Citation: Liu Jianguo, Zhang Mingyue, Wang Nan, Wang Chenguang, Ma Longlong. Research Progress of Covalent Organic Framework Materials in Catalysis[J]. Acta Chimica Sinica, ;2020, 78(4): 311-325. doi: 10.6023/A19120426 shu

Research Progress of Covalent Organic Framework Materials in Catalysis

Liu Jianguo ^a,b,c,, ,
Zhang Mingyue ^a,b ,
Wang Nan ^a,b,d ,
Wang Chenguang ^a,b ,
Ma Longlong ^a,b,d,,

a.
Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Dalian National Laboratory for Clean Energy, Dalian 116023, China
d.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China

Corresponding author: Liu Jianguo, liujg@ms.giec.ac.cn Ma Longlong, mall@ms.giec.ac.cn
Received Date: 14 December 2019
Available Online: 8 April 2020
Fund Project: the National Natural Science Foundation of China 51976225Project supported by the National Natural Science Foundation of China (No. 51976225) and Dalian National Laboratory for Clean Energy Cooperation Fund, Chinese Academy of Sciences (No. DNL201916)Dalian National Laboratory for Clean Energy Cooperation Fund, Chinese Academy of Sciences DNL201916

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Covalent organic framework materials (COFs) are a class of organic porous materials with large specific surface area, high porosity and crystallinity. Owning to their special nature of functional versatility and easy modification, COFs can be designed to be efficient catalysts either embed functional active sites into the skeleton through a "top-down" strategy, or load metal nanoparticles into the framework via a post-modification approach. These studies have laid the foundation for the extension of COF's application in heterogeneous and other catalytic fields. The synthetic strategy and application of COF in different types of catalytic reactions are reviewed in this paper. Moreover, the current research situation of COF catalyst is summarized and prospected. Finally, the remaining challenges in this field are also indicated.
- covalent organic framework,
- porous material,
- COF supporter,
- catalyst,
- heterogeneous catalysis
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