Citation: Guo Jinqiu, Du Yaping, Zhang Hongbo. A Brief Summary of Research Progress on the Application of Rare Earth Materials in Heterogeneous Catalysis[J]. Acta Chimica Sinica, ;2020, 78(7): 625-633. doi: 10.6023/A20030053 shu

A Brief Summary of Research Progress on the Application of Rare Earth Materials in Heterogeneous Catalysis

Guo Jinqiu ^a ,
Du Yaping ^b,, ,
Zhang Hongbo ^a,b,,

a.
School of Materials Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 300350
b.
Tianjin Key Laboratory of Rare Earth Materials and Application, Nankai University, Tianjin 300350

Corresponding author: Du Yaping, ypdu@nankai.edu.cn Zhang Hongbo, hbzhang@nankai.edu.cn
Received Date: 4 March 2020
Available Online: 22 June 2020
Fund Project: Nankai University 023-92022018Project supported by the "111 Project" of China (No. B18030), Nankai University (No. 023-92022018), Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering of Ministry of Education, Dalian University of Technology (No. KLIEEE-19-07) and Natural Science Foundation of Tianjin (No. BE122121)Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering of Ministry of Education, Dalian University of Technology KLIEEE-19-07Natural Science Foundation of Tianjin BE122121the "111 Project" of China B18030

Figures(11)

