Citation:
ZHANG Fang, ZHANG Xiao-Gang. Mn2O3 Sub-Micron Powder: Preparation via Complex Thermolysis Route and Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry,
;2012, 28(12): 2626-2632.
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This report describes a facile preparation and electrochemical properties of Mn2O3 sub-micron powder via thermal decomposition of an isonicotinic acid manganese complex. An isonicotinic acid manganese complex of [Mn(INA)2(H2O)4]n (INA=isonicotinic acid) was synthesized by liquid diffusion method using an aqueous solution of manganese acetate and isonicotinic acid as the raw material. Mn2O3 sub-micron powder was then prepared by solid-state thermolysis of the as-synthesized INA-Mn complex at higher temperature under atmospheric pressure. The obtained products were characterized by FTIR, TG-DTA, XRD, TEM and FESEM. As an electrode material for supercapacitors, the prepared Mn2O3 electrode shows a strong cycle stability in 0.5 mol·g-1 Na2SO4 electrolyte and a specific capacitance of 88 F·g-1 at a current density of 0.5 A·g-1 vs. the saturated calomel electrode (SCE).
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[1]
[1] Du J, Gao Y Q, Li L, et al. Nanotechnology, 2006,17:4923-4928
-
[2]
[2] Yu P, Zhang X, Chen Y, et al. Mater. Chem. Phys., 2009, 118:303-307
-
[3]
[3] Jiang H, Zhao T, Yan C Y, et al. Nanoscale, 2010,2:2195-2198
-
[4]
[4] Baldi M. Appl. Catal. B: Environ., 1998,17:L175-L182
-
[5]
[5] Zang H M, Teraoka Y. Catal. Today, 1989,6:155-162
-
[6]
[6] Tabuchi M, Ado K. J. Electrochem. Soc., 1998,145:L49-L52
-
[7]
[7] Qiu Y C, Xu G L, Yang S H, et al. J. Mater. Chem., 2011, 21:6346-6353
-
[8]
[8] Nathan T, Cloke M, Prabaharan S R S. J. Nanomater., 2008, 2008:1-6
-
[9]
[9] Liu L, Liang H, Yang H X, et al. Nanotechnology, 2012,22: 015603
-
[10]
[10] Yu S, Yoshimura M. Adv. Mater., 2002,14:296-300
-
[11]
[11] He W L, Zhang Y C, Zhang X X, et al. J. Cryst. Growth, 2003,252:285-288
-
[12]
[12] Lei S J, Tang K B, Fang Z, et al. Mater. Lett., 2006,60:53-56
-
[13]
[13] Chen L Y, Xing H, Shen Y M, et al. J. Solid State Chem., 2009,182:1387-1395
-
[14]
[14] Chen L Y, Shen Y M, Bai J F, et al. J. Solid State Chem., 2009,182:2298-2306
-
[15]
[15] Salavati-Niasari M, Mohandes F, Davar F, et al. Inorgan. Chim. Acta, 2009,362:3691-3697
-
[16]
[16] Mohandes F, Davar F, Salavati-Niasari M. J. Magn. Magn. Mater., 2010,322:872-877
-
[17]
[17] Liu Y H, Lu Y L, Tsai H L, et al. J. Solid State Chem. 2001,158:315-319
-
[18]
[18] Can N, Sözerli Can S E, et al. Polyhedron, 2004,23:1109-1113
-
[19]
[19] Chapman M E, Ayyappan P, Foxman B M, et al. Cryst. Growth Des., 2001,1:159-163
-
[20]
[20] Zhang F, Zhang X G, Hao L. Mater. Chem. Phys., 2001,126: 853-858
-
[21]
[21] Li Z Q, Xie Y, Xiong Y J, et al. New J. Chem., 2003,27: 1518-1521
-
[22]
[22] Xiong Y J, Xie Y, Li Z Q, et al. Chem. Eur. J., 2003,9: 1645-1651
-
[23]
[23] Schmitt W, Hill J P, Malik S, et al. Angew. Chem. Int. Ed., 2005,44:7048-7053
-
[24]
[24] Chen L Y, Bai J F, Wang C Z, et al. Chem. Commun., 2008,11:1581-1583
-
[25]
[25] Xu M W, Kong L B, Zhou W J, et al. J. Phys. Chem. C, 2007,111:19141-19147
-
[26]
[26] Devaraj S, Munichandraiah N. J. Phys. Chem. C, 2008,112: 4406-4417
-
[27]
[27] Devaraj S, Munichandraiah N. J. Electrochem. Soc., 2007, 154:A80-A88
-
[28]
[28] Wang Y G, Xia Y Y. J. Electrochem. Soc., 2006,153:A450-A454
-
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