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Citation: ZHU Shen, LIU Xuewen, WANG Pu, GU Zhongze, HAN Guozhi. Synthesis of Benzo-15-crown-5 Under Ultrasonication[J]. Chinese Journal of Applied Chemistry, ;2013, 30(1): 120-122. doi: DOI:10.3724/SP.J.1095.2013.20050 shu

Synthesis of Benzo-15-crown-5 Under Ultrasonication

ZHU Shen ^a,b ,
LIU Xuewen ^a ,
WANG Pu ^a ,
GU Zhongze ^b,, ,
HAN Guozhi ^a,b,,

1.
a Department of Applied Chemistry, Nanjing University of Technology, Nanjing 210009, China;
2.
b State Key Laboratory of Molecular Electronics, Southeast University, Nanjing 210096, China

Corresponding author: GU Zhongze, HAN Guozhi,
Received Date: 20 February 2012
Available Online: 25 May 2012
Fund Project: 江苏省博士后基金(1002006C) (1002006C)中国博士后基金(20100481084)资助项目 (20100481084)

Using o-dihydroxybenzene and 1,11-dichloro-3,6,9-trioxaundecane as raw materials,sodium hydroxide as template,DMF as solvent and appropriate amount of 2,6-di-tert-butyl-4-methylphenol as antioxidant,benzo-15-crown-5 was successfully synthesized under ultrasonication at temperature 60~70℃.Compared with traditional synthetic routes,reaction time could be reduced to within 2 h,and the yield reached up to 30.7%.
- o-dihydroxybenzene,
- dichloro-trioxaundecane,
- ultrasonic synthesis,
- benzo-15-crown-5
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