Rare earth (RE) resources are in big amount in China, which can be effectively purified based on the strategies developed by Prof. Guangxian Xu et al. last century, which sets up solid fundamentals for applied research on rare earth materials nowadays. Rare earth elements, including scandium, yttrium and lanthanides, feature stable overall chemical properties, variable valence states and coordination form as well as special Lewis acidity due to the unique electron configuration in the outermost and secondary outer orbitals of the lanthanide elements ([Xe] 4f^n-15d^0~16s² (n=1~15)), especially on their 4f electron shell structure, having been extensively used in catalysis. However, the efficiency and selectivity to the desired products are always the major challenges due to the complexity of catalysis, in particular, the mechanism by which rare earth metals affect catalytic reactions through structural or electronic effects has not been clarified. Therefore, this mini-review summarizes the research progress on the application of rare earth materials in heterogeneous catalysis (specifically on thermal catalysis). Firstly, a brief summary of rare earth materials' structural properties is provided with emphasis on the unique distribution of the 4f electron. Afterward, the application of RE elements in thermal catalysis was discussed in detail. For example:(1) as a support to promote catalytic reaction, such as CeO₂, which has variable chemical valence and can be used as an active support to participate in the redox reaction; (2) as moderate Lewis acid (base) center to catalyze the aldol condensation of acetaldehyde/ethanol mixture and effectively control the C-C bond coupling; (3) as electronic and structural promoters to improve catalytic activity and stability. Hence, the structure-function relationship is illustrated in accordance with the studies of the rare earth materials as the supports, Lewis acid (base) active center and catalytic promoters, suggesting great potential of rare earth materials in catalysis.
- rare earth material,
- support,
- Lewis acid (base),
- catalytic promoters
1. [1]
  Dong, H.; Du, S. R.; Zheng, X. Y.; Lyu, G. M.; Sun, L. D.; Li, L. D.; Zhang, P. Z.; Zhang, C.; Yan, C. H. Chem. Rev. 2015, 115, 10726. doi: 10.1021/acs.chemrev.5b00091
2. [2]
  Information Office of the State Council of the People's Republic of China. China Metal Bulletin 2012, 24, 20(in Chinese).
3. [3]
  Wang, M.; Shen, M.; Jin, X. X.; Tian, J. J.; Li, M. L.; Zhou, Y. J.; Zhang, L. X.; Li, Y. S.; Shi, J. L. ACS Catal. 2019, 9, 4573.
4. [4]
  Liang, M. F.; Borjigin, T.; Zhang, Y. H.; Liu, B. H.; Liu, H.; Guo, H. Appl. Catal. B: Environ. 2018, 243, 566.
5. [5]
  Zhang, F.; Braun, G. B.; Shi, Y. F.; Sun, X. H.; Reich, N. O.; Zhao, D. Y.; Stucky, G. J. Am. Chem. Soc. 2010, 132, 2850.
6. [6]
  Meng, S. Y.; Wang, M. M.; Lü, B. L.; Xue, Q. J.; Yang, Z. W. Acta Chim. Sinica 2019, 77, 1184(in Chinese).
7. [7]
  Xia, J. L.; Zhao, H. Y.; Pang, W. K.; Yin, Z. Y; Zhou, B.; He, G.; Guo, Z. P.; Du, Y. P. Chem. Sci. 2018, 9, 3421. doi: 10.1039/C7SC05185A
8. [8]
  Ha, H. W.; Yun, N. J.; Kim, M. H.; Woo, M. H.; Kim, K. Electrochim. Acta 2006, 51, 3297.
9. [9]
  Chen, P. L.; Chen, I. W. J. Am. Ceram. Soc. 1993, 76, 1577. doi: 10.1111/j.1151-2916.1996.tb07998.x
10. [10]
