Citation: HU Bin, YAN Liu-Shui, ZHANG Ai-Qin, HUANG Wei. Synthesis, Crystal Structures, Cis-Trans Conformation and Substituent Effects of Manganese(Ⅱ) and Cobalt(Ⅱ) Complexes Having 3,8-Dithiophen or 3,8-Di-3-methylthiophen-1,10-phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2540-2547. shu

Synthesis, Crystal Structures, Cis-Trans Conformation and Substituent Effects of Manganese(Ⅱ) and Cobalt(Ⅱ) Complexes Having 3,8-Dithiophen or 3,8-Di-3-methylthiophen-1,10-phenanthroline

HU Bin ^1,2,, ,
YAN Liu-Shui ¹ ,
ZHANG Ai-Qin ¹ ,
HUANG Wei ^2,,

1.
1. School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China;

Corresponding author: HU Bin, HUANG Wei,
Received Date: 6 March 2012
Available Online: 5 July 2012
Fund Project: 国家自然科学基金(No.21165013,21171088) (No.21165013,21171088)中国博士后基金(No.2012M511720) (No.2012M511720)江西省自然科学基金(No.2010GZH0112) (No.2010GZH0112)南昌航空大学博士基金(No.EA201102327)资助项目. (No.EA201102327)

A dinuclear 3,8-dithiophen substituted 1,10-phenanthroline (dtphen) manganese(Ⅱ) complex and a pair of 3,8-di-3-methylthiophen substituted 1,10-phenanthroline (dmtphen) manganese(Ⅱ) and cobalt(Ⅱ) complexes, formulated as [trans-Mn₂Cl₄(dtphen)₂] (1), [cis-MnCl₂(dmtphen)₂] (2) and [cis-CoCl₂(dmtphen)₂] (3), were synthesized and characterized by elemental analysis, FTIR, UV-Vis spectra and X-ray single-crystal structural analysis. The two Mn(Ⅱ) complexes exhibit diverse coordination models in the whole molecular structures. In mononuclear complexe 2 and 3, both dmtphen ligands have similar trans/trans conformation but different dihedral angles ranging from 14.1(1)°~51.5(1)° because of the spatial crowding effects of methyl group. In contrast, the dihedral angles of dtphen ligands in dinuclear complex 1 are only within 2.0(1)°~20.2(1)° and the two side thiophene rings in the dtphen ligand adopt the cis/trans conformation relative to the central phen unit. CCDC: 870021, 1; 870022, 2; 870023, 3.
- manganese(Ⅱ) complexe;cobalt(Ⅱ) complexe;substituent effects;cis and trans configuration;crystal structure
1. [1]
  [1] Liu B, Bazan G C. Chem. Mater., 2004,16(23):4467-4476
2. [2]
  [2] Xue X J, Wang F, Liu X G. J. Am. Chem. Soc., 2008,130 (11):3244-3245
3. [3]
  [3] McQuade D T, Pullen A E, Swager T M. Chem. Rev., 2000, 100(7):2537-2574
4. [4]
  [4] Thomas S W, Joly G D, Swager T M. Chem. Rev., 2007,107 (4):1339-1386
5. [5]
  [5] McGehee M D, Heeger A J. Adv. Mater., 2000,12(22):1655-1668
6. [6]
  [6] Chen C Y, Wang M K, Li J Y, et al. ACS Nano., 2009,3(10): 3103-3109
7. [7]
  [7] Hara K, Sato T, Katoh R, et al. Adv. Funct. Mater., 2005,15 (2):246-252
8. [8]
  [8] Wu W P, Liu Y Q, Zhu D B. Chem. Soc. Rev., 2010,39(5): 1489-1502
9. [9]
  [9] Gross M, Muller D C, Nothofer H G, et al. Nature, 2000, 405(6787):661-665
10. [10]
  [10] Kulkarni A P, Tonzola C J, Babel A, et al. Chem. Mater., 2004,16(23):4556-4573
11. [11]
  [11] Lo S C, Burn P L. Chem. Rev., 2007,107(4):1097-1116
12. [12]
  [12] Zang L, Che Y K, Moore J S. Accounts Chem. Res., 2008, 41(12):1596-1608
13. [13]
  [13] Bencini A, Lippolis V. Coord. Chem. Rev., 2010,254(17-18): 2096-2180
14. [14]
  [14] Melnik M, Holloway C E. Coord. Chem. Rev., 2006,250(17-18):2261-2270
15. [15]
  [15] Huang W, Tanaka H, Ogawa T. J. Phys. Chem. C, 2008,112 (30):11513-11526
16. [16]
  [16] Huang W, Masuda G, Maeda S, et al. Inorg. Chem., 2008, 47(2):468-480
17. [17]
  [17] Wang L, You W, Huang W, et al. Inorg. Chem., 2009,48 (10):4295-4305
18. [18]
  [18] Huang W, Tanaka H, Ogawa T, et al. Adv. Mater., 2010,22 (25):2753-2758
19. [19]
  [19] Hu B, Fu S J, Xu F, et al. J. Org. Chem., 2011,76(11):4444-4456
20. [20]
  [20] Hu B, Xu F, Fu S J, et al. Inorg. Chim. Acta, 2010,363(7): 1348-1354
21. [21]
  [21] Saitoh Y, Koizumi T, Osakada K, et al. Can. J. Chem.-Rev. Can. Chim., 1997,75(10):1336-1339
22. [22]
  [22] Araki K, Endo H, Masuda G, et al. Chem.-Eur. J., 2004,10 (13):3331-3340
23. [23]
  [23] Siemens, SAINT v4 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, 2000.
24. [24]
  [24] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Dectector Data, Univ. of Gottingen, Germany, 2000.
25. [25]
  [25] Sheldrick G M. SHELXTL, Version 6.10 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, 2000.
26. [26]
  [26] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc. Dalton Trans., 1984(7):1349-1356
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
7. [7]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
13. [13]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
16. [16]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
19. [19]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
20. [20]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(315)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142