Citation: Zhu Qingqing, Song Xiaojun, Deng Zhaoxiang. Tunable Charge Transfer Plasmon at Gold/Copper Heterointerface[J]. Acta Chimica Sinica, ;2020, 78(7): 675-679. doi: 10.6023/A20050145 shu

Tunable Charge Transfer Plasmon at Gold/Copper Heterointerface

CAS Key Laboratory of Soft Matter Chemistry, Hefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Deng Zhaoxiang, zhxdeng@ustc.edu.cn
Received Date: 19 May 2020
Available Online: 29 June 2020
Fund Project: the National Natural Science Foundation of China 21425521Project supported by the National Key Research and Development Program of China (Nos. 2016YFA0201300, 2018YFA0702001) and the National Natural Science Foundation of China (Nos. 21425521, 21972130, 21521001)the National Natural Science Foundation of China 21521001the National Key Research and Development Program of China 2016YFA0201300the National Natural Science Foundation of China 21972130the National Key Research and Development Program of China 2018YFA0702001

Figures(4)

Metal nanostructures with localized surface plasmon resonance (LSPR) have attracted great attention in catalysis, sensing, nanooptics, and nanomedicine. Charge transfer plasmon (CTP) is a LSPR mode that strongly depends on a conductive junction between metallic nanounits. Benefitting from the charge transfer junction, CTP provides a facile way to generate widely tunable LSPR with highly localized/enhanced light magnetic field and photothermal effect. The limited availability of highly tunable CTP structures and their fabrication techniques hinders a further pursuit of their functions and applications. In response to this situation, the present work aims at developing a simple while highly efficient synthetic route to width-adjustable Au/Cu heterojunctions capable of evoking tunable CTP behaviors. The strategy relies on a non-specific surface adsorption of low-cost, naturally occurred fish sperm DNA on a gold nanoseed to control heterogeneous copper nucleation. Such a process offers a chance to tailor the contact area between the gold and copper nano-domains in the bimetallic structure. Highly tunable CTP resonance from visible to near-infrared region is then realizable on the basis of this method. Experimental and calculated extinction spectra consistently reveal three key variables for the CTP structure, including the width of conductive junction and the sizes of gold and copper particles. These parameters are associated with DNA coverage, copper precursor concentration, and the synthetic conditions for gold nanoparticles, which allow for a CTP tuning from visible to near infrared wavelengths. By fully exploiting these highly controllable parameters, the maximally achievable CTP wavelength readily enters a near infrared Ⅱ domain. The resulting CTP signals have a red-shift of up to 750 nm relative to the 530~570 nm LSPR peaks of individual gold and copper nanoparticles, corresponding to a very narrow Au/Cu conductive contact of 11~13 nm in width. The role of nonspecific DNA adsorption in the above process proves unique (currently irreplaceable) compared to other molecular adsorbates. The easily tunable Au/Cu heterointerface paves a way to integrated CTP and catalytic/sensing functions in future research.
