Advanced Search

Citation: Chen Yingying, Liu Huan, Cheng Yan, Xie Qingji. Preparation of Honeycomb-structured AuPtCu Electrocatalyst by Dynamic Hydrogen Bubble and Sacrificial Cu Templates for Oxidation of Formic Acid[J]. Acta Chimica Sinica, ;2020, 78(4): 330-336. doi: 10.6023/A19110400 shu

Preparation of Honeycomb-structured AuPtCu Electrocatalyst by Dynamic Hydrogen Bubble and Sacrificial Cu Templates for Oxidation of Formic Acid

  • Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research(Ministry of Education of China), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

  • Corresponding author: Xie Qingji, xieqj@hunnu.edu.cn
  • Received Date: 12 November 2019
    Available Online: 11 March 2020

    Fund Project: the National Natural Science Foundation of China 21475041Project supported by the National Natural Science Foundation of China (Nos. 21675050, 21475041 and 21775137), Hunan Lotus Scholars Program (2011) and Foundation of the Science & Technology Department of Hunan Province (No. 2016SK2020)the National Natural Science Foundation of China 21675050the National Natural Science Foundation of China 21775137Foundation of the Science & Technology Department of Hunan Province 2016SK2020Hunan Lotus Scholars Program 2011

Figures(5)

  • Improving the performance of electrocatalytic formic acid oxidation is the key issue to develop high-performance direct formic acid fuel cells (DFAFC). Pt-based and Pd-based materials are the important electrocatalysts for formic acid oxidation. Micro/nano-porous metal materials are widely concerned in the electrochemistry field due to the high specific electrode-surface area. The dynamic hydrogen bubble template (DHBT) method has been widely used for preparing the three-dimensional honeycomb-like porous nano-metals (3DHPNMs). However, as far as we know, the use of a sacrificial metal template to prepare the 3DHPNMs with improved performance for the electrocatalytic oxidation of small organic molecules has not been reported. Herein, a three-dimensional honeycomb-like porous nano-AuPtCu (3DHPN-AuPtCu) composite was electrodeposited on a gold-plated glassy carbon electrode (Aupla/GCE) by the DHBT method, followed by anodic stripping of Cu to yield a 3DHPN-AuPtCu/Aupla/GCE. The relevant modified electrodes were characterized by cyclic voltammetry (CV), metallographic microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy and inductively coupled plasma-atomic emission spectrometry. The SEM results clearly revealed that the use of the sacrificial Cu template can modulate the metal-honeycomb structure, and the 3DHPN-AuPtCu/Aupla/GCE can thus possess the better micro/nano-porous structure and the improved electrocatalytic performance than a Cu-template-free 3DHPN-AuPt/Aupla/GCE. In our opinion, the simultaneous electrodeposition of Cu can intervene in the electrodeposition of Au and Pt, and thus a new structure with more active sites exposed and the electrocatalysis performance improved can be obtained after the anodic stripping of electrodeposited Cu. As a result, the 3DHPN-AuPtCu/Aupla/GCE exhibited high anti-poisoning nature and high stability, because many discontinuous Pt atoms on this electrode can suppress the formation of adsorption-state COads during the electrocatalytic oxidation of formic acid. The electrocatalytic oxidation peak current density on 3DHPN-AuPtCu/Aupla/GCE in 0.5 mol/L aqueous H2SO4 containing 0.2 mol/L HCOOH was 12.5 mA·cmPt-2 (CV, -0.3~1.0 V, 50 mV/s), which is superior to the control electrodes and many reported Pt-based electrocatalysis electrodes. The suggested double- template method for preparing honeycomb-structured micro/nano-porous metal materials with improved performance has the potential for wider electrocatalysis and electroanalysis applications.
  • 加载中
    1. [1]

      Kim, J.; Roh, C.-W.; Sahoo, S. K.; Yang, S.; Bae, J.; Han, J. W.; Lee, H. Adv. Energy Mater. 2018, 8, 1701476.  doi: 10.1002/aenm.201701476

    2. [2]

      Marcinkowski, M. D.; Murphy, C. J.; Liriano, M. L.; Wasio, N. A.; Lucci, F. R.; Sykes, E. C. H. ACS Catal. 2015, 5, 7371.  doi: 10.1021/acscatal.5b01994

