Citation: Feng Sheng, Gao Wenbo, Cao Hujun, Guo Jianping, Chen Ping. Advances in the Chemical Looping Ammonia Synthesis[J]. Acta Chimica Sinica, ;2020, 78(9): 916-927. doi: 10.6023/A20060207 shu

Advances in the Chemical Looping Ammonia Synthesis

Feng Sheng ^a,b ,
Gao Wenbo ^a ,
Cao Hujun ^a ,
Guo Jianping ^a,, ,
Chen Ping ^a,b

a.
Dalian National Laboratory for Clean Energy, Collaborative Innovation Center of Chemistry for Energy Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
b.
Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, China

Corresponding author: Guo Jianping, guojianping@dicp.ac.cn
Received Date: 4 June 2020
Available Online: 9 July 2020
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21872137, 21922205) and Youth Innovation Promotion Association Chinese Academy of Sciences (No. 2018213).the National Natural Science Foundation of China 21922205Youth Innovation Promotion Association Chinese Academy of Sciences 2018213the National Natural Science Foundation of China 21872137

Figures(9)

Ammonia is not only the main raw material of nitrogen fertilizer, but also a promising energy carrier for the storage and utilization of renewable energy. The fossil fuel-based Haber-Bosch ammonia synthesis industry is an energy-consuming and high CO₂-emission process. For the sustainable growth of human society, it is critically important to develop "green" ammonia synthesis processes driven by renewable energies. This scenario motivates growing interests on ammonia synthesis via heterogeneous catalysis, electro-chemical and photo-chemical routes as well as chemical looping process. Chemical looping ammonia synthesis (CLAS) process involves a series of individual reactions which produce ammonia in a distinctly different manner to the catalytic process. The CLAS could be operated under ambient pressure, and the switching on/off operation is flexible. Therefore, CLAS may be more amenable to variable and intermittent operation compared to the conventional catalytic process. More importantly, the competitive adsorption of N₂ and H₂ or H₂O in the catalytic process can be circumvented to a great extent, which opens new opportunities for the design and development of nitrogen carriers especially for low-temperature ammonia production. Because of these unique features, the application of chemical looping technology for ammonia synthesis has been received increasing attention in recent years. The development of high-efficiency nitrogen carriers is the key component for the implementation of CLAS. A wide range of materials including metal nitrides, metal imides, nitride-hydrides and oxynitrides have been evaluated as nitrogen carriers for CLAS. The knowledge accumulated during the past decade will no doubt beneficial for the further optimization and development of nitrogen carriers. This article reviews the research progress in the field of chemical looping ammonia synthesis in recent years, with the focuses on the materials development of nitrogen carriers in CLAS. Furthermore, the challenges and future directions of CLAS are also discussed. With the development of nitrogen carriers and process design, CLAS would potentially play an important role in the green ammonia synthesis as well as the future energy system.
- ammonia synthesis,
- chemical looping,
- nitrogen carrier,
- nitride,
- imide
1. [1]
  Liu, H. Z. Chem. Ind. Eng. Prog. 2013, 32, 1995(in Chinese).
2. [2]
  Klerke, A.; Christensen, C. H.; Norskov, J. K.; Vegge, T. J. Mater. Chem. 2008, 18, 2304. doi: 10.1039/b720020j
3. [3]
  Guo, J. P.; Chen, P. Chem 2017, 3, 709. doi: 10.1016/j.chempr.2017.10.004
4. [4]
  Valera-Medina, A.; Xiao, H.; Owen-Jones, M.; David, W. I. F.; Bowen, P. J. Prog. Energy Combust. Sci. 2018, 69, 63. doi: 10.1016/j.pecs.2018.07.001
5. [5]
  Smith, C.; Hill, A. K.; Torrente-Murciano, L. Energy Environ. Sci. 2020, 13, 331. doi: 10.1039/C9EE02873K
6. [6]
  Erisman, J. W.; Sutton, M. A.; Galloway, J.; Klimont, Z.; Winiwarter, W. Nat. Geosci. 2008, 1, 636. doi: 10.1038/ngeo325
7. [7]
  Wang, Q. R.; Guo, J. P.; Chen, P. J. Energy Chem. 2019, 36, 25(in Chinese).
8. [8]
  Norskov, J. K.; Chen, J. G. Sustainable Ammonia Synthesis, US Department of Energy, 2016.
