Citation: CHEN Hui-Fen, WANG Shuai-Hua, XU Zhong-Ning, WANG Guan-E, WANG Ming-Sheng, GUO Guo-Cong. Syntheses and Crystal Structures of Two Europium(Ⅲ) and Terbium(Ⅲ) Complexes with 6,7-Dicyanodipyridoquinoxaline[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2558-2564.
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Two lanthanideⅢ metal-organic complexes, [Eu(DICNQ)2(NO3)3]·(CH3CN)2 (1) and [Tb(DICNQ)(NO3)3]2 (2), were prepared from Eu(NO3)3·6H2O and Tb(NO3)3·6H2O with 6,7-dicyanodipyridoquinoxaline (DICNQ) by solvothermal reactions, respectively, and characterized by single-crystal X-ray diffraction analyses. Compound 1 crystallizes in the monoclinic noncentrosymmetric space group Cc, with a=1.157 7(6) nm, b=3.193 4(2) nm, c=1.106 6(6) nm, β=97.633(2)°, V=4.055(4) nm3, Z=4, Mr=984.63, Dc=1.613 g·cm-3, μ=1.623 mm-1, F(000)=1 952, S=1.035 and T=293(2) K. The final R=0.033 5 and wR=0.078 1 for 6 467 observed reflections with I>2σ(I). Compound 2 crystallizes in the triclinic centrosymmetric space group P1, with a=0.871 1(3) nm, b=0.890 8(3) nm, c=1.544 9(5) nm, α=80.852(9)°, β=84.217(9)°, γ=65.475(7)°, V=1.076 0(6) nm3, Z=1, Mr=1 254.44, Dc=1.936 g·cm-3, μ=3.356 mm-1, F(000)=604, S=1.026 and T=293(2) K. The final R=0.036 8 and wR=0.095 6 for 3 697 observed reflections with I>2σ(I). Compound 1 is built upon isolated neutral molecules, which are connected by C-H…O hydrogen-bonding interactions, while compound 2 forms a packing structure by π…π stacking interactions as well as intermolcular C-H…N and intramolecular C-H…O hydrogen-bonding interactions. CCDC: 857317, 1; 857318, 2.
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-
[1]
[1] An J, Geib S J, Rosi N L. J. Am. Chem. Soc., 2010,132:38-39
-
[2]
[2] Chen B, Xiang S C, Qian G. Acc. Chem. Res., 2010,43:1115 -1124
-
[3]
[3] Jiang H L, Xu Q. Chem. Commun., 2011,47:3351-3370
-
[4]
[4] Hollingsworth M D. Science, 2002,295:2410-2413
-
[5]
[5] Lozan V, Loose C, Kortus J, et al. Coord. Chem. Rev., 2009, 253:2244-2260
-
[6]
[6] Lozan V, Loose C, Kortus J, et al. Coord. Chem. Rev., 2009, 253:2244-2260
-
[7]
[7] Holliday B J, Mirkin C A. Angew. Chem. Int. Ed., 2001,40: 2022-2043
-
[8]
[8] Weng Z, Liu D, Chen Z, et al. Cryst. Growth Des., 2009,9: 4163-4170
-
[9]
[9] Mahmoudi G, Morsali A. CrystEngComm, 2009,11:50-51
-
[10]
[10] Tephenson M D, Hardie M J. Cryst. Growth Des., 2006,6: 423-432
-
[11]
[11] Chen H F, Li Y, Wang M S, et al. Chinese J. Struct. Chem. (Jiegou Huaxue), 2008,11:1398-1403
-
[12]
[12] Delahaye S, Loosli C, Liu S X, et al. Adv. Funct. Mater., 2006,16:286-295
-
[13]
[13] Chen H F, Jiang X M, Wang M S, et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 2011,30:324-329
-
[14]
[14] Xu Z D, Liu H, Wang M, et al. J. Chinese Pharm. Sci. (Zhongguo Yaoxue), 2002,11:125-131
-
[15]
[15] Xu Z D, Liu H, Wang M, et al. J. Inorg. Biochem., 2002, 92:149-155
-
[16]
[16] Liu H, Du M, Ge X J, et al. Acta Crystallogr. Sect. E, 2001, 57:m100-m102
-
[17]
[17] Si Z, Li J, Li B, et al. J. Phys. Chem. C, 2008,112:3920-3925
-
[18]
[18] Kozlov L, Goldberg I. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2008,64:m123-m126
-
[19]
[19] Chen H F, Guo G C, Wang M S, et al. Dalton Trans., 2009, 46:10166-10168
-
[20]
[20] Rigaku. Crystal Clear Version 1.3.5, Rigaku Corporation, Japan, 2002.
-
[21]
[21] Siemens. SHELXTLTM Version 5 Reference Manual, Siemens Energy & Automation Inc., Madison, Wisconsin, USA, 1994.
-
[22]
[22] Cotton S A, Franckevicius V, Mahon M F, et al. Polyhedron, 2006,25:1057-1068
-
[23]
[23] Fukuda Y, Nakao A, Hayashi K. J. Chem. Soc., Dalton Trans., 2002:527-533
-
[24]
[24] Yang L W, Liu S, Rettig S J, et al. Inorg. Chem., 1995,34: 4921-4925
-
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