    3. [3]

      Fan, H. s.; Cheng, M.; Wang, L.; Song, Y. j.; Cui, Y.; Wang, R. m. Nano Energy 2018, 48, 1.  doi: 10.1016/j.nanoen.2018.03.018

    4. [4]

      Wang, X.-M.; Wang, M.-E.; Zhou, D.-D.; Xia, Y.-Y. Phys. Chem. Chem. Phys. 2011, 13, 13594.  doi: 10.1039/c1cp21680e

    5. [5]

      Li, M.; Liu, R.; Han, G.; Tian, Y.; Chang, Y.; Xiao, Y. Chin. J. Chem. 2017, 35, 1405.  doi: 10.1002/cjoc.201700061

    6. [6]

      Li, N. Chin. J. Chem. 2016, 34, 1129.  doi: 10.1002/cjoc.201600427

    7. [7]

      Cao, J.; Zhu, Z.; Zhao, W.; Xu, J.; Chen, Z. Chin. J. Chem. 2016, 34, 1086.  doi: 10.1002/cjoc.201600366

    8. [8]

      Liu, J.; Wu, B.; Gao, Y. Acta Chim. Sinica 2012, 70, 1743.

    9. [9]

      Shi, Y.; Li, J.; Xing, J.; Xiao, M.; Chen, Y.; Zhou, Y.; Lu, T.; Tang, Y. Acta Chim. Sinica 2012, 70, 1257.  doi: 10.3866/PKU.WHXB201202212

    10. [10]

      Huang, X.; Zhao, Z.; Fan, J.; Tan, Y.; Zheng, N. J. Am. Chem. Soc. 2011, 133, 4718.  doi: 10.1021/ja1117528

    11. [11]

      Xia, B. Y.; Wu, H. B.; Yan, Y.; Lou, X. W.; Wang, X. J. Am. Chem. Soc. 2013, 135, 9480.  doi: 10.1021/ja402955t

    12. [12]

      Ji, X.; Lee, K. T.; Holden, R.; Zhang, L.; Zhang, J.; Botton, G. A.; Couillard, M.; Nazar, L. F. Nat. Chem. 2010, 2, 286.  doi: 10.1038/nchem.553

    13. [13]

      Wang, R.; Wang, C.; Cai, W.-B.; Ding, Y. Adv. Mater. 2010, 22, 1845.  doi: 10.1002/adma.200903548

    14. [14]

      Zhang, Q.; Yao, Z.; Zhou, R.; Du, Y.; Yang, P. Acta Chim. Sinica 2012, 70, 2149.

    15. [15]

      Zhou, R.; Zhang, H.; Du, Y.; Yang, P. Acta Chim. Sinica 2011, 69, 1533.

    16. [16]

      Plowman, B. J.; Jones, L. A.; Bhargava, S. K. Chem. Commun. 2015, 51, 4331.  doi: 10.1039/C4CC06638C

    17. [17]

      Xu, M.; Sui, Y.; Xiao, G.; Yang, X.; Wei, Y.; Zou, B. Nanoscale 2017, 9, 2514.  doi: 10.1039/C6NR08518K

    18. [18]

      Wang, Z.; Ning, S.; Liu, P.; Ding, Y.; Hirata, A.; Fujita, T.; Chen, M. Adv. Mater. 2017, 29, 1703601.  doi: 10.1002/adma.201703601

    19. [19]

      He, F.; Qiao, Z.; Qin, X.; Chao, L.; Tan, Y.; Xie, Q.; Yao, S. Sens. Actuators B:Chem. 2019, 296, 126679.  doi: 10.1016/j.snb.2019.126679

    20. [20]

      Liu, J.; Cao, L.; Huang, W.; Li, Z. ACS Appl. Mater. Inter. 2011, 3, 3552.  doi: 10.1021/am200782x

    21. [21]

      Plowman, B. J.; O'Mullane, A. P.; Selvakannan, P. R.; Bhargava, S. K. Chem. Commun. 2010, 46, 9182.  doi: 10.1039/c0cc03696j

    22. [22]