9. [9]
  Zeng, L.; Cheng, Z.; Fan, J. A.; Fan, L. S.; Gong, J. L. Nat. Rev. Chem. 2018, 2, 349. doi: 10.1038/s41570-018-0046-2
10. [10]
  Gao, W. B.; Guo, J. P.; Wang, P. K.; Wang, Q. R.; Chang, F.; Pei, Q. J.; Zhang, W. J.; Liu, L.; Chen, P. Nat. Energy 2018, 3, 1067. doi: 10.1038/s41560-018-0268-z
11. [11]
  Koerts, T.; Vansanten, R. A. J. C. S. Chem. Commun. 1991, 1281.
12. [12]
  Wang, Q. R.; Guo, J. P.; Chen, P. Joule 2020, 4, 705. doi: 10.1016/j.joule.2020.02.008
13. [13]
  Zeng, L.; Luo, S. W.; Li, F. X.; Fan, L. S. Sci. China Chem. 2012, 42, 260(in Chinese).
14. [14]
  Chen, S.; Zeng, L.; Mu, R. T.; Xiong, C. Y.; Zhao, Z. J.; Zhao, C. J.; Pei, C. L.; Peng, L. M.; Luo, J.; Fan, L. S.; Gong, J. L. J. Am. Chem. Soc. 2019, 141, 18653. doi: 10.1021/jacs.9b09235
15. [15]
  Gao, Y. F.; Wang, X. J.; Liu, J. C.; Huang, C. D.; Zhao, K.; Zhao, Z. L.; Wang, X. D.; Li, F. X. Sci. Adv. 2020, 6, eaaz9339.
16. [16]
  Tomkins, P.; Ranocchiari, M.; van Bokhoven, J. A. Acc. Chem. Res. 2017, 50, 418. doi: 10.1021/acs.accounts.6b00534
17. [17]
  Groothaert, M. H.; Smeets, P. J.; Sels, B. F.; Jacobs, P. A.; Schoonheydt, R. A. J. Am. Chem. Soc. 2005, 127, 1394. doi: 10.1021/ja047158u
18. [18]
  Cheng, Z.; Baser, D. S.; Nadgouda, S. G.; Qin, L.; Fan, J. A.; Fan, L. S. ACS Energy Lett. 2018, 3, 1730. doi: 10.1021/acsenergylett.8b00851
19. [19]
  Huang, C. D.; Wu, J.; Chen, Y. T.; Tian, M.; Rykov, A. I.; Hou, B. L.; Lin, J.; Chang, C. R.; Pan, X. L.; Wang, J. H.; Wang, A. Q.; Wang, X. D. Commun. Chem. 2018, 1, 55. doi: 10.1038/s42004-018-0050-y
20. [20]
  Liu, Y.; Qin, L.; Cheng, Z.; Goetze, J. W.; Kong, F. H.; Fan, J. A.; Fan, L. S. Nat. Commun. 2019, 10, 6. doi: 10.1038/s41467-018-07858-8
21. [21]
  Xu, B. J.; Bhawe, Y.; Davis, M. E. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 9260. doi: 10.1073/pnas.1206407109
22. [22]
  Abanades, S.; Flamant, G. Solar Energy 2006, 80, 1611. doi: 10.1016/j.solener.2005.12.005
23. [23]
  Zhu, X.; Imtiaz, Q.; Donat, F.; Muller, C. R.; Li, F. X. Energy Environ. Sci. 2020, 13, 772. doi: 10.1039/C9EE03793D
24. [24]
  Duan, Y. F.; Chen, C. Z.; Zhang, J. S.; Wang, X. H.; Wei, J. J. Sci. China Chem. 2020, 50, 337(in Chinese).
25. [25]
  Jennings, J. R. Catalytic ammonia synthesis:Fundamentals and practice, Plenum Press, New York, 1991.
26. [26]
  Frank, A. R. Trans. Faraday Soc. 1908, 4, 099. doi: 10.1039/tf9080400099
27. [27]
  Michalsky, R.; Pfromm, P. H. AlChE J. 2012, 58, 3203. doi: 10.1002/aic.13717
28. [28]
  Haber, F.; van Oordt, G. Z. Anorg. Chem. 1905, 44, 341. doi: 10.1002/zaac.19050440122
29. [29]
  Chen, J. G.; Crooks, R. M.; Seefeldt, L. C.; Bren, K. L.; Bullock, R. M.; Darensbourg, M. Y.; Holland, P. L.; Hoffman, B.; Janik, M. J.; Jones, A. K.; Kanatzidis, M. G.; King, P.; Lancaster, K. M.; Lymar, S. V.; Pfromm, P.; Schneider, W. F.; Schrock, R. R. Science 2018, 360, eaar6611.
