Citation: HU Bing, YAO Xiao-Qiang, LU Yan-Yun, ZHANG You-Ming, WEI Tai-Bao. Synthesis of Zinc(Ⅱ) Complex of [5-Amino-1,3,4-thiadiazol-2-yl]thioglycolic and the Study of Its Crystal Structure and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2581-2586. shu

Synthesis of Zinc(Ⅱ) Complex of [5-Amino-1,3,4-thiadiazol-2-yl]thioglycolic and the Study of Its Crystal Structure and Properties

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1. Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China; Key Laboratory of Polymer Materials of Gansu Province; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

Corresponding author: WEI Tai-Bao,
Received Date: 28 December 2011
Available Online: 12 September 2012
Fund Project: 国家自然科学基金(No.21064006,21161018,21262032) (No.21064006,21161018,21262032)甘肃省自然科学基金(No.1010RJZA018) (No.1010RJZA018)

A complex of Zinc(Ⅱ), [Zn(atma)₂]_n in which the Hatma=[5-amino-1,3,4-thiadiazol-2-yl]thioglycolic acid has been synthesized and structurally characterized. The structure of the complex was determined by IR, TGA, elemental analysis and single crystal X-ray diffraction. In crystal, the title compound self-assembled from 2D layers to 3D surpramolecular framework by π-π interaction, hydrogen bonding and intercalation of groups. The cyclic voltammetry behaviors of the complex on glass carbon electrode showed a typical irreversible process. The antibacterial assays indicate that the complex shows better activities than ligand. CCDC: 805509.
- coordination polymer;crystal structure;cyclic voltammetry;antibacterial
1. [1]
  [1] Beyersmann D, Haase H. BioMetals, 2001,14:331-341
2. [2]
  [2] Farrell N. Coord. Chem. Rev., 2002,232:1-4
3. [3]
  [3] Vaira M D, Bazzicalupi C, Orioli P, et al. Inorg. Chem., 2004,43:3795-3797
4. [4]
  [4] Li Z Q, Wu F J, Gong Y, et al. Chin. J. Chem., 2007,25: 1809-1814
5. [5]
  [5] d′Angelo J, Morgant G, Ghermani N E, et al. Polyhedron, 2008,27:537-546
6. [6]
  [6] Sakurai H, Kojima Y, Yoshikawa Y, et al. Coord. Chem. Rev., 2002,226:187-198
7. [7]
  [7] Zhou Q, Hambley T W, Kennedy B J, et al. Inorg. Chem., 2000,39:3742-3748
8. [8]
  [8] Kasuga N C, Sekino K, Ishikawa M, et al. J. Inorg. Biochem., 2003,96:298-310
9. [9]
  [9] Kovala-Demertzi D, Yadav P N, Wiecek J, et al. J. Inorg. Biochem., 2006,100:1558-1567
10. [10]
  [10] Labanauskas L, Kalcas V, Udrenaite E, et al. Pharmazie, 2001,56:617-619
11. [11]
  [11] Schenone S, Bruno O, Ranise A, et al. Bioorg. Med. Chem., 2001,9:2149-2153
12. [12]
  [12] Baldwin J J, Engelhardt E L, Hirschmann R, et al. J. Med. Chem., 1980,23:65-70
13. [13]
  [13] Varvaresou A, Tsantili-Kakoulidou A, Siatra-Papastasikoudi T, et al. Arzneimittel-Forschung., 2000,50:48-54
14. [14]
  [14] Clerici F, Pocav D, Guido M, et al. J. Med. Chem., 2001, 44:931-936
15. [15]
  [15] WEI Tai-Bao(魏太保), WANG Wen-Li(王文利), GUO Xiao-Di(郭潇迪), et al. Chin. J. Org. Chem.(Youji Huaxue Xuebao), 2008,28:1820-1825
16. [16]
  [16] ZHANG You-Ming (张有明), LIN Qi (林奇), WEI Tai-Bao (魏太保), et al. Sci. China Ser. B(Zhongguo Kexue), 2004, 34:154-159
17. [17]
  [17] ZHANG You-Ming (张有明), LIU Yong(刘勇), LIN Qi(林奇), et al. Sci. China-Chem.(Zhongguo Kexue), 2011,41: 869-877
18. [18]
  [18] Misra U, Shukla S, Gurtu S, et al. Boll. Chim. Farm., 1995, 134:492-496
19. [19]
  [19] Satpathy K C, Jal B B, Mishra R. Indian J. Chem., 1984, 23:959-961
20. [20]
  [20] Wang Y T, Zhang L P, Fan Y T, et al. Inorg. Chim. Acta, 2007,360:2958-2966
21. [21]
  [21] Vyacheslav E S, Anatoly S M, Alexandra D V, et al. Eur. J. Med. Chem., 2011,46:4715-4724
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沈阳化工大学材料科学与工程学院沈阳 110142