Citation: Feng Sheng, Gao Wenbo, Cao Hujun, Guo Jianping, Chen Ping. Advances in the Chemical Looping Ammonia Synthesis[J]. Acta Chimica Sinica, ;2020, 78(9): 916-927. doi: 10.6023/A20060207 shu

Advances in the Chemical Looping Ammonia Synthesis

Feng Sheng ^a,b ,
Gao Wenbo ^a ,
Cao Hujun ^a ,
Guo Jianping ^a,, ,
Chen Ping ^a,b

a.
Dalian National Laboratory for Clean Energy, Collaborative Innovation Center of Chemistry for Energy Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
b.
Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, China

Corresponding author: Guo Jianping, guojianping@dicp.ac.cn
Received Date: 4 June 2020
Available Online: 9 July 2020
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21872137, 21922205) and Youth Innovation Promotion Association Chinese Academy of Sciences (No. 2018213).the National Natural Science Foundation of China 21922205Youth Innovation Promotion Association Chinese Academy of Sciences 2018213the National Natural Science Foundation of China 21872137

Figures(9)

Ammonia is not only the main raw material of nitrogen fertilizer, but also a promising energy carrier for the storage and utilization of renewable energy. The fossil fuel-based Haber-Bosch ammonia synthesis industry is an energy-consuming and high CO₂-emission process. For the sustainable growth of human society, it is critically important to develop "green" ammonia synthesis processes driven by renewable energies. This scenario motivates growing interests on ammonia synthesis via heterogeneous catalysis, electro-chemical and photo-chemical routes as well as chemical looping process. Chemical looping ammonia synthesis (CLAS) process involves a series of individual reactions which produce ammonia in a distinctly different manner to the catalytic process. The CLAS could be operated under ambient pressure, and the switching on/off operation is flexible. Therefore, CLAS may be more amenable to variable and intermittent operation compared to the conventional catalytic process. More importantly, the competitive adsorption of N₂ and H₂ or H₂O in the catalytic process can be circumvented to a great extent, which opens new opportunities for the design and development of nitrogen carriers especially for low-temperature ammonia production. Because of these unique features, the application of chemical looping technology for ammonia synthesis has been received increasing attention in recent years. The development of high-efficiency nitrogen carriers is the key component for the implementation of CLAS. A wide range of materials including metal nitrides, metal imides, nitride-hydrides and oxynitrides have been evaluated as nitrogen carriers for CLAS. The knowledge accumulated during the past decade will no doubt beneficial for the further optimization and development of nitrogen carriers. This article reviews the research progress in the field of chemical looping ammonia synthesis in recent years, with the focuses on the materials development of nitrogen carriers in CLAS. Furthermore, the challenges and future directions of CLAS are also discussed. With the development of nitrogen carriers and process design, CLAS would potentially play an important role in the green ammonia synthesis as well as the future energy system.
- ammonia synthesis,
- chemical looping,
- nitrogen carrier,
- nitride,
- imide
1. [1]
  Liu, H. Z. Chem. Ind. Eng. Prog. 2013, 32, 1995(in Chinese).
2. [2]
  Klerke, A.; Christensen, C. H.; Norskov, J. K.; Vegge, T. J. Mater. Chem. 2008, 18, 2304. doi: 10.1039/b720020j
3. [3]
  Guo, J. P.; Chen, P. Chem 2017, 3, 709. doi: 10.1016/j.chempr.2017.10.004
4. [4]
  Valera-Medina, A.; Xiao, H.; Owen-Jones, M.; David, W. I. F.; Bowen, P. J. Prog. Energy Combust. Sci. 2018, 69, 63. doi: 10.1016/j.pecs.2018.07.001
5. [5]
  Smith, C.; Hill, A. K.; Torrente-Murciano, L. Energy Environ. Sci. 2020, 13, 331. doi: 10.1039/C9EE02873K
6. [6]
  Erisman, J. W.; Sutton, M. A.; Galloway, J.; Klimont, Z.; Winiwarter, W. Nat. Geosci. 2008, 1, 636. doi: 10.1038/ngeo325
7. [7]
  Wang, Q. R.; Guo, J. P.; Chen, P. J. Energy Chem. 2019, 36, 25(in Chinese).
8. [8]
  Norskov, J. K.; Chen, J. G. Sustainable Ammonia Synthesis, US Department of Energy, 2016.