30. [30]
  Galvez, M. E.; Halmann, M.; Steinfeld, A. Ind. Eng. Chem. Res. 2007, 46, 2042. doi: 10.1021/ie061550u
31. [31]
  Galvez, M. E.; Frei, A.; Halmann, M.; Steinfeld, A. Ind. Eng. Chem. Res. 2007, 46, 2047. doi: 10.1021/ie061551m
32. [32]
  Molisani, A. L.; Yoshimura, H. N. Mater. Res. Bull. 2010, 45, 733. doi: 10.1016/j.materresbull.2010.02.012
33. [33]
  Wu, Y.; Jiang, G. D.; Zhang, H. B.; Sun, Z.; Gao, Y.; Chen, X. P.; Liu, H. Z.; Tian, H. J.; Lai, Q. H.; Fan, M. H.; Liu, D. Chem. Commun. 2017, 53, 10664. doi: 10.1039/C7CC04742H
34. [34]
  Gao, Y.; Wu, Y.; Zhang, Q.; Chen, X. P.; Jiang, G. D.; Liu, D. Int. J. Hydrogen Energy 2018, 43, 16589. doi: 10.1016/j.ijhydene.2018.07.042
35. [35]
  Wu, Y.; Gao, Y.; Zhang, Q.; Cai, T.; Chen, X.; Liu, D.; Fan, M. Fuel 2020, 264, 116821. doi: 10.1016/j.fuel.2019.116821
36. [36]
  Zhang, Q.; Wu, Y.; Gao, Y.; Chen, X.; Liu, D.; Fan, M. Int. J. Hydrogen Energy 2020, 45, 9903. doi: 10.1016/j.ijhydene.2020.01.172
37. [37]
  Michalsky, R.; Pfromm, P. H. Solar Energy 2011, 85, 2642. doi: 10.1016/j.solener.2011.08.005
38. [38]
  Michalsky, R.; Pfromm, P. H. J. Phys. Chem. C 2012, 116, 23243. doi: 10.1021/jp307382r
39. [39]
  Michalsky, R.; Parman, B. J.; Amanor-Boadu, V.; Pfromm, P. H. Energy 2012, 42, 251. doi: 10.1016/j.energy.2012.03.062
40. [40]
  Heidlage, M. G.; Kezar, E. A.; Snow, K. C.; Pfromm, P. H. Ind. Eng. Chem. Res. 2017, 56, 14014. doi: 10.1021/acs.iecr.7b03173
41. [41]
  Medford, A. J.; Vojvodic, A.; Hummelshoj, J. S.; Voss, J.; Abild-Pedersen, F.; Studt, F.; Bligaard, T.; Nilsson, A.; Norskov, J. K. J. Catal. 2015, 328, 36. doi: 10.1016/j.jcat.2014.12.033
42. [42]
  Appl, M. Ammonia:Principles and industrial practice, Wiley-VCH, Weinheim, 1999.
43. [43]
  Michalsky, R.; Avram, A. M.; Peterson, B. A.; Pfromm, P. H.; Peterson, A. A. Chem. Sci. 2015, 6, 3965. doi: 10.1039/C5SC00789E
44. [44]
  Laassiri, S.; Zeinalipour-Yazdi, C. D.; Catlow, C. R. A.; Hargreaves, J. S. J. Appl. Catal. B 2018, 223, 60. doi: 10.1016/j.apcatb.2017.04.073
45. [45]
  Michalsky, R.; Pfromm, P. H.; Steinfeld, A. Interface Focus 2015, 5, 20140084. doi: 10.1098/rsfs.2014.0084
46. [46]
  Shan, N.; Chikan, V.; Pfromm, P.; Liu, B. J. Phys. Chem. C 2018, 122, 6109. doi: 10.1021/acs.jpcc.7b12569
47. [47]
  Shan, N. N.; Huang, C. R.; Lee, R. T.; Manavi, N.; Xu, L. B.; Chikan, V.; Pfromm, P. H.; Liu, B. ChemCatChem 2020, 12, 2233. doi: 10.1002/cctc.201902383
48. [48]
  Jacobsen, C. J. H. Chem. Commun. 2000, 1057.
49. [49]
  Jacobsen, C. J. H.; Dahl, S.; Clausen, B. S.; Bahn, S.; Logadottir, A.; Norskov, J. K. J. Am. Chem. Soc. 2001, 123, 8404. doi: 10.1021/ja010963d
50. [50]
  Kojima, R.; Aika, K. Chem. Lett. 2000, 514.
