Citation: Zhang Chao, Zhang Baoqing, Liu Chenyang. Dispersions of α-Zirconium Phosphate/organic Solvent with Structural Colors[J]. Acta Chimica Sinica, ;2020, 78(12): 1399-1403. doi: 10.6023/A20100470 shu

Dispersions of α-Zirconium Phosphate/organic Solvent with Structural Colors

Zhang Chao ^a,b ,
Zhang Baoqing ^a,b ,
Liu Chenyang ^a,b,,

a.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Liu Chenyang, liucy@iccas.ac.cn
Received Date: 14 October 2020
Available Online: 11 December 2020
Fund Project: the National Natural Science Foundation of China 21674122Project supported by the National Natural Science Foundation of China (No. 21674122)

Figures(5)

α-zirconium phosphate (α-ZrP) crystals with high-crystallinity were synthesized via hydrothermal method and exfoliated with tetrabutylammonium hydroxide (TBAOH) in aqueous dispersion maintained at 0℃ in an ice bath. The exfoliated α-ZrP nano-sheets were then transferred into selected organic solvents, such as acetone, via centrifugal precipitation and re-dispersion process. This process was repeated 3 to 5 times to replace the water with the desired organic solvents. During the solvent-replacing process, most of the free TBAOH in α-ZrP/H₂O dispersion was also removed, which was confirmed by characterizing the organic contents via thermo-gravimetric analysis for the solids obtained from both the water dispersion and the resulted acetone dispersion. Serendipitously, the dispersions of α-ZrP/organic solvent with structural colors could be easily obtained using this solvent-replacement method. After the solvent-replacing process was repeated for 5 times, the resulted α-ZrP/acetone dispersions could reflect visible light in the range of 426 nm to 635 nm when the mass fraction of α-ZrP was between 0.76% and 1.86%, thus showing the corresponding structural colors. Increasing the concentration of TBA⁺ ions in α-ZrP/acetone dispersion (α-ZrP mass fraction 0.87%), its UV-Vis reflection spectrum showed a blue-shift, indicating that the formation of periodic structures mainly depended on the electrostatic repulsion between α-ZrP nano-sheets. The formation of structural color also showed a size-dependence on the exfoliated α-ZrP nano-sheets. The nano-sheets with large-size was more likely to form the long-range ordered structure showing structural color compared with the relatively small ones (1.10 μm vs. 0.48 μm). The dispersions with acetonitrile or butyronitrile as solvent, which exhibited obvious structural colors, could also be obtained using this solvent-replacement method. At present, many plate-like inorganic particles used in the research have intrinsic charges on their gallery faces that similar to the microstructure of α-ZrP crystals, so the method reported here can give general guidance for the preparation of the dispersions with long-range periodic structures for these particles.
- α-zirconium phosphate,
- nano-sheets,
- dispersion,
- liquid crystal phase,
- structural color
1. [1]
  Bates, M. A.; Frenkel, D. J. Chem. Phys. 1999, 110, 6553.
2. [2]
  Miyamoto, N.; Nakato, T. Isr. J. Chem. 2012, 52, 881.
3. [3]
  Li, P.; Wong, M. H.; Zhang, X.; Yao, H. Q.; Ishige, R.; Takahara, A.; Miyamoto, M.; Nishimura, R.; Sue, H. J. ACS Photonics 2014, 1, 79.
4. [4]
  Shen, T. Z.; Hong, S. H.; Lee, B.; Song, J. K. NPG Asia Mater. 2016, 8, e296.
5. [5]
  Wang, Y.-F.; Yang, Q.; Su, B. Acta Chim. Sinica 2017, 75, 1071 (in Chinese).
6. [6]
  Ye, C.-Q.; Chen, S.-R.; Li, F.-Y.; Ge, J.; Yong, P.-Y.; Qin, M.; Song, Y.-L. Acta Chim. Sinica 2018, 76, 237 (in Chinese).
7. [7]
  Wong, M. H.; Ishige, R.; Hoshino, T.; Hawkins, S.; Li, P.; Takahara, A.; Sue, H. J. Chem. Mater. 2014, 26, 1528.
8. [8]
  Sano, K.; Kim, Y. S.; Ishida, Y.; Ebina, Y.; Sasaki, T.; Hikima, T.; Aida, T. Nature Commun. 2016, 7, 12559.
9. [9]
  Sun, L. Y.; Boo, W. J.; Sue, H. J.; Clearfield, A. New J. Chem. 2007, 31, 39.
10. [10]
  Chen, F.; Chen, M. F.; Chang, Y. W.; Lin, P. C.; Chen, Y.; Cheng, Z. D. Soft Matter 2017, 13, 3789.
11. [11]
  Chen, M. F.; He, M.; Lin, P. C.; Chen, Y.; Cheng, Z. D. Soft Matter 2017, 13, 4457.
12. [12]
  Sun, L. Y.; Boo, W. J.; Sue, H. J. J. Chem. Mater. 2007, 19, 1749.
13. [13]
  Mejia, A. F.; Chang, Y. W.; Ng, R.; Shuai, M.; Mannan, M. S.; Cheng, Z. D. Phys. Rev. E 2012, 85, 061708.
14. [14]
  Jalili, R.; Aboutalebi, S. H.; Esrafilzadeh, D.; Konstantinov, K.; Moulton, S. E.; Razal, J. M.; Wallace, G. G. ACS Nano 2013, 7, 3981.
15. [15]
  Masud, A. R.; Hong, S. H.; Shen, T. Z.; Ahn, C. H.; Song, J. K. Opt. Express 2018, 26, 173.
16. [16]
  Masud, A. R.; Hong, S. H.; Shen, T. Z.; Shahzad, A.; Song, J. K. RSC Adv. 2018, 8, 16549.
17. [17]
  Barton, A. F. M. CRC Handbook of Solubility Parameters and Other Cohesion Parameters, 2nd ed., CRC Press, Boca Raton, FL, 1991.
18. [18]
  Lide, D. R. CRC Handbook of Chemistry and Physics, 79th ed., CRC Press, Boca Raton, FL, 1999.
1. [1]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
6. [6]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
7. [7]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
10. [10]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
11. [11]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
12. [12]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
13. [13]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
14. [14]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
15. [15]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
16. [16]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
17. [17]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035
18. [18]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
19. [19]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
20. [20]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054

Get Citation

PDF

XML

Metrics

PDF Downloads(41)
Abstract views(2844)
HTML views(341)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142