      Qiu, H.; Tang, T.; Asif, M.; Huang, X.; Hou, Y. Adv. Funct. Mater. 2019, 29, 1808468.  doi: 10.1002/adfm.201808468

    23. [23]

      Mattarozzi, L.; Cattarin, S.; Comisso, N.; Guerriero, P.; Musiani, M.; Verlato, E. Electrochim. Acta 2016, 198, 296.  doi: 10.1016/j.electacta.2016.03.084

    24. [24]

      Li, R.; Mao, H.; Zhang, J.; Huang, T.; Yu, A. J. Power Sources 2013, 241, 660.  doi: 10.1016/j.jpowsour.2013.05.032

    25. [25]

      Kottakkat, T.; Klingan, K.; Jiang, S.; Jovanov, Z. P.; Davies, V. H.; El-Nagar, G. A. M.; Dau, H.; Roth, C. ACS Appl. Mater. Inter. 2019, 11, 14734.  doi: 10.1021/acsami.8b22071

    26. [26]

      Yuan, W.; Zhang, J.; Shen, P. K.; Li, C. M.; Jiang, S. P. Electrochim. Acta 2016, 190, 817.  doi: 10.1016/j.electacta.2015.12.152

    27. [27]

      Pilapil, B. K.; van Drunen, J.; Makonnen, Y.; Beauchemin, D. Jerkiewicz, G.; Gates, B. D. Adv. Funct. Mater. 2017, 27, 1703171.  doi: 10.1002/adfm.201703171

    28. [28]

      Xi, Z.; Lv, H.; Erdosy, D. P.; Su, D.; Li, Q.; Yu, C.; Li, J.; Sun, S. Nanoscale 2017, 9, 7745.  doi: 10.1039/C7NR02711G

    29. [29]

      Wang, C.; van der Vliet, D.; More, K. L.; Zaluzec, N. J.; Peng, S.; Sun, S.; Daimon, H.; Wang, G.; Greeley, J.; Pearson, J.; Paulikas, A. P.; Karapetrov, G.; Strmcnik, D.; Markovic, N. M.; Stamenkovic, V. R. Nano Lett. 2011, 11, 919.  doi: 10.1021/nl102369k

    30. [30]

      Al Amri, Z.; Mercer, M. P.; Vasiljevic, N. Electrochim. Acta 2016, 210, 520.  doi: 10.1016/j.electacta.2016.05.161

    31. [31]

      You, H.; Zhang, F.; Liu, Z.; Fang, J. ACS Catal. 2014, 4, 2829.  doi: 10.1021/cs500390s

    32. [32]

      Sneed, B. T.; Young, A. P.; Jalalpoor, D.; Golden, M. C.; Mao, S.; Jiang, Y.; Wang, Y.; Tsung, C.-K. ACS Nano 2014, 8, 7239.  doi: 10.1021/nn502259g

    33. [33]

      Wang, X.; Orikasa, Y.; Uchimoto, Y. ACS Catal. 2016, 6, 4195.  doi: 10.1021/acscatal.6b00497

    34. [34]

      Saleem, F.; Xu, B.; Ni, B.; Liu, H.; Nosheen, F.; Li, H.; Wang, X. Adv. Mater. 2015, 27, 2013.  doi: 10.1002/adma.201405319

    35. [35]

      Ramani, S.; Sarkar, S.; Vemuri, V.; Peter, S. C. J. Mater. Chem. A 2017, 5, 11572.  doi: 10.1039/C6TA06339J

    36. [36]

      Xu, H.; Yan, B.; Li, S.; Wang, J.; Wang, C.; Guo, J.; Du, Y. Chem. Eng. J. 2018, 334, 2638.  doi: 10.1016/j.cej.2017.10.175

    37. [37]

      Huang, Y.; Zhao, T.; Zeng, L.; Tan, P.; Xu, J. Electrochim. Acta 2016, 190, 956.  doi: 10.1016/j.electacta.2015.12.223

    38. [38]

      Li, D.; Meng, F.; Wang, H.; Jiang, X.; Zhu, Y. Electrochim. Acta 2016, 190, 852.  doi: 10.1016/j.electacta.2016.01.001

    39. [39]