- charge transfer,
- interface,
- metal,
- dimerization,
- DNA
1. [1]
  Hutter, E.; Fendler, J. H. Adv. Mater. 2004, 16, 1685. doi: 10.1002/adma.200400271
2. [2]
  Halas, N. J.; Lal, S.; Chang, W. S.; Link, S.; Nordlander, P. Chem. Rev. 2011, 111, 3913. doi: 10.1021/cr200061k
3. [3]
  Nordlander, P.; Oubre, C.; Prodan, E.; Li, K.; Stockman, M. I. Nano Lett. 2004, 4, 899. doi: 10.1021/nl049681c
4. [4]
  Romero, I.; Aizpurua, J.; Bryant, G. W.; de Abajo, F. J. G. Opt. Express 2006, 14, 9988. doi: 10.1364/OE.14.009988
5. [5]
  Rechberger, W.; Hohenau, A.; Leitner, A.; Krenn, J. R.; Lamprecht, B.; Aussenegg, F. R. Opt. Commun. 2003, 220, 137. doi: 10.1016/S0030-4018(03)01357-9
6. [6]
  Savage, K. J.; Hawkeye, M. M.; Esteban, R.; Borisov, A. G.; Aizpurua, J.; Baumberg, J. J. Nature 2012, 491, 574. doi: 10.1038/nature11653
7. [7]
  Esteban, R.; Borisov, A. G.; Nordlander, P.; Aizpurua, J. Nat. Commun. 2012, 3, 825. doi: 10.1038/ncomms1806
8. [8]
  Wen, F. F.; Zhang, Y.; Gottheim, S.; King, N. S.; Zhang, Y.; Nordlander, P.; Halas, N. J. ACS Nano 2015, 9, 6428. doi: 10.1021/acsnano.5b02087
9. [9]
  Atay, T.; Song, J. H.; Nurmikko, A. V. Nano Lett. 2004, 4, 1627. doi: 10.1021/nl049215n
10. [10]
  Pérez-González, O.; Zabala, N.; Borisov, A. G.; Halas, N. J.; Nordlander, P.; Aizpurua, J. Nano Lett. 2010, 10, 3090. doi: 10.1021/nl1017173
11. [11]
  Grosjean, T.; Mivelle, M.; Baida, F. I.; Burr, G. W.; Fischer, U. C. Nano Lett. 2011, 11, 1009. doi: 10.1021/nl103817f
12. [12]
  Lim, B. K.; Kobayashi, H.; Yu, T.; Wang, J. G.; Kim, M. J.; Li, Z. Y.; Rycenga, M.; Xia, Y. N. J. Am. Chem. Soc. 2010, 132, 2506. doi: 10.1021/ja909787h
13. [13]
  Tao, Z. X.; Wu, Z. S.; Yuan, X. L.; Wu, Y. S.; Wang, H. L. ACS Catal. 2019, 9, 10894. doi: 10.1021/acscatal.9b03158
14. [14]
  Morales-Guio, C. G.; Cave, E. R.; Nitopi, S. A.; Feaster, J. T.; Wang, L.; Kuhl, K. P.; Jackson, A.; Johnson, N. C.; Abram, D. N.; Hatsukade, T.; Hahn, C.; Jaramillo, T. F. Nat. Catal. 2018, 1, 764. doi: 10.1038/s41929-018-0139-9
15. [15]
  Zhu, X. Z.; Yip, H. K.; Zhuo, X. L.; Jiang, R. B.; Chen, J. L.; Zhu, X.-M.; Yang, Z.; Wang, J. F. J. Am. Chem. Soc. 2017, 139, 13837. doi: 10.1021/jacs.7b07462
16. [16]
  Kortlever, R.; Peters, I.; Balemans, C.; Kas, R.; Kwon, Y.; Mul, G.; Koper, M. T. M. Chem. Commun. 2016, 52, 10229. doi: 10.1039/C6CC03717H
17. [17]
  Cai, Z.; Kuang, Y.; Luo, L.; Wang, L. R.; Sun, X. M. Acta Chim. Sinica 2013, 71, 1265(in Chinese).
18. [18]
  Liu, B. L.; Zhang, H. C.; Ding, Y. Chin. Chem. Lett. 2018, 29, 1725. doi: 10.1016/j.cclet.2018.12.006
19. [19]
  Huang, J.; Mensi, M.; Oveisi, E.; Mantella, V.; Buonsanti, R. J. Am. Chem. Soc. 2019, 141, 2490. doi: 10.1021/jacs.8b12381
20. [20]
  Huang, X.; Li, Y.; Zhou, H.; Zhong, X.; Duan, X.; Huang, Y. Chem. Eur. J. 2012, 18, 9505. doi: 10.1002/chem.201200817
21. [21]
  Wu, K. H.; Zhou, Y. W.; Ma, X. Y.; Ding, C.; Cai, W. B. Acta Chim. Sinica 2018, 76, 292(in Chinese). doi: 10.7503/cjcu20170465
22. [22]
  Xu, S. Y.; Liu, Z. H.; Zhang, H.; Yu, J. R. Acta Chim. Sinica 2019, 77, 427(in Chinese).
