Citation: Yang Jing-Liang, Yang Wei-Min, Lin Jia-Sheng, Wang An, Xu Juan, Li Jian-Feng. Plasmon-induced Hot Electrons Influenced by Electric Field[J]. Acta Chimica Sinica, ;2020, 78(7): 670-674. doi: 10.6023/A20050150 shu

Plasmon-induced Hot Electrons Influenced by Electric Field

a.
College of Physical Science and Technology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
b.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000

Corresponding author: Xu Juan, xjzhejiang.2008@163.com Li Jian-Feng, Li@xmu.edu.cn
Received Date: 8 May 2020
Available Online: 16 June 2020
Fund Project: the National Natural Science Foundation of China 21925404Project supported by the National Natural Science Foundation of China (Nos. 21925404, 21703180, 21775127)the National Natural Science Foundation of China 21703180the National Natural Science Foundation of China 21775127

Figures(4)

The plasmonic nanostructures have attracted particular attention due to their superior ability to capture and modulate light in ultraviolet-visible and near-infrared range, by changing the size, morphology, and the composition of nanostructures. Especially in plasmon-driven chemical reactions, plasmon-induced hot electrons (HEs) can be transferred from the surface of metal nanostructures to the lowest unoccupied molecular orbital (LUMO) of the adsorbate molecule or the conduction band of the semiconductor to achieve catalytic reaction. Therefore, how to improve the excitation efficiency of HEs has become a key problem to be solved urgently. In this paper, 120 nm Ag nanoparticles (NPs) were synthesized by seed growth method using 45 nm Au as seed. Subsequently, (3-aminopropyl)trimethoxysilane as coupling agent and sodium silicate as the silicon source were used to prepare the shell-isolated Ag NPs with 2~3 nm SiO₂ shell (Ag SHINs). Finally, Ag SHINs were modified with poly(allylamine hydrochloride), then small Au (ca. 15 nm) as satellites were electrostatic self-assembled onto the surface of Ag SHINs to form a 3D Ag SHINs-Au superstructure. Using p-aminothiophenol (pATP) as probe molecule, in-situ surface-enhanced Raman spectroscopy (SERS) was employed to real-timely monitor the catalytic reaction processes from pATP to DMAB, using 532, 638, and 785 nm lasers for excitation, respectively. The results showed that the highest conversion efficiency was achieved when 638 nm laser was applied. In addition, the reaction rate under 785 nm excitation was faster than that under exposure to 532 nm laser. Then, we used three dimensional (3D) finite-difference time-domain (FDTD) to simulate the electric field distribution of 3D Ag SHINs-Au superstructure. The electric field simulation results are consistent with the experimental results. In consequence, the stronger the electric field intensity, the higher the HEs excitation efficiency. On the other hand, the intra-band transitions produce HEs more efficiently than inter-band transitions. Therefore, this study is helpful for understanding how the electric field intensity affect the excitation efficiency of the HEs.
- SERS,
- plasmonics,
- hot electrons,
- electric field intensity,
- p-aminothiophenol
1. [1]
  Moskovits, M. Rev. Mod. Phys. 1985, 57, 783. doi: 10.1103/RevModPhys.57.783
2. [2]
  Nie, S.; Emory, S. R. Science 1997, 275, 1102. doi: 10.1126/science.275.5303.1102
3. [3]
  Gersten, J. I.; Birke, R. L.; Lombardi, J. R. Phys. Rev. Lett. 1979, 43, 147. doi: 10.1103/PhysRevLett.43.147
4. [4]
  Li, C. Y.; Le, J. B.; Wang, Y. H.; Chen, S.; Yang, Z. L.; Li, J. F.; Cheng, J.; Tian, Z. Q. Nat. Mater. 2019, 18, 697. doi: 10.1038/s41563-019-0356-x
5. [5]
  Dong, J. C.; Zhang, X. G.; Briega-Martos, V.; Jin, X.; Yang, J.; Chen, S.; Yang, Z. L.; Wu, D. Y.; Feliu, J. M.; Williams, C. T.; Tian, Z. Q.; Li, J. F. Nat. Energy 2019, 4, 60. doi: 10.1038/s41560-018-0292-z
6. [6]
  Fleischmann, M.; Hendra, P. J.; McQuillan, A. J. Chem. Phys. Lett. 1974, 26, 163. doi: 10.1016/0009-2614(74)85388-1
7. [7]
  Kozich, V.; Werncke, W. J. Phys. Chem. C 2010, 114, 10484.
8. [8]
  Li, J. F.; Huang, Y. F.; Ding, Y.; Yang, Z. L.; Li, S. B.; Zhou, X. S.; Fan, F. R.; Zhang, W.; Zhou, Z. Y.; Wu, D. Y.; Ren, B.; Wang, Z. L.; Tian, Z. Q. Nature 2010, 464, 392. doi: 10.1038/nature08907
9. [9]
  Gao, Z. G.; Zhen, T. T.; Deng, J.; Li, X. R.; Qu, Y. Y.; Lu, Y.; Liu, T. J.; Luo, Y.; Zhao, W. J.; Lin, B. C. Acta Chim. Sinica 2017, 75, 355(in Chinese). doi: 10.7503/cjcu20160572
10. [10]
  Zhang, H.; Wei, J.; Zhang, X. G.; Zhang, Y. J.; Radjenovica, P. M.; Wu, D. Y.; Pan, F.; Tian, Z. Q.; Li J. F. Chem 2020, 6, 1.
11. [11]
  Zuo, F. T.; Xu, W.; Zhao, A. W. Acta Chim. Sinica 2019, 77, 379(in Chinese). doi: 10.7503/cjcu20180485
12. [12]
  Avanesian, T.; Christopher, P. J. Phys. Chem. C 2014, 48, 28017.
13. [13]
  Wei, Q.; Wu, S.; Sun, Y. Adv. Mater. 2018, 48, e1802082.
14. [14]
  Besteiro, L. V.; Kong, X. T.; Wang, Z.; Hartland, G.; Govorov, A. O. ACS Photonics 2017, 11, 2759.
15. [15]
  Kazuma, E.; Kim, Y. Angew. Chem. Int. Ed. 2019, 15, 4800.
16. [16]
  Zhang, J.; Guan, M. X.; Lischner, J.; Meng, S.; Prezhdo, O. V. Nano Lett. 2019, 19, 3187. doi: 10.1021/acs.nanolett.9b00647
17. [17]
  Kim, M.; Lin, M.; Son, J.; Xu, H.; Nam, J. M. Adv. Opt. Mater. 2017, 15, 1700004.
18. [18]
  Peckus, D.; Rong, H.; Stankevičius, L.; Juodėnas, M.; Tamulevičius, S.; Tamulevičius, T.; Henzie, J. J. Phys. Chem. C 2017, 43, 24159.
19. [19]
  Yang, J. L.; Xu, J.; Ren, H.; Sun, L.; Xu, Q. C.; Zhang, H.; Li, J. F.; Tian, Z. Q. Nanoscale 2017, 9, 6254. doi: 10.1039/C7NR00655A
1. [1]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
2. [2]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
3. [3]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
4. [4]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
5. [5]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
6. [6]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
7. [7]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
8. [8]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
9. [9]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
10. [10]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
13. [13]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
14. [14]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
15. [15]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
16. [16]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
17. [17]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
18. [18]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
19. [19]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
20. [20]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032

Get Citation

PDF

XML

Metrics

PDF Downloads(23)
Abstract views(873)
HTML views(129)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142