  Frey, A. M.; Karmee, S. K.; de Jong, K. P.; Bitter, J. H.; Hanefeld, U. ChemCatChem 2013, 5, 594. doi: 10.1002/cctc.201200282
11. [11]
  Chen, Z. Y.; Liu, J. W.; Cui, H.; Zhang, L.; Su, C. Y. Acta Chim. Sinica 2019, 77, 242(in Chinese).
12. [12]
  Song, T. Y.; Xu, J. N.; Cheng, G. Z.; Wang, L. Inorganic Chemistry (Third edition), Higher Education Press, Beijing, 2014, p. 816(in Chinese).
13. [13]
  Risse, T.; Shaikhutdinov, S.; Nilius, N.; Sterrer, M.; Freund, H. J. Acc. Chem. Res. 2008, 41, 949. doi: 10.1021/ar800078m
14. [14]
  Mattos, L. V.; Noronha, F. B. J. Catal. 2005, 233, 453. doi: 10.1016/j.apcata.2005.05.015
15. [15]
  Summers, J. C.; Ausen, S. A. J. Catal. 1979, 58, 131. doi: 10.1016/0021-9517(79)90251-3
16. [16]
  Yao, H. C.; Yao, Y. F. J. Catal. 1984, 86, 254.
17. [17]
  Shyu, J. Z.; Otto, K.; Watkins, W. L. H.; Graham, G. W.; Belitz, R. K. J. Catal. 1988, 114, 23. doi: 10.1016/0021-9517(88)90005-x
18. [18]
  Kašpar, J.; Fornasiero, P.; Graziani, M. Catal. Today 1999, 50, 285. doi: 10.1016/S0920-5861(98)00510-0
19. [19]
  Fornasiero, P.; Monte, R. D.; Rao, G. R.; Kašpar, J.; Meriani, S.; Trovarelli, A.; Graziani, M. J. Catal. 1995, 151, 168. doi: 10.1006/jcat.1995.1019
20. [20]
  Valsamakis, I.; Flytzani-Stephanopoulos, M. Appl. Catal. B: Environ. 2011, 106, 255.
21. [21]
  Al-Sultan, F. S.; Basahel, S. N.; Narasimharao, K. Fuel 2018, 233, 796. doi: 10.1016/j.fuel.2018.06.130
22. [22]
  Zheng, T. T.; He, J. J.; Zhao, Y. K.; Xia, W. Z.; He, J. L. J. Rare Earth 2014, 32, 97.
23. [23]
  Korneeva, E. V.; Ivanova, A. S.; Bukhtiyarova, G. A.; Aleksandrov, P. V.; Zaikovskii, V. I.; Prosvirin, I. P.; Noskov, A. S. Kinet. Catal. 2011, 52, 579. doi: 10.1134/s0023158411030128
24. [24]
  Mokhnachuk, O. V.; Soloviev, S. O.; Kapran, A. Y. Catal. Today 2007, 119, 145.
25. [25]
  Lemonidou, A. A.; Vagia, E. C.; Lercher, J. A. ACS Catal. 2013, 3, 1919. doi: 10.1021/cs4003063
26. [26]
  Li, X. Y.; Li, D.; Tian, H.; Zeng, L.; Zhao, Z. J.; Gong, J. L. Appl. Catal. B: Environ. 2017, 202, 683. doi: 10.1016/j.apcatb.2016.09.071
27. [27]
  Sodesawa, T.; Dobashi, A.; Nozaki, F. Kinet. Catal. Lett. 1979, 12, 107. doi: 10.1007/bf02071433
28. [28]
  Luo, J. Z.; Yu, Z. L.; Ng, C. F.; Au, C. T. J. Catal. 2000, 194, 198. doi: 10.1023/A:1019035220233
29. [29]
  Singh, S.; Zubenko, D.; Rosen, B. A. ACS Catal. 2016, 6, 4199. doi: 10.1021/acscatal.6b00673
30. [30]
  Pawar, V.; Appari, S.; Monder, D. S.; Janardhanan, V. M. Ind. Eng. Chem. Res. 2017, 56, 8448. doi: 10.1021/acs.iecr.7b01662
31. [31]
  Dahdah, E.; Rached, J. A.; Aouad, S.; Gennequin, C.; Tidahy, H. L.; Estephane, J.; Aboukais, A.; Aad, E. A. Int. J. Hydrogen Energy 2017, 48, 12808. doi: 10.1007/s11356-016-7480-9
32. [32]
  Liu, H. R.; Wierzbicki, D.; Debek, R.; Motak, M.; Grzybek, T.; Costa, P. D.; Gálvez, M. E. Fuel 2016, 182, 8. doi: 10.1016/j.fuel.2016.05.073
33. [33]
  Tsipouriari, V. A.; Verykios, X. E. J. Catal. 1999, 187, 85. doi: 10.1006/jcat.1999.2565
34. [34]
  Oemar, U.; Kathiraser, Y.; Mo, L.; Ho, X. K.; Kawi, S. Catal. Sci. Technol. 2016, 6, 1173. doi: 10.1039/C5CY00906E
35. [35]
  Li, K.; He, F.; Yu, H. M.; Wang, Y.; Wu, Z. J. J. Catal. 2018, 364, 248.
36. [36]
  May, Y. A.; Wang, W. W.; Yan, H.; Wei, S.; Jia, C. J. Chin. J. Catal. 2020, 41, 1017.
37. [37]
  Zhou, Y.; Chen, A.; Ning, J.; Shen, W. J. Chin. J. Catal. 2020, 41, 928.
38. [38]
