Citation: Guo Jinqiu, Du Yaping, Zhang Hongbo. A Brief Summary of Research Progress on the Application of Rare Earth Materials in Heterogeneous Catalysis[J]. Acta Chimica Sinica, ;2020, 78(7): 625-633. doi: 10.6023/A20030053 shu

A Brief Summary of Research Progress on the Application of Rare Earth Materials in Heterogeneous Catalysis

Guo Jinqiu ^a ,
Du Yaping ^b,, ,
Zhang Hongbo ^a,b,,

a.
School of Materials Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 300350
b.
Tianjin Key Laboratory of Rare Earth Materials and Application, Nankai University, Tianjin 300350

Corresponding author: Du Yaping, ypdu@nankai.edu.cn Zhang Hongbo, hbzhang@nankai.edu.cn
Received Date: 4 March 2020
Available Online: 22 June 2020
Fund Project: Nankai University 023-92022018Project supported by the "111 Project" of China (No. B18030), Nankai University (No. 023-92022018), Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering of Ministry of Education, Dalian University of Technology (No. KLIEEE-19-07) and Natural Science Foundation of Tianjin (No. BE122121)Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering of Ministry of Education, Dalian University of Technology KLIEEE-19-07Natural Science Foundation of Tianjin BE122121the "111 Project" of China B18030

Figures(11)

Rare earth (RE) resources are in big amount in China, which can be effectively purified based on the strategies developed by Prof. Guangxian Xu et al. last century, which sets up solid fundamentals for applied research on rare earth materials nowadays. Rare earth elements, including scandium, yttrium and lanthanides, feature stable overall chemical properties, variable valence states and coordination form as well as special Lewis acidity due to the unique electron configuration in the outermost and secondary outer orbitals of the lanthanide elements ([Xe] 4f^n-15d^0~16s² (n=1~15)), especially on their 4f electron shell structure, having been extensively used in catalysis. However, the efficiency and selectivity to the desired products are always the major challenges due to the complexity of catalysis, in particular, the mechanism by which rare earth metals affect catalytic reactions through structural or electronic effects has not been clarified. Therefore, this mini-review summarizes the research progress on the application of rare earth materials in heterogeneous catalysis (specifically on thermal catalysis). Firstly, a brief summary of rare earth materials' structural properties is provided with emphasis on the unique distribution of the 4f electron. Afterward, the application of RE elements in thermal catalysis was discussed in detail. For example:(1) as a support to promote catalytic reaction, such as CeO₂, which has variable chemical valence and can be used as an active support to participate in the redox reaction; (2) as moderate Lewis acid (base) center to catalyze the aldol condensation of acetaldehyde/ethanol mixture and effectively control the C-C bond coupling; (3) as electronic and structural promoters to improve catalytic activity and stability. Hence, the structure-function relationship is illustrated in accordance with the studies of the rare earth materials as the supports, Lewis acid (base) active center and catalytic promoters, suggesting great potential of rare earth materials in catalysis.
- rare earth material,
- support,
- Lewis acid (base),
- catalytic promoters
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