      Zhang, S.; Shao, Y.; Yin, G.; Lin, Y. Angew. Chem., Int. Ed. 2010, 49, 2211.  doi: 10.1002/anie.200906987

    40. [40]

      Wang, R.; Liu, J.; Liu, P.; Bi, X.; Yan, X.; Wang, W.; Ge, X.; Chen, M.; Ding, Y. Chem. Sci. 2014, 5, 403.  doi: 10.1039/C3SC52792A

    41. [41]

      Kang, Y.; Qi, L.; Li, M.; Diaz, R. E.; Su, D.; Adzic, R. R.; Stach, E.; Li, J.; Murray, C. B. J. Am. Chem. Soc. 2012, 6, 2818.

    42. [42]

      Fu, G.-T.; Xia, B.-Y.; Ma, R.-G.; Chen, Y.; Tang, Y.-W.; Lee, J.-M. Nano Energy 2015, 12, 824.  doi: 10.1016/j.nanoen.2015.01.041

    43. [43]

      Choi, M.; Ahn, C.-Y.; Lee, H.; Kim, J. K.; Oh, S.-H.; Hwang, W.; Yang, S.; Kim, J.; Kim, O.-H.; Choi, I.; Sung, Y.-E.; Cho, Y.-H.; Rhee, C. K.; Shin, W. Appl. Catal. B:Environ. 2019, 253, 187.  doi: 10.1016/j.apcatb.2019.04.059

    44. [44]

      Tao, X.; Li, L.; Qi, X.; Wei, Z. Acta Chim. Sinica 2017, 75, 237.  doi: 10.11862/CJIC.2017.042

    45. [45]

      Guo, J. W.; Zhao, T. S.; Prabhuram, J.; Chen, R.; Wong, C. W. J. Power Sources 2006, 156, 345  doi: 10.1016/j.jpowsour.2005.05.093

  • 加载中
    1. [1]

      Enqi CHEN , Xinyi MA , Xiang HAN , Yutong YE , Kexin QIN , Shenghui LI , Changli ZHANG , Min YU , Changyun CHEN . Research progress on MOF-based electrocatalysts for the urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 1871-1892. doi: 10.11862/CJIC.20260168

    2. [2]

      Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-0. doi: 10.1016/j.actphy.2025.100149

    3. [3]

      Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398

    4. [4]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    5. [5]

      Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni2P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045

    6. [6]

      Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

    7. [7]

      Wenliang Wang ,  Weina Wang ,  Tian Sheng ,  Nan Wei ,  Sufan Wang ,  Tao Zhou . 过渡金属/氧化物催化CO2加H2还原生成甲醇的甲酸盐与甲酰基路径的前线轨道对称性分析. University Chemistry, 2026, 41(9): 405-411. doi: 10.12461/PKU.DXHX202508059

    8. [8]

      Bin Liu . Teaching case design of chemistry “101 Plan” syntheticchemistry experiment course: taking the experiment of preparation of platinum nanocatalyst supported on carbon and determination of its electrochemical catalytic performance of methanol oxidation as an example. University Chemistry, 2026, 41(6): 125-135. doi: 10.12461/PKU.DXHX202506043

    9. [9]

      Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071

    10. [10]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    11. [11]

      Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO2 hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133

    12. [12]

      Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO2 by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420

    13. [13]

      Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 100026-0. doi: 10.3866/PKU.WHXB202405002

    14. [14]

      Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    15. [15]

      Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029

    16. [16]

      Yuying JIANG , Jia LUO , Zhan GAO . Development status and prospects of solid oxide cell high entropy electrode catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1719-1730. doi: 10.11862/CJIC.20250124

    17. [17]

      Jiayi Yang ,  Jianxiu Hao ,  Huacong Zhou ,  Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105

    18. [18]

      Yunbo ZHU , Linxiang ZHOU , Chaoyang SHI , Jie YU , Danyang WEI , Mingli XU . Stable Fe—P structure catalysts: Enabled by a strong coordination strategy and high-efficiency oxygen electrocatalysis performance. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 2021-2032. doi: 10.11862/CJIC.20260080

    19. [19]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    20. [20]

      Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

Get Citation
PDF
XML
Metrics
  • PDF Downloads(14)
  • Abstract views(2526)
  • HTML views(390)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return