Citation: Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance[J]. Acta Chimica Sinica, ;2020, 78(8): 805-814. doi: 10.6023/A20040128 shu

Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance

Fu Jingru ,
Ben Teng ^,

College of Chemistry, Jilin University, Changchun 130012

Corresponding author: Ben Teng, tben@jlu.edu.cn
Received Date: 28 April 2020
Available Online: 9 June 2020
Fund Project: the Science and Technology Department of Jilin Province Foundation 20180414009GHthe National Natural Science Foundation of China 21871103"111" Project BP0719036Project supported by the National Natural Science Foundation of China (Nos. 91956108, 21871103), "111" Project (No. BP0719036) and the Science and Technology Department of Jilin Province Foundation (No. 20180414009GH)the National Natural Science Foundation of China 91956108

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Herein, we employ 2, 5-dimethoxyterephthalaldehyde (DMTA) containing ether oxygen group in the structure as the construction unit to react with tetra-(4-anilyl)-methane (TAM) through Schiff-based condensation reaction in a Teflon-lined autoclave to synthesize a novel three-dimensional covalent organic framework named DMTA-COF. Furthermore, the condensation reaction was confirmed by Fourier transform infrared spectroscopy (FT-IR). The crystal structure of DMTA-COF was analyzed by the powder X-ray diffraction (PXRD) measurement in conjunction with structural simulation. The morphology, thermal stability, porosity and pore distribution of DMTA-COF were measured by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and N₂ adsorption-desorption at 77 K. The high affinity for CO₂ adsorption was also confirmed by low pressure CO₂ sorption. Considering the relatively small pore size and the strong CO₂ adsorption interaction of DMTA-COF due to an abundant of ether oxygen group and imine linkage, we synthesized one continuous supported DMTA-COF membrane for H₂/CO₂ separation. In our study, the porous Al₂O₃ support surface was first coated with polyaniline (PANI) and was then further functionalized with aldehyde groups by reaction with DMTA at 150 ℃ for 1 h. Finally, in situ growth of the COF membrane utilizing the covalent linkage yielded a novel continuous DMTA-COF membrane. X-ray diffraction (XRD) result indicated that the DMTA-COF membrane was pure phase and had high crystallinity. From SEM characterization, we could see that the DMTA-COF membrane was compact and well intergrowth and adhered to the support tightly. Gas separation performance results shown that DMTA-COF membrane had a high H₂ permeance and selectivity of H₂/CO₂. For DMTA-COF membrane, the 1:1 binary mixture gas separation factors of H₂/CO₂ calculated as the gas molar ratios in permeate and retentate side was 8.3 at room temperature and atmospheric pressure. And H₂/CO₂ separation factor of DMTA-COF membrane exceeded the corresponding Knudsen coefficient (4.7), with H₂ permeance of up to 6.3×10^－7 mol·m^－2·s^－1·Pa^－1. Because of its outstanding characteristics, the novel DMTA-COF membrane is expected to be widely used in the field of H₂ purification and separation.
- covalent organic framework,
- crystal structure,
- membranes,
- gas separation,
- H₂ purification
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