponding author: ZHENG He-Gen,
Received Date: 8 May 2012
Available Online: 5 August 2012
Fund Project: 国家自然科学基金(No.20971065,91022011) (No.20971065,91022011)国家重点基础研究发展计划(No.2010CB923303)资助项目. (No.2010CB923303)

A new zinc(Ⅱ) coordination polymer [Zn(bbmb)(Pht)]_n (bbmb=4,4′-bis(benzimidazol-1-ylmethy1)biphenyl, H2Pht=phthalic acid) has been prepared by hydrothermal method and structurally characterized by elemental analysis, IR, PXRD, TGA and single-crystal X-ray diffraction. The title compound crystallizes in monoclinic, space group P2_1/c with a=1.085 28(10) nm, b=2.286 7(2) nm, c=1.218 53(12) nm, β=102.589(3)°, V=2.951 3(5) nm³, Z=4, and exhibits a 2D network. Fluorescence spectrum studies reveals that the zinc(Ⅱ) complex exhibits strong fluorescence absorption at 416 nm (λ_max) in the solid state at room temperature. CCDC: 880548.
- hydrothermal synthesis;crystal structure;zinc(Ⅱ) complex
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沈阳化工大学材料科学与工程学院沈阳 110142