Citation: YE Jian, ZHANG Hai-Yan, CHEN Yi-Ming, HU Li, RAN Qi-Yan, DU Lei. Preparation of Graphene by Ball Milling-Assisted Oxidization-Reduction Method[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2523-2529. shu

Preparation of Graphene by Ball Milling-Assisted Oxidization-Reduction Method

1.
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: ZHANG Hai-Yan,
Received Date: 9 May 2012
Available Online: 11 June 2012
Fund Project: 国家自然科学基金(No.20971027)资助项目. (No.20971027)

Graphite oxide (GO) was prepared from natural graphite by a modified Hummers method. GO was firstly ball milled for 10 h and then exfoliated into graphene oxide by ultrasonication. Finally, graphene was prepared by magnetic mixing reflux method using hydrazine monohydrate as reductant. Graphene is characterized by SEM, AFM, XRD, Raman, FTIR, TEM measurements. The surface morphology and structure of graphene sheets which are prepared by low-energy ball milling assisted oxidization-reduction method and oxidization-reduction method without ball milling are compared and analyzed. The results show that ball milling contributes to the thinning and exfoliation of GO. Otherwise, low-energy ball milling can promote the reduction degree of GO, shorten the reflux reaction time and improve the efficiency of graphene preparation.
- graphene oxide;graphene;ball milling;ultrasonication;magnetic mixing
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