Citation: NIE Xiang, GUO Xiao-Dong, ZHONG Ben-He, LIU Heng, FANG Wei-Mao. Effect of Mn Source on 5 V LiNi_0.5Mn_1.5O₄ Positive Electrode Materials Prepared by Combustion Method[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2573-2580. shu

Effect of Mn Source on 5 V LiNi_0.5Mn_1.5O₄ Positive Electrode Materials Prepared by Combustion Method

1.
1. College of Chemical Engineering, Sichuan University, Chengdu 610065, China;

Corresponding author: GUO Xiao-Dong,
Received Date: 22 March 2012
Available Online: 13 June 2012
Fund Project: 国家科技支撑计划(No.2007BAQ01055) (No.2007BAQ01055)国家自然科学基金(No.50574063)以及四川大学青年基金(No.2011SCU11081)资助项目. (No.50574063)以及四川大学青年基金(No.2011SCU11081)

Sub-micrometric LiNi_0.5Mn_1.5O₄ cathode materials were prepared by sucrose combustion method with two different Mn sources. The effect of manganese acetate and manganese nitrate on the crystal structure, morphology, particle size and electrical performance of the prepared samples was evaluated by X-ray diffraction (XRD),scanning electron microscopy (SEM), particle size analysis, cyclic voltammetry (CV),galvanostatic charge-discharge test and electrochemical impedance spectroscopy (EIS). XRD analysis shows that the structure of both samples is a typical cubic spinel with Fd3m space group. The particle size and the distribution of the LiNi_0.5Mn_1.5O₄ powder are strongly influenced by Mn source. The materials prepared by manganese acetate have smaller particle size and narrower particle size distribution, which can facilitate Li ions extraction and insertion. Furthermore, the sample LiNi_0.5Mn_1.5O₄ prepared by manganese acetate has better electrochemical performances. An initial specific capacity of 144.5 mAh·g^-1 at 1C in the voltage range of 3.6~5.2 V, 96% of the initial capacity after 100 cycles is maintained, and capacities of 136.3, 132.0, 124.7 and 96.6 mAh·g^-1 are achieved at the rate of 3C, 5C, 10C and 20C, respectively.
- high voltage cathode materials;sucrose combustion method;LiNi_0.5Mn_1.5O₄;Mn source
1. [1]
  [1] Guo X D, Zhong B H, Liu H, et al. J. Electrochem. Soc., 2009,156:A787-A790
2. [2]
  [2] TANG Yan(唐艳), ZHONG Ben-He(钟本和), GUO Xiao-Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(4):869-874
3. [3]
  [3] Wolfgang M, Jean-Francios C, Dietrich G, et al. Electrochimica Acta, 2010,55:4964-4969
4. [4]
  [4] Liu G Q, Wen L, Liu Y M. J. Solid State Electrochem., 2010,14:2191-2202
5. [5]
  [5] Chi L H, Dinh N N, Brutti S, et al. Electrochimica Acta., 2010,55:5110-5116
6. [6]
  [6] Yi T F, Zhu Y R, Zhu R S. Solid State Ionics., 2008,179: 2132-2136
7. [7]
  [7] Mohamed A, Jose M A, Rosa M, et al. J. Power Sources, 2008,185:501-511
8. [8]
  [8] CHEN Zhao-Yong(陈召勇), XIAO Jing(肖劲), ZHU Hua-Li (朱华丽), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(9):1417-1421
9. [9]
  [9] Yang T Y, Sun K, Lei Z Y, et al. J. Alloys Compd., 2010, 502:215-219
10. [10]
  [10] Liu H Y, Wu Y P, Rahm E, et al. J. Solid State Electrochem., 2004,8:450-466
11. [11]
  [11] Chang Z R, Dai D M, Tang H W, et al. Electrochimica Acta, 2010,55:5506-5510
12. [12]
  [12] DAI Ke-Hua(代克化), MAO Jing(毛景), ZHAI Yu-Chun (翟玉春). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(8):2130-2134
13. [13]
  [13] HE Ze-Qiang(何则强), XIONG Li-Zhi(熊利芝), WU Xian-Ming(吴显明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(5): 875-878
14. [14]
  [14] Yang T Y, Sun K N, Lei Z Y, et al. J. Solid State Electrochem., 2011,15:391-397
15. [15]
  [15] Feng X Y, Shen C, Fang X, et al. J. Alloys Compd.,2011, 509:3623-3626
16. [16]
  [16] PANG Pei-Pei(庞佩佩), TANG Zhi-Yuan(唐致远), YUAN Xiu-Lan(袁秀兰). J. Chinese Battery Industry.(Dianchi Gongye),2010,15(3):160-164
17. [17]
  [17] Fang X, Ding N, Feng X Y, et al. Electrocheimica Acta, 2009,54:7471-7475
18. [18]
  [18] Yi T F, Shu J, Zhu Y R, et al. J. Phys. Chem. Solids, 2009,70:153-158
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Effect of Mn Source on 5 V LiNi0.5Mn1.5O4 Positive Electrode Materials Prepared by Combustion Method

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Effect of Mn Source on 5 V LiNi_0.5Mn_1.5O₄ Positive Electrode Materials Prepared by Combustion Method