9. [9]
  Zeng, L.; Cheng, Z.; Fan, J. A.; Fan, L. S.; Gong, J. L. Nat. Rev. Chem. 2018, 2, 349. doi: 10.1038/s41570-018-0046-2
10. [10]
  Gao, W. B.; Guo, J. P.; Wang, P. K.; Wang, Q. R.; Chang, F.; Pei, Q. J.; Zhang, W. J.; Liu, L.; Chen, P. Nat. Energy 2018, 3, 1067. doi: 10.1038/s41560-018-0268-z
11. [11]
  Koerts, T.; Vansanten, R. A. J. C. S. Chem. Commun. 1991, 1281.
12. [12]
  Wang, Q. R.; Guo, J. P.; Chen, P. Joule 2020, 4, 705. doi: 10.1016/j.joule.2020.02.008
13. [13]
  Zeng, L.; Luo, S. W.; Li, F. X.; Fan, L. S. Sci. China Chem. 2012, 42, 260(in Chinese).
14. [14]
  Chen, S.; Zeng, L.; Mu, R. T.; Xiong, C. Y.; Zhao, Z. J.; Zhao, C. J.; Pei, C. L.; Peng, L. M.; Luo, J.; Fan, L. S.; Gong, J. L. J. Am. Chem. Soc. 2019, 141, 18653. doi: 10.1021/jacs.9b09235
15. [15]
  Gao, Y. F.; Wang, X. J.; Liu, J. C.; Huang, C. D.; Zhao, K.; Zhao, Z. L.; Wang, X. D.; Li, F. X. Sci. Adv. 2020, 6, eaaz9339.
16. [16]
  Tomkins, P.; Ranocchiari, M.; van Bokhoven, J. A. Acc. Chem. Res. 2017, 50, 418. doi: 10.1021/acs.accounts.6b00534
17. [17]
  Groothaert, M. H.; Smeets, P. J.; Sels, B. F.; Jacobs, P. A.; Schoonheydt, R. A. J. Am. Chem. Soc. 2005, 127, 1394. doi: 10.1021/ja047158u
18. [18]
  Cheng, Z.; Baser, D. S.; Nadgouda, S. G.; Qin, L.; Fan, J. A.; Fan, L. S. ACS Energy Lett. 2018, 3, 1730. doi: 10.1021/acsenergylett.8b00851
19. [19]
  Huang, C. D.; Wu, J.; Chen, Y. T.; Tian, M.; Rykov, A. I.; Hou, B. L.; Lin, J.; Chang, C. R.; Pan, X. L.; Wang, J. H.; Wang, A. Q.; Wang, X. D. Commun. Chem. 2018, 1, 55. doi: 10.1038/s42004-018-0050-y
20. [20]
  Liu, Y.; Qin, L.; Cheng, Z.; Goetze, J. W.; Kong, F. H.; Fan, J. A.; Fan, L. S. Nat. Commun. 2019, 10, 6. doi: 10.1038/s41467-018-07858-8
21. [21]
  Xu, B. J.; Bhawe, Y.; Davis, M. E. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 9260. doi: 10.1073/pnas.1206407109
22. [22]
  Abanades, S.; Flamant, G. Solar Energy 2006, 80, 1611. doi: 10.1016/j.solener.2005.12.005
23. [23]
  Zhu, X.; Imtiaz, Q.; Donat, F.; Muller, C. R.; Li, F. X. Energy Environ. Sci. 2020, 13, 772. doi: 10.1039/C9EE03793D
24. [24]
  Duan, Y. F.; Chen, C. Z.; Zhang, J. S.; Wang, X. H.; Wei, J. J. Sci. China Chem. 2020, 50, 337(in Chinese).
25. [25]
  Jennings, J. R. Catalytic ammonia synthesis:Fundamentals and practice, Plenum Press, New York, 1991.
26. [26]
  Frank, A. R. Trans. Faraday Soc. 1908, 4, 099. doi: 10.1039/tf9080400099
27. [27]
  Michalsky, R.; Pfromm, P. H. AlChE J. 2012, 58, 3203. doi: 10.1002/aic.13717
28. [28]
  Haber, F.; van Oordt, G. Z. Anorg. Chem. 1905, 44, 341. doi: 10.1002/zaac.19050440122
29. [29]
  Chen, J. G.; Crooks, R. M.; Seefeldt, L. C.; Bren, K. L.; Bullock, R. M.; Darensbourg, M. Y.; Holland, P. L.; Hoffman, B.; Janik, M. J.; Jones, A. K.; Kanatzidis, M. G.; King, P.; Lancaster, K. M.; Lymar, S. V.; Pfromm, P.; Schneider, W. F.; Schrock, R. R. Science 2018, 360, eaar6611.
