Citation: MAO Jun-Xian, JIANG Jiao, WANG Hua-Kai, YANG Li-Jun, WANG Yang-Nian, GENG Jiao, WANG Xi-Zhang, HU Zheng. Immobilizing Ruthenium Nanoparticles onto Nitrogen-Doped Carbon Nanotubes for Aerobic Oxidation of Benzyl Alcohol under Ambient Pressure[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2508-2512. shu

Immobilizing Ruthenium Nanoparticles onto Nitrogen-Doped Carbon Nanotubes for Aerobic Oxidation of Benzyl Alcohol under Ambient Pressure

1.
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: GENG Jiao, WANG Xi-Zhang,
Received Date: 8 May 2012
Available Online: 1 July 2012
Fund Project: 国家自然科学基金(No.21173114,21173115,20833002) (No.21173114,21173115,20833002) “973”项目(No.2007CB936302) (No.2007CB936302)江苏省自然科学基金(No.BK2010304)资助项目. (No.BK2010304)

Ruthenium nanoparticles were conveniently immobilized on nitrogen-doped carbon nanotubes (NCNTs) via microwave-assisted ethylene glycol reduction. Ru/NCNTs catalysts presented the excellent catalytic performance and cyclical stability for the aerobic oxidation of benzyl alcohol under atmospheric condition, compared with the catalysts supported on carbon nanotubes (CNTs) and activated carbon (AC). The conversion of benzyl alcohol could rearch 93% and the selectivity of benzaldehyde was higher than 99% at 90 ℃. The doped nitrogen atoms embedded in the NCNTs wall are responsible for the improved catalytic performance.
- oxidation of benzyl alcohol;nitrogen-doped carbon nanotubes;Ru nanoparticles;microwave-assisted ethylene glycol reduction
1. [1]
  [1] Tamas M, Alfons B. Chem. Rev., 2004,104:3037-3058
2. [2]
  [2] Muzart J. Chem. Rev., 1992,92:113-140
3. [3]
  [3] Uchiyama M, Kimura Y, Ohta A. Tetrahedron Lett., 2000,41: 10013-10017
4. [4]
  [4] Berkowitz L M, Rylander P N. J. Am. Chem. Soc., 1959,80: 6682-668
5. [5]
  [5] Menger F M, Lee C. Tetrahedron Lett., 1981,22:1655-1656
6. [6]
  [6] An G, Lim M, Rhee H, et al. Synlett., 2007,1:95-98
7. [7]
  [7] Korovchenko P, Donze C, Gallezot P, et al. Catal. Today, 2007,121:13-21
8. [8]
  [8] Yun H N, Shigeru I, Michio M, et al. Chem. Commun., 2008,27:3181-3183
9. [9]
  [9] Onal Y, Schimpf S, Claus P. J. Catal., 2004,223:122-133
10. [10]
  [10] Yamaguchi Y, Mizuno N. Angew. Chem. Int. Ed., 2002,41: 4538-4542
11. [11]
  [11] Enache D I, Edwards J K, Hutchings G J, et al. Science, 2006,311:362-365
12. [12]
  [12] Iijima S. Nature, 1991,354:56-58
13. [13]
  [13] Deng W P, Liu M, Tan X S, et al. J. Catal., 2010,271:22-32
14. [14]
  [14] Rodrigues E G, Carabineiro S, Chen X, et al. J. Catal., 2012,285:83-91
15. [15]
  [15] Xiong H F, Moyo M, Coville N J, et al. J. Catal., 2011,278:26-40
16. [16]
  [16] Julien A, Kambiz C, Cuong P H, et al. Catal. Today, 2008, 138:62-68
17. [17]
  [17] Yue B, Ma Y W,Hu Z, et al. J. Mater. Chem., 2008,18: 1747-1750
18. [18]
  [18] Jiang S J, Ma Y W, Hu Z, et al. Adv. Mater., 2009,21:4953-4956
19. [19]
  [19] Wang X Z,Xue H, Hu Z, et al. Nanotechnol., 2011,22: 395401-395407
20. [20]
  [20] Yang Y, Hu Z, Wang X Z, et al. Nanotechnol., 2003,14: 733-737
21. [21]
  [21] Chen H, Yang Y, Hu Z, et al. J. Phys. Chem. B, 2006,110: 16422-16427
22. [22]
  [22] XUE Hua(薛华), YANG Li-Jun(杨立军), WANG Xi-Zhang (王喜章), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(12):2459-2463
23. [23]
  [23] Zamudio A, Elias A L, Terrones M, et al. Small, 2006,2: 346-350
24. [24]
  [24] Lepro X, Terres E, Terrones M, et al. Chem. Phys. Lett., 2008,463:124-129
25. [25]
  [25] Fu X, Yu H, Peng F, et al. Appl. Catal. A: General, 2007, 321:190-197
26. [26]
  [26] GAO Wei-Jie(高伟洁), GUO Shu-Jing(郭淑静), ZHANG Hong-Bo(张洪波), et al. Chin. J. Catal. (Cuihua Xuebao) 2011,32:1418-1423
27. [27]
  [27] Yang L J, Jiang S J, Zhao Y, et al. Angew. Chem. Int. Ed., 2011,50:7132-7135
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
3. [3]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
4. [4]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
7. [7]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
8. [8]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
9. [9]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
10. [10]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
11. [11]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
12. [12]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
13. [13]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
14. [14]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
15. [15]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
18. [18]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
19. [19]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
20. [20]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(292)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142