Citation: ZHAI Bin, YI Yong-Ling, HAN Nan-Nan, ZHANG Xiang-Fei. Synthesis, Crystal Structure and Magnetic Research of 1D Chain Manganese Coordination Polymer Based on Pyrazine-2,3,5,6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2535-2539. shu

Synthesis, Crystal Structure and Magnetic Research of 1D Chain Manganese Coordination Polymer Based on Pyrazine-2,3,5,6-tetracarboxylic Acid

1.
1. College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, Henan 476000, China;

Corresponding author: ZHAI Bin,
Received Date: 16 February 2012
Available Online: 12 July 2012
Fund Project: 国家自然科学基金(No.21001071) (No.21001071)河南省教育厅自然科学研究计划(No.2010A150018)资助项目. (No.2010A150018)

Coordination polymer {[Mn₂(phen)₂(H₂pztc)Mn₂(phen)₂(Hpztc)₂ (H₂O)₂]·4H₂O}_n (1) has been synthesized by the hydrothermal reaction of MnCl₂·4H₂O, pyrazine-2,3,5,6-tetracarboxylic acid (H₄pztc) and 1,10-phenanthroline (phen), which were further characterized by IR, elemental analysis, X-ray diffraction single-crystal structural analysis and magnetic susceptibility. It belongs to triclinic crystal system, P1 space group with a=0.955 02(19) nm, b=1.323 4(3) nm, c=1.515 7(3) nm, α=68.95(3)°, β=77.33(3)°, γ=81.92(3)°, V=1.740 3(6) nm³, Z=2. The manganese(Ⅱ) ions in the complex are 6-coordinated and 7-coordinated. The Mn(Ⅱ) ions of complex 1 are connected by pztc and phen, resulting in a 1D chain. Variable temperature magnetic susceptibility measurements reveal the existence of antiferromagnetic interactions in the complex 1. CCDC: 694108.
- one-dimensional chain;manganese(Ⅱ) complex;crystal structure;pyrazine-2,3,5,6-tetracarboxylic acid;magnetic property
1. [1]
  [1] Yigit M V, Wang Y, Moulton B, et al. Cryst. Growth Des., 2006,6:829-832
2. [2]
  [2] Ghosh S K, Bharadwaj P K. Eur. J. Inorg. Chem., 2005:4880 -4885
3. [3]
  [3] Ghosh S K, Bharadwaj P K. Inorg. Chem., 2004,22:6887-6889
4. [4]
  [4] Gao H L, Zhang Y P, Yang A H, et al. J. Mol. Stru., 2009, 918:97-100
5. [5]
  [5] Yang A H, Quan Y P, Gao H L, et al. CrystEngComm, 2009, 11:2719-2727
6. [6]
  [6] GAO Hong-Ling(高洪苓), CHENG Peng(程鹏). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(10):1145-1149
7. [7]
  [7] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Stru-cture Determination, Göttingen University, Germany, 1997.
8. [8]
  [8] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Determination, Göttingen University, Germany, 1997.
9. [9]
  [9] Kazuo N, Translated by HUANG De-Ru(黄德如), WANG Ren -Qing(汪仁庆), LIAO Dai-Wei(廖代伟). Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和配位化合物的红外和拉曼光谱). Beijing: Chemical Industry Press, 1986.
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
5. [5]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
14. [14]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
17. [17]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
18. [18]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
19. [19]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
20. [20]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(160)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142