23. [23]
  Jung, H.; Cha, H.; Lee, D.; Yoon, S. ACS Nano 2015, 9, 12292. doi: 10.1021/acsnano.5b05568
24. [24]
  Scholl, J. A.; Garcia-Etxarri, A.; Koh, A. L.; Dionne, J. A. Nano Lett. 2013, 13, 564. doi: 10.1021/nl304078v
25. [25]
  Jones, M. R.; Osberg, K. D.; Macfarlane, R. J.; Langille, M. R.; Mirkin, C. A. Chem. Rev. 2011, 111, 3736. doi: 10.1021/cr1004452
26. [26]
  Lan, X.; Chen, Z.; Liu, B. J.; Ren, B.; Henzie, J.; Wang, Q. B. Small 2013, 9, 2308. doi: 10.1002/smll.201202503
27. [27]
  Zhong, Z. Y.; Patskovskyy, S.; Bouvrette, P.; Luong, J. H. T.; Gedanken, A. J. Phys. Chem. B 2004, 108, 4046. doi: 10.1021/jp037056a
28. [28]
  Maye, M. M.; Nykypanchuk, D.; Cuisinier, M.; van der Lelie, D.; Gang, O. Nat. Mater. 2009, 8, 388. doi: 10.1038/nmat2421
29. [29]
  Yu, H.; Man, T. T.; Ji, W.; Shi, L. L.; Wu, C. W.; Pei, H.; Zhang, C. Chin. Chem. Lett. 2019, 30, 175. doi: 10.1016/j.cclet.2018.04.020
30. [30]
  Kim, J.-Y.; Kotov, N. A. Chem. Mater. 2014, 26, 134. doi: 10.1021/cm402675k
31. [31]
  Li, Y. L.; Deng, Z. X. Acc. Chem. Res. 2019, 52, 3442. doi: 10.1021/acs.accounts.9b00463
32. [32]
  Song, L.; Deng, Z. X. ChemNanoMat 2017, 3, 698. doi: 10.1002/cnma.201700222
33. [33]
  Fang, L. L.; Wang, Y. L.; Liu, M.; Gong, M.; Xu, A.; Deng, Z. X. Angew. Chem. Int. Ed. 2016, 55, 14296. doi: 10.1002/anie.201608271
34. [34]
  Fang, L. L.; Liu, D. L.; Wang, Y. L.; Li, Y. J.; Song, L.; Gong, M.; Li, Y.; Deng, Z. X. Nano Lett. 2018, 18, 7014. doi: 10.1021/acs.nanolett.8b02965
35. [35]
  Liu, M.; Fang, L. L.; Li, Y. L.; Gong, M.; Xu, A.; Deng, Z. X. Chem. Sci. 2016, 7, 5435. doi: 10.1039/C6SC01407K
36. [36]
  Wang, Y. L.; Fang, L. L.; Gong, M.; Deng, Z. X. Chem. Sci. 2019, 10, 5929. doi: 10.1039/C9SC00403C
37. [37]
  Sun, Y. Natl. Sci. Rev. 2015, 2, 329. doi: 10.1093/nsr/nwv037
38. [38]
  Gu, H. W.; Yang, Z. M.; Gao, J. H.; Chang, C. K.; Xu, B. J. Am. Chem. Soc. 2005, 127, 34. doi: 10.1021/ja045220h
39. [39]
  Zhu, C.; Zeng, J.; Tao, J.; Johnson, M. C.; Schmidt-Krey, I.; Blubaugh, L.; Zhu, Y. M.; Gu, Z. Z.; Xia, Y. N. J. Am. Chem. Soc. 2012, 134, 15822. doi: 10.1021/ja305329g
40. [40]
  Yu, H.; Chen, M.; Rice, P. M.; Wang, S. X.; White, R. L.; Sun, S. H. Nano Lett. 2005, 5, 379. doi: 10.1021/nl047955q
41. [41]
  Feng, Y. H.; He, J. T.; Wang, H.; Tay, Y. Y.; Sun, H.; Zhu, L. F.; Chen, H. Y. J. Am. Chem. Soc. 2012, 134, 2004. doi: 10.1021/ja211086y
42. [42]
  Sun, Y. G.; Foley, J. J.; Peng, S.; Li, Z.; Gray, S. K. Nano Lett. 2013, 13, 3958. doi: 10.1021/nl402361b
43. [43]
  Song, T. J.; Tang, L. H.; Tan, L. H.; Wang, X. J.; Satyavolu, N. S. R.; Xing, H.; Wang, Z. D.; Li, J. H.; Liang, H. J.; Lu, Y. Angew. Chem. Int. Ed. 2015, 54, 8114. doi: 10.1002/anie.201500838
44. [44]
  Lee, J. H.; You, M. H.; Kim, G. H.; Nam, J. M. Nano Lett. 2014, 14, 6217. doi: 10.1021/nl502541u
45. [45]
  Gawande, M. B.; Goswami, A.; Felpin, F. X.; Asefa, T.; Huang, X. X.; Silva, R.; Zou, X. X.; Zboril, R.; Varma, R. S. Chem. Rev. 2016, 116, 3722. doi: 10.1021/acs.chemrev.5b00482
46. [46]
  Chen, S. T.; Jenkins, S. V.; Tao, J.; Zhu, Y. M.; Chen, J. Y. J. Phys. Chem. C 2013, 117, 8924. doi: 10.1021/jp4013653
47. [47]