  Si, R.; Flytzani-Stephanopoulos, M. Angew. Chem., Int. Ed. 2008, 47, 2884. doi: 10.1002/anie.200705828
39. [39]
  Fu, Q.; Weber, A.; Flytzani-Stephanopoulos, M. Catal. Lett. 2001, 77, 87. doi: 10.1023/a:1012666128812
40. [40]
  Zhang, F.; Chan, S. W.; Spanier, J. E.; Apak, E.; Jin, Q.; Robinson, R. D.; Herman, I. P. Appl. Phys. Lett. 2002, 80, 127. doi: 10.1063/1.1430502
41. [41]
  Gatla, S.; Aubert, D.; Agostini, G.; Mathon, O.; Pascarelli, S.; Lunkenbein, T.; Willinger, M. G.; Kaper, H. ACS Catal. 2016, 6, 6151. doi: 10.1021/acscatal.6b00677
42. [42]
  Nie, L.; Mei, D. H.; Xiong, H. F.; Peng, B.; Ren, Z. B.; Hernandez, X. I. P.; DeLaRiva, A.; Wang, M.; Engelhard, M. H.; Kovarik, L.; Datye, A. K.; Wang, Y. Science 2017, 358, 1419.
43. [43]
  Spezzati, G.; Benavidez, A. D.; DeLaRiva, A. T.; Su, Y. Q.; Hofmann, J. P.; Asahina, S.; Olivier, E. J.; Neethling, J. H.; Miller, J. T.; Datye, A. K.; Hensen, E. J. M. Appl. Catal. B: Environ. 2019, 243, 36.
44. [44]
  Liu, L. C.; Corma, A. Chem. Rev. 2018, 118, 4981.
45. [45]
  Zhao, S.; Chen, F.; Duan, S. B.; Shao, B.; Li, T. B.; Tang, H. L.; Lin, Q. Q.; Zhang, J. Y.; Li, L.; Huang, J. H.; Bion, N.; Liu, W.; Sun, H.; Wang, A. Q.; Haruta, M.; Qiao, B. T.; Li, J.; Liu, J. Y.; Zhang, T. Nat. Commun. 2019, 10, 3824.
46. [46]
  Liu, J. C.; Wang, Y. G.; Li, J. J. Am. Chem. Soc. 2017, 139, 6190.
47. [47]
  Jones, J.; Xiong, H. F.; DeLaRiva, A. T.; Peterson, E. J.; Pham, H.; Challa, S. R.; Qi, G. S.; Oh, S.; Wiebenga, M. H.; Hernandez, X. I. P.; Wang, Y.; Datye, A. K. Science 2016, 353, 150. doi: 10.1126/science.aaf8800
48. [48]
  Fu, Q.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Science 2003, 301, 935. doi: 10.1126/science.1085721
49. [49]
  Dongil, A. B.; Pastor-Perez, L.; Escalona, N.; Sepulveda-Escribano, A. Carbon 2016, 101, 296. doi: 10.1016/j.apcata.2015.11.048
50. [50]
  Reina, T. R.; Ivanova, S.; Centeno, M. A.; Odriozola, J. A. Appl. Catal. B: Environ. 2016, 187, 98. doi: 10.1016/j.apcatb.2016.01.031
51. [51]
  Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Senanayake, S. D.; White, M. G.; Chen, J. G. ACS Catal. 2015, 6, 6696. doi: 10.1021/acscatal.5b01755
52. [52]
  Micoud, F.; Maillard, F.; Bonnefont, A.; Job, N.; Chatenet, M. Phys. Chem. Chem. Phys. 2010, 12, 1182. doi: 10.1039/b915244j
53. [53]
  Li, S. W.; Xu, Y.; Chen, Y. F.; Li, W. Z.; Lin, L. L.; Li, M. Z.; Deng, Y. C.; Wang, X. P.; Ge, B. H.; Yang, C.; Yao, S. Y.; Xie, J. L.; Li, Y. W.; Liu, X.; Ma, D. Angew. Chem., Int. Ed. 2017, 56, 10761. doi: 10.1002/ange.201705002
54. [54]
  Guo, Y.; Mei, S.; Yuan, K.; Wang, D. J.; Liu, H. C.; Yan, C. H.; Zhang, Y. W. ACS Catal. 2018, 8, 6203. doi: 10.1021/acscatal.7b04469
55. [55]
  Xu, J.; Chen, X. Y.; Xu, Y. S.; Du, Y. P.; Yan, C. H. Adv. Mater. 2019, 1806461.
56. [56]
  Pudukudy, M.; Yaakob, Z.; Takriff, M. S. Energy Convers. Manage. 2016, 126, 302. doi: 10.1016/j.enconman.2016.08.006
57. [57]
  Pudukudy, M.; Yaakob, Z.; Jia, Q. M.; Takriff, M. S. Appl. Surf. Sci. 2019, 467~468, 236.
58. [58]
  Lessard, J. D.; Valsamakis, I.; Flytzani-Stephanopoulos, M. Chem. Commun. 2012, 48, 4857. doi: 10.1039/c2cc31105d
59. [59]
  Akhmedov, V. M.; Al-Khowaiter, S. H. Catal. Rev.-Sci. Eng. 2007, 44, 455.
60. [60]
  Jacinto, S.; Ace, M.; Delgado, J. J.; Goguet, A.; Hardacre, C.; Morgan, K. ChemCatChem 2011, 3, 394. doi: 10.1002/ange.201102066
61. [61]
  Wang, Z. Q.; Wang, D.; Gong, X. Q. ACS Catal. 2020, 10, 586.
