Advanced Search

Citation: YANG Xiao-Wei, ZHANG Yun-Wang, AN Mao-Zhong, ZHANG Lin. Electrodeposition of Gold from Non-cyanide Bath Using 5, 5′-Dimethylhydantoin-gold Complex[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2617-2625. shu

Electrodeposition of Gold from Non-cyanide Bath Using 5, 5′-Dimethylhydantoin-gold Complex

  • 1.

    1. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan, 621900, China;

  • Corresponding author: ZHANG Lin, 
  • Received Date: 16 March 2012
    Available Online: 19 June 2012

    Fund Project:

  • The effect of plating time and brightening additives (composed of saccharin, butynediol and sodium dodecyl sulfate) on the properties of gold deposits plated from a non-cyanide bath with 5, 5′-dimethylhydantoin (DMH) as the complexing agent was investigated by using scanning electron microscopy (SEM) and linear sweep voltammetry measurements. The results indicate that surface morphologies of gold electrodeposits are not markedly affected and do not change significantly with increasing deposition time, and brightening additives increase the cathodic polarization of bath and refine the grains of electrodeposits. The gold deposition rate in basic bath containing HAuCl4, DMH, K3PO4, KH2PO4 is 0.3 μm·min-1, and the high deposition rate is not influenced by the introduction of brightening additives. The properties of electrodeposits were evaluated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the gold electrodeposits have a preferential orientation along (111) direction and are composed of pure Au0 state. The electrochemical behavior of Au(Ⅲ) in the bath onto glassy carbon electrode (GCE) at 45 ℃ was studied by cyclic voltammetry and standard rotating disk. The results indicate that the electrodeposition of metallic Au in the bath is an irreversible process and is controlled by the diffusion of Au (Ⅲ) onto GCE. The stability of the DMH-gold bath is also discussed.
  • 加载中
    1. [1]

      [1] Haferkamp H, Niemeyer M, Boehm R, et al. Mater. Sci. Forum, 2000,350:31-35.

    2. [2]

      [2] Gemmler A, Keller W, Ritcher H, et al. Plat. Surf. Finish, 1994,81(8):52-58

    3. [3]

      [3] Liu J, Duan J L, Toimil M E, et al. Nanotechnology, 2006,17 (8):1922-1926

    4. [4]

      [4] Christie I R, Cameron B P, et al. Gold Bull., 1994,27(1):12-20

    5. [5]

      [5] Osaka T, Kodera A, Misato T, et al. J. Electrochem. Soc., 1997,144(10):3462-3469

    6. [6]

      [6] Masaru K, Kazutaka S, Yuta M, et al. Electrochim Acta, 2007,53(1):11-15

    7. [7]

      [7] Natter H, Hempelmann R, et al. Electrochim Acta, 2003,49: 51-61

    8. [8]

      [8] Osaka T, Kodera A, Misato T, et al. J. Electrochem. Soc., 1997,144(10):3462-3469

    9. [9]

      [9] Green T A, Liew M J, Roy S, et al. J. Electrochem. Soc., 2003,150(3):104-110

    10. [10]

      [10] Honma H, Hagiwara K, et al. J. Electrochem. Soc., 1995, 142(1):81-87

    11. [11]

      [11] Morrisey R J, Versatile A, et al. Plat. Surf. Finish, 1993,80 (4):75-79

    12. [12]

      [12] Honma H, Kagaya Y, et al. J. Electrochem. Soc., 1993,140 (9):135-137

    13. [13]

      [13] Liew M J, Sobri S, Roy S, et al. Electrochimica Acta, 2005,51(5):877-881

    14. [14]

      [14] Ohtani Y, Sugawara K, Nemoto K J, et al. Surface Finish. Soc. Japan, 2006,57(2):167-171

    15. [15]

      [15] Jayakumar M, Venkatesan K A, Srinivasan T G, et al. Electrochimica Acta, 2007,52(24):7121-7127

    16. [16]

      [16] LU J F(卢俊峰). Thesis for the Doctorate of Harbin Institute of Technology University(哈尔滨工业大学博士论文). 2007.

    17. [17]

      [17] Wang J G, Tian M L, Mallouk T E, et al. J. Phys. Chem., 2004,108:841-845

  • 加载中
    1. [1]

      Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207

    2. [2]

      Xiaoyang Li ,  Xiaowei Huang ,  Yimeng Zhang ,  Huan Liu ,  Shao Jin ,  Junpeng Zhuang . Comprehensive Chemical Experiments on the Synthesis of 1,3-Dibromo-5,5-Dimethylhydantoin and Its Application as a Brominating Reagent. University Chemistry, 2025, 40(7): 286-293. doi: 10.12461/PKU.DXHX202408035

    3. [3]

      . 

      南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

      . CCS Chemistry, 2025, 7(0): -.

    4. [4]

      Zhenlin Zhou ,  Siyuan Chen ,  Yi Liu ,  Chengguo Hu ,  Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049

    5. [5]

      Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008

    6. [6]

      Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007

    7. [7]

      Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . Thickness-Insensitive, Cyano-Modified Perylene Diimide Derivative as a Cathode Interlayer Material for High-Efficiency Organic Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-0. doi: 10.3866/PKU.WHXB202406007

    8. [8]

      Zixuan Zhao ,  Miao Fan . “Carbon” with No “Ester”: A Boundless Journey of CO2 Transformation. University Chemistry, 2025, 40(7): 213-217. doi: 10.12461/PKU.DXHX202409040

    9. [9]

      Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

    10. [10]

      Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    11. [11]

      Kun Li ,  Na Gao ,  Shuangyan Huan ,  Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068

    12. [12]

      Xiaomei Ning ,  Liang Zhan ,  Xiaosong Zhou ,  Jin Luo ,  Xunfu Zhou ,  Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085

    13. [13]

      Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097

    14. [14]

      Shanying Chen ,  Kangning Huo ,  Ke Qi ,  Jingyi Li ,  Shuxin Li ,  Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067

    15. [15]

      Jinyao Du ,  Xingchao Zang ,  Ningning Xu ,  Yongjun Liu ,  Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039

    16. [16]

      Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105

    17. [17]

      Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040

    18. [18]

      Junjian Wang , Qingquan Yu , Shunyao Liu , Yuke Chen , Xiaoyu Liu , Guodong Li , Xiaoyan Liu , Hong Liu , Weijia Zhou . Laser-Induced Carbonization of Hydroxyapatite Sandwich Paper for Inkless Printing. Acta Physico-Chimica Sinica, 2024, 40(4): 2304024-0. doi: 10.3866/PKU.WHXB202304024

    19. [19]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    20. [20]

      Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(445)
  • HTML views(46)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return