30. [30]
  Galvez, M. E.; Halmann, M.; Steinfeld, A. Ind. Eng. Chem. Res. 2007, 46, 2042. doi: 10.1021/ie061550u
31. [31]
  Galvez, M. E.; Frei, A.; Halmann, M.; Steinfeld, A. Ind. Eng. Chem. Res. 2007, 46, 2047. doi: 10.1021/ie061551m
32. [32]
  Molisani, A. L.; Yoshimura, H. N. Mater. Res. Bull. 2010, 45, 733. doi: 10.1016/j.materresbull.2010.02.012
33. [33]
  Wu, Y.; Jiang, G. D.; Zhang, H. B.; Sun, Z.; Gao, Y.; Chen, X. P.; Liu, H. Z.; Tian, H. J.; Lai, Q. H.; Fan, M. H.; Liu, D. Chem. Commun. 2017, 53, 10664. doi: 10.1039/C7CC04742H
34. [34]
  Gao, Y.; Wu, Y.; Zhang, Q.; Chen, X. P.; Jiang, G. D.; Liu, D. Int. J. Hydrogen Energy 2018, 43, 16589. doi: 10.1016/j.ijhydene.2018.07.042
35. [35]
  Wu, Y.; Gao, Y.; Zhang, Q.; Cai, T.; Chen, X.; Liu, D.; Fan, M. Fuel 2020, 264, 116821. doi: 10.1016/j.fuel.2019.116821
36. [36]
  Zhang, Q.; Wu, Y.; Gao, Y.; Chen, X.; Liu, D.; Fan, M. Int. J. Hydrogen Energy 2020, 45, 9903. doi: 10.1016/j.ijhydene.2020.01.172
37. [37]
  Michalsky, R.; Pfromm, P. H. Solar Energy 2011, 85, 2642. doi: 10.1016/j.solener.2011.08.005
38. [38]
  Michalsky, R.; Pfromm, P. H. J. Phys. Chem. C 2012, 116, 23243. doi: 10.1021/jp307382r
39. [39]
  Michalsky, R.; Parman, B. J.; Amanor-Boadu, V.; Pfromm, P. H. Energy 2012, 42, 251. doi: 10.1016/j.energy.2012.03.062
40. [40]
  Heidlage, M. G.; Kezar, E. A.; Snow, K. C.; Pfromm, P. H. Ind. Eng. Chem. Res. 2017, 56, 14014. doi: 10.1021/acs.iecr.7b03173
41. [41]
  Medford, A. J.; Vojvodic, A.; Hummelshoj, J. S.; Voss, J.; Abild-Pedersen, F.; Studt, F.; Bligaard, T.; Nilsson, A.; Norskov, J. K. J. Catal. 2015, 328, 36. doi: 10.1016/j.jcat.2014.12.033
42. [42]
  Appl, M. Ammonia:Principles and industrial practice, Wiley-VCH, Weinheim, 1999.
43. [43]
  Michalsky, R.; Avram, A. M.; Peterson, B. A.; Pfromm, P. H.; Peterson, A. A. Chem. Sci. 2015, 6, 3965. doi: 10.1039/C5SC00789E
44. [44]
  Laassiri, S.; Zeinalipour-Yazdi, C. D.; Catlow, C. R. A.; Hargreaves, J. S. J. Appl. Catal. B 2018, 223, 60. doi: 10.1016/j.apcatb.2017.04.073
45. [45]
  Michalsky, R.; Pfromm, P. H.; Steinfeld, A. Interface Focus 2015, 5, 20140084. doi: 10.1098/rsfs.2014.0084
46. [46]
  Shan, N.; Chikan, V.; Pfromm, P.; Liu, B. J. Phys. Chem. C 2018, 122, 6109. doi: 10.1021/acs.jpcc.7b12569
47. [47]
  Shan, N. N.; Huang, C. R.; Lee, R. T.; Manavi, N.; Xu, L. B.; Chikan, V.; Pfromm, P. H.; Liu, B. ChemCatChem 2020, 12, 2233. doi: 10.1002/cctc.201902383
48. [48]
  Jacobsen, C. J. H. Chem. Commun. 2000, 1057.
49. [49]
  Jacobsen, C. J. H.; Dahl, S.; Clausen, B. S.; Bahn, S.; Logadottir, A.; Norskov, J. K. J. Am. Chem. Soc. 2001, 123, 8404. doi: 10.1021/ja010963d
50. [50]
  Kojima, R.; Aika, K. Chem. Lett. 2000, 514.
51. [51]
  McKay, D.; Gregory, D. H.; Hargreaves, J. S. J.; Hunter, S. M.; Sun, X. Chem. Commun. 2007, 3051.