62. [62]
  Huang, Z. Q.; Zhang, T. Y.; Chang, C. R.; Li, J. ACS Catal. 2019, 9, 5523.
63. [63]
  Sun, J. M.; Zhu, K. K.; Gao, F.; Wang, C. M.; Liu, J.; Peden, C. H. F.; Wang, Y. J. Am. Chem. Soc. 2011, 133, 11096. doi: 10.1021/ja204235v
64. [64]
  Ogo, S.; Onda, A.; Iwasa, Y.; Hara, K.; Fukuoka, A.; Yanagisawa, K. J. Catal. 2012, 296, 24. doi: 10.1016/j.jcat.2012.08.019
65. [65]
  Zhang, H. B.; Ibrahim, M. Y. S.; Flaherty, D. W. J. Catal. 2018, 361, 290. doi: 10.1016/j.jcat.2018.02.030
66. [66]
  Pang, J. F.; Zheng, M. Y.; He, L.; Li, L.; Pan, X. L.; Wang, A. Q.; Wang, X. D.; Zhang, T. J. Catal. 2016, 344, 184.
67. [67]
  Moteki, T.; Flaherty, D. W. ACS Catal. 2016, 6, 4170. doi: 10.1021/acscatal.6b00556
68. [68]
  Dai, J. J.; Zhang, H. B. Sci. China Mater. 2019, 62, 1642.
69. [69]
  Cota, I.; Ramírez, E.; Medina, F.; Layrac, C.; Tichit, D.; Gérardin, C. J. Mol. Catal. A: Chem. 2016, 412, 101.
70. [70]
  Yan, T. T.; Dai, W. L.; Wu, G. J.; Lang, S.; Hunger, M.; Guan, N. J.; Li, L. D. ACS Catal. 2018, 8, 2760. doi: 10.1021/acscatal.8b00014
71. [71]
  Wang, Z.; Fongarland, P.; Lu, G. Z.; Essayem, N. J. Catal. 2014, 318, 108. doi: 10.1016/j.jcat.2014.07.006
72. [72]
  Meis, N. N. A. H.; Bitter, J. H.; de Jong, K. P. Ind. Eng. Chem. Res. 2010, 49, 1229. doi: 10.1021/ie901114d
73. [73]
  Álvarez, M. G.; Plísková, M.; Segarra, A. M.; Medina, F.; Figueras, F. Appl. Catal. B: Environ. 2012, 113~114, 212.
74. [74]
  Liang, Z.; Jiang, D. H.; Fang, G. Q.; Leng, W. H.; Tu, P. X.; Tong, Y. Q.; Liu, L.; Ni, J.; Li, X. N. ChemistrySelect 2019, 4, 4364. doi: 10.1002/slct.201900712
75. [75]
  Zhen, K. J.; Li, R. S.; Wang, G. J.; Bi, Y. L.; Kan, Q. B. Catalysis Basics (Third edition), Science Press, Beijing, 2004, p. 239. (in Chinese).
76. [76]
  Cunha, A. F.; Mahata, N.; Órfão, J. J. M.; Figueiredo, J. L. Energy Fuels 2009, 23, 4047.
77. [77]
  Gao, J.; Hou, Z. Y.; Guo, J. Z.; Zhu, Y. H.; Zheng, X. M. Catal. Today 2008, 131, 278. doi: 10.1016/j.cattod.2007.10.019
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
3. [3]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
4. [4]
  Xinghai Liu , Hongke Wu . Exploration and Practice of Ideological and Political Education in Heterocyclic Chemistry Based on "Fentanyl" Event. University Chemistry, 2024, 39(8): 359-364. doi: 10.3866/PKU.DXHX202312100
5. [5]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
6. [6]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
7. [7]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
8. [8]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
9. [9]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
12. [12]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
13. [13]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
14. [14]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
15. [15]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
16. [16]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
17. [17]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
18. [18]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
19. [19]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
20. [20]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

Get Citation

PDF

XML

Metrics

PDF Downloads(113)
Abstract views(2663)
HTML views(860)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142