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Citation: XU Gang, DONG Wenli, REN Lingyan, LIU Huoan. Synthesis and Application of Copper(Ⅱ) Schiff Base Complex with Ethylene-diamine-bis-(salicylaldehyde)[J]. Chinese Journal of Applied Chemistry, ;2013, 30(1): 88-92. doi: DOI:10.3724/SP.J.1095.2013.20024 shu

Synthesis and Application of Copper(Ⅱ) Schiff Base Complex with Ethylene-diamine-bis-(salicylaldehyde)

1.
College of Safety Engineering, Chongqing University of Science and Technology, Chongqing 401331, China

Corresponding author: XU Gang,
Received Date: 16 January 2012
Available Online: 23 February 2012
Fund Project: 国家国际科技合作专项(2009DFA91450)资助 (2009DFA91450)

A copper(Ⅱ) Schiff base complex with ethylene-diamine-bis-(salicylaldehyde)[Cu(Ⅱ)-EDBSAD] was synthesized and a poly vinyl chloride(PVC) membrane electrode with the complex as neutral carrier was prepared.The electrode displays a preferential potentiometric response to SCN^-and exhibits near Nernst response for SCN^- within a wide concentration range(1.0×10^-1~1.0×10^-7 mol/L) with calibration curve equation of E(mV)=-51.75lg c_SCN^--255.29,and a detection limit of 5.6×10^-8 mol/L in pH=5.5 phosphate buffer solution at 25℃.This electrode was applied to the determination of SCN^- in waste water and the obtained result was in good agreement with those of high-performance liquid chromatography method.
- copper(Ⅱ) complex,
- ion-selective electrode,
- SCN^-,
- waste water
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