52. [52]
  Hunter, S. M.; McKay, D.; Smith, R. J.; Hargreaves, J. S. J.; Gregory, D. H. Chem. Mater. 2010, 22, 2898. doi: 10.1021/cm100208a
53. [53]
  Hunter, S. M.; Gregory, D. H.; Hargreaves, J. S. J.; Richard, M.; Duprez, D.; Bion, N. ACS Catal. 2013, 3, 1719. doi: 10.1021/cs400336z
54. [54]
  Zeinalipour-Yazdi, C. D.; Hargreaves, J. S. J.; Catlow, C. R. A. J. Phys. Chem. C 2015, 119, 28368. doi: 10.1021/acs.jpcc.5b06811
55. [55]
  Alexander, A. M.; Hargreaves, J. S. J.; Mitchell, C. Top. Catal. 2012, 55, 1046. doi: 10.1007/s11244-012-9890-3
56. [56]
  Alexander, A. M.; Hargreaves, J. S. J.; Mitchell, C. Top. Catal. 2013, 56, 1963. doi: 10.1007/s11244-013-0133-z
57. [57]
  Roy, D.; Navarro-Vazquez, A.; Schleyer, P. V. R. J. Am. Chem. Soc. 2009, 131, 13045. doi: 10.1021/ja902980j
58. [58]
  Swearer, D. F.; Knowles, N. R.; Everitt, H. O.; Halas, N. J. ACS Energy Lett. 2019, 4, 1505. doi: 10.1021/acsenergylett.9b00860
59. [59]
  McEnaney, J. M.; Singh, A. R.; Schwalbe, J. A.; Kibsgaard, J.; Lin, J. C.; Cargnello, M.; Jaramillo, T. F.; Nrskov, J. K. Energy Environ. Sci. 2017, 10, 1621. doi: 10.1039/C7EE01126A
60. [60]
  Goshome, K.; Miyaoka, H.; Yamamoto, H.; Ichikawa, T.; Ichikawa, T.; Kojima, Y. Mater. Trans. 2015, 56, 410. doi: 10.2320/matertrans.M2014382
61. [61]
  Yamaguchi, S.; Ichikawa, T.; Wang, Y. M.; Nakagawa, Y.; Isobe, S.; Kojima, Y.; Miyaoka, H. ACS Omega 2017, 2, 1081. doi: 10.1021/acsomega.6b00498
62. [62]
  Yamaguchi, T.; Shinzato, K.; Yamamoto, K.; Wang, Y.; Nakagawa, Y.; Isobe, S.; Ichikawa, T.; Miyaoka, H.; Ichikawa, T. Int. J. Hydrogen Energy 2020, 45, 6806. doi: 10.1016/j.ijhydene.2019.12.190
63. [63]
  Gao, W. B.; Guo, J. P.; Chen, P. Chin. J. Chem. 2019, 37, 442. doi: 10.1002/cjoc.201800586
64. [64]
  Veser, G. Nat. Energy 2018, 3, 1025. doi: 10.1038/s41560-018-0293-y
65. [65]
  Hagen, S.; Barfod, R.; Fehrmann, R.; Jacobsen, C. J. H.; Teunissen, H. T.; Chorkendorff, I. J. Catal. 2003, 214, 327. doi: 10.1016/S0021-9517(02)00182-3
66. [66]
  Liu, T.; Temprano, I.; Jenkins, S. J.; King, D. A. J. Chem. Phys. 2013, 139, 184708
67. [67]
  Vojvodic, A.; Medford, A. J.; Studt, F.; Abild-Pedersen, F.; Khan, T. S.; Bligaard, T.; Norskov, J. K. Chem. Phys. Lett. 2014, 598, 108. doi: 10.1016/j.cplett.2014.03.003
68. [68]
  Michalsky, R.; Steinfeld, A. Catal. Today 2017, 286, 124. doi: 10.1016/j.cattod.2016.09.023
69. [69]
  Bartel, C. J.; Rumptz, J. R.; Weimer, A. W.; Holder, A. M.; Musgrave, C. B. ACS Appl. Mater. Interfaces 2019, 11, 24850. doi: 10.1021/acsami.9b01242
1. [1]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
2. [2]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
3. [3]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
4. [4]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
5. [5]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
6. [6]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
7. [7]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
8. [8]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
9. [9]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
10. [10]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
11. [11]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
12. [12]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
13. [13]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
14. [14]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
15. [15]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
16. [16]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
17. [17]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
18. [18]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
19. [19]
  Fei Liu , Dong-Yang Zhao , Kai Sun , Ting-Ting Yu , Xin Wang . Comprehensive Experimental Design for Photochemical Synthesis, Analysis, and Characterization of Seleno-Containing Medium-Sized N-Heterocycles. University Chemistry, 2024, 39(3): 369-375. doi: 10.3866/PKU.DXHX202309047
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(110)
Abstract views(5114)
HTML views(1159)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142