51. [51]
  McKay, D.; Gregory, D. H.; Hargreaves, J. S. J.; Hunter, S. M.; Sun, X. Chem. Commun. 2007, 3051.
52. [52]
  Hunter, S. M.; McKay, D.; Smith, R. J.; Hargreaves, J. S. J.; Gregory, D. H. Chem. Mater. 2010, 22, 2898. doi: 10.1021/cm100208a
53. [53]
  Hunter, S. M.; Gregory, D. H.; Hargreaves, J. S. J.; Richard, M.; Duprez, D.; Bion, N. ACS Catal. 2013, 3, 1719. doi: 10.1021/cs400336z
54. [54]
  Zeinalipour-Yazdi, C. D.; Hargreaves, J. S. J.; Catlow, C. R. A. J. Phys. Chem. C 2015, 119, 28368. doi: 10.1021/acs.jpcc.5b06811
55. [55]
  Alexander, A. M.; Hargreaves, J. S. J.; Mitchell, C. Top. Catal. 2012, 55, 1046. doi: 10.1007/s11244-012-9890-3
56. [56]
  Alexander, A. M.; Hargreaves, J. S. J.; Mitchell, C. Top. Catal. 2013, 56, 1963. doi: 10.1007/s11244-013-0133-z
57. [57]
  Roy, D.; Navarro-Vazquez, A.; Schleyer, P. V. R. J. Am. Chem. Soc. 2009, 131, 13045. doi: 10.1021/ja902980j
58. [58]
  Swearer, D. F.; Knowles, N. R.; Everitt, H. O.; Halas, N. J. ACS Energy Lett. 2019, 4, 1505. doi: 10.1021/acsenergylett.9b00860
59. [59]
  McEnaney, J. M.; Singh, A. R.; Schwalbe, J. A.; Kibsgaard, J.; Lin, J. C.; Cargnello, M.; Jaramillo, T. F.; Nrskov, J. K. Energy Environ. Sci. 2017, 10, 1621. doi: 10.1039/C7EE01126A
60. [60]
  Goshome, K.; Miyaoka, H.; Yamamoto, H.; Ichikawa, T.; Ichikawa, T.; Kojima, Y. Mater. Trans. 2015, 56, 410. doi: 10.2320/matertrans.M2014382
61. [61]
  Yamaguchi, S.; Ichikawa, T.; Wang, Y. M.; Nakagawa, Y.; Isobe, S.; Kojima, Y.; Miyaoka, H. ACS Omega 2017, 2, 1081. doi: 10.1021/acsomega.6b00498
62. [62]
  Yamaguchi, T.; Shinzato, K.; Yamamoto, K.; Wang, Y.; Nakagawa, Y.; Isobe, S.; Ichikawa, T.; Miyaoka, H.; Ichikawa, T. Int. J. Hydrogen Energy 2020, 45, 6806. doi: 10.1016/j.ijhydene.2019.12.190
63. [63]
  Gao, W. B.; Guo, J. P.; Chen, P. Chin. J. Chem. 2019, 37, 442. doi: 10.1002/cjoc.201800586
64. [64]
  Veser, G. Nat. Energy 2018, 3, 1025. doi: 10.1038/s41560-018-0293-y
65. [65]
  Hagen, S.; Barfod, R.; Fehrmann, R.; Jacobsen, C. J. H.; Teunissen, H. T.; Chorkendorff, I. J. Catal. 2003, 214, 327. doi: 10.1016/S0021-9517(02)00182-3
66. [66]
  Liu, T.; Temprano, I.; Jenkins, S. J.; King, D. A. J. Chem. Phys. 2013, 139, 184708
67. [67]
  Vojvodic, A.; Medford, A. J.; Studt, F.; Abild-Pedersen, F.; Khan, T. S.; Bligaard, T.; Norskov, J. K. Chem. Phys. Lett. 2014, 598, 108. doi: 10.1016/j.cplett.2014.03.003
68. [68]
  Michalsky, R.; Steinfeld, A. Catal. Today 2017, 286, 124. doi: 10.1016/j.cattod.2016.09.023
69. [69]
  Bartel, C. J.; Rumptz, J. R.; Weimer, A. W.; Holder, A. M.; Musgrave, C. B. ACS Appl. Mater. Interfaces 2019, 11, 24850. doi: 10.1021/acsami.9b01242
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