Citation: YIN Cong-Ming, XU Li-Qiang, JU Zhi-Cheng, QIAN Yi-Tai. Cubic Niobium Nitride Nanomaterials as Anode Materiasl in Lithium Ion Rechargeable Battery: Synthesis and Property[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2612-2616. shu

Cubic Niobium Nitride Nanomaterials as Anode Materiasl in Lithium Ion Rechargeable Battery: Synthesis and Property

1.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China

Corresponding author: XU Li-Qiang,
Received Date: 31 December 2012
Available Online: 24 May 2012
Fund Project: 国家自然科学基金(No.11179043,20971079) (No.11179043,20971079)973计划(No.2011CB935901)资助项目. (No.2011CB935901)

Niobium nitride (NbN) nanoparticles have been synthesized by using a solid state reaction method in an autoclave at 350 ℃. According to the X-ray powder diffraction pattern, the NbN product can be index as cubic Fm3m space group. High-resolution electron microscopy and scanning electron microscope investigations show that the NbN particles obtained have diameters ranging from 30 to 300 nm. TGA curves indicate that the sample has good stability before 540 °C in air. The NbN sample combined with Li sheet was assembled into a coin cell. Its first charge specific capacity can reach 314 mAh·g^-1. After 50 cycles, its capacity remains 228 mAh·g^-1, showing a good cycling stability.
- niobium nitride;nanometer material;lithium battery
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沈阳化工大学材料科学与工程学院沈阳 110142