  Osowiecki, W. T.; Ye, X. C.; Satish, P.; Bustillo, K. C.; Clark, E. L.; Alivisatos, A. P. J. Am. Chem. Soc. 2018, 140, 8569. doi: 10.1021/jacs.8b04558
48. [48]
  Wu, S. H.; Chen, D. H. J. Colloid Interface Sci. 2004, 273, 165. doi: 10.1016/j.jcis.2004.01.071
49. [49]
  Lin, M. H.; Kim, G. H.; Kim, J. H.; Oh, J. W.; Nam, J. M. J. Am. Chem. Soc. 2017, 139, 10180. doi: 10.1021/jacs.7b04202
50. [50]
  Kim, J. H.; Park, J. E.; Lin, M.; Kim, S.; Kim, G. H.; Park, S.; Ko, G.; Nam, J. M. Adv. Mater. 2017, 29, 1702945. doi: 10.1002/adma.201702945
51. [51]
  Kislenko, V. N.; Oliynyk, L. P. J. Polym. Sci., Part A:Polym. Chem. 2002, 40, 914. doi: 10.1002/pola.10157
52. [52]
  Hohenester, U.; Trügler, A. Comput. Phys. Commun. 2012, 183, 370. doi: 10.1016/j.cpc.2011.09.009
53. [53]
  Wolf, L. K.; Gao, Y.; Georgiadis, R. M. Langmuir 2004, 20, 3357. doi: 10.1021/la036125+
54. [54]
  Fang, Y. J. Chem. Phys. 1998, 108, 4315.
1. [1]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
2. [2]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
3. [3]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
4. [4]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
5. [5]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
6. [6]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
7. [7]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
8. [8]
  Chang Liu , Tao Wu , Lijiao Deng , Xuzi Li , Xin Fu , Shuzhen Liao , Wenjie Ma , Guoqiang Zou , Hai Yang . Programmed DNA walkers for biosensors. Chinese Chemical Letters, 2024, 35(9): 109307-. doi: 10.1016/j.cclet.2023.109307
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
11. [11]
  Yang Qin , Jiangtian Li , Xuehao Zhang , Kaixuan Wan , Heao Zhang , Feiyang Huang , Limei Wang , Hongxun Wang , Longjie Li , Xianjin Xiao . Toeless and reversible DNA strand displacement based on Hoogsteen-bond triplex. Chinese Chemical Letters, 2024, 35(5): 108826-. doi: 10.1016/j.cclet.2023.108826
12. [12]
  Xiaohong Wen , Mei Yang , Lie Li , Mingmin Huang , Wei Cui , Suping Li , Haiyan Chen , Chen Li , Qiuping Guo . Enzymatically controlled DNA tetrahedron nanoprobes for specific imaging of ATP in tumor. Chinese Chemical Letters, 2024, 35(8): 109291-. doi: 10.1016/j.cclet.2023.109291
13. [13]
  Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
16. [16]
  Tian Feng , Yun-Ling Gao , Di Hu , Ke-Yu Yuan , Shu-Yi Gu , Yao-Hua Gu , Si-Yu Yu , Jun Xiong , Yu-Qi Feng , Jie Wang , Bi-Feng Yuan . Chronic sleep deprivation induces alterations in DNA and RNA modifications by liquid chromatography-mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(8): 109259-. doi: 10.1016/j.cclet.2023.109259
17. [17]
  Zhe-Han Yang , Jie Yin , Lei Xin , Yuanfang Li , Yijie Huang , Ruo Yuan , Ying Zhuo . Research advancement of DNA-based intelligent hydrogels: Manufacture, characteristics, application of disease diagnosis and treatment. Chinese Chemical Letters, 2024, 35(10): 109558-. doi: 10.1016/j.cclet.2024.109558
18. [18]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
19. [19]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
20. [20]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(952)
HTML views(140)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142