Citation: Shi Lei, Pang Hongwei, Wang Xiangxue, Zhang Pan, Yu Shujun. Study on the Migration and Transformation Mechanism of Graphene Oxide in Aqueous Solutions[J]. Acta Chimica Sinica, ;2019, 77(11): 1177-1183. doi: 10.6023/A19070276 shu

Study on the Migration and Transformation Mechanism of Graphene Oxide in Aqueous Solutions

a.
MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China
b.
Heibei Key Lab of Power Plant Flue Gas Multi-Pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China

Corresponding author: Yu Shujun, sjyu@ncepu.edu.cn
Received Date: 26 July 2019
Available Online: 24 November 2019

Figures(5)

Graphene oxide (GO) is widely used in energy chemical, environmental restoration, nanomaterials, liquid phase catalysis, etc. due to its excellent physical and chemical properties. At the same time, GO is inevitably discharged into nature during the application process, and the toxicity released into the environment may lead to instability of the biological system. Therefore, this paper systematically studied several common cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), anions (PO₄^3-, SO₄^2-, CO₃^2-, HCO₃^-, Cl^-) and clay minerals (montmorillonite, kaolin, bentonite, nano-alumina) on GO coagulation at different concentrations. And FTIR is used to characterize the clay minerals before and after the precipitation of GO. The experimental results show that the cations have strong GO coagulation ability, and the coagulation ability of different valence cations has a large difference. After analysis, the electrical properties of GO in aqueous solution are negative, the cation acts as a counter ion, and the coagulation behavior conforms to the Schulze-Hardy rule. The main reason for the difference in coagulation ability between isovalent cations is electronegativity and ionic hydration. The anion acts to increase the stability of GO, and the coagulation ability of the cation is more effective than the stabilization ability of the anion. The ability of sodium salts with the same valence anion to coagulate GO also differs, mainly because the hydrolysis of HCO₃^- and CO₃^2- causes a decrease in the negative charges, resulting in a decrease in the ability to stabilize GO. The clay minerals contain hydroxyl and metal-oxygen bonds that interact with GO. According to the maximum removal rate, the clay minerals have the coagulation ability:nano-alumina > kaolin > bentonite > montmorillonite. The main influencing factors are the electrical properties of clay minerals in aqueous solution. This paper is helpful to understand the coagulation behavior of GO in different water environments, and it is of great significance for the future application of graphene engineering in pollution control.
- graphene oxide,
- coagulation,
- cation,
- anion,
- clay mineral
1. [1]
  Loh, K. P.; Bao, Q. L.; Ang, P. K.; Yang, J. X. J. Mater. Chem. 2010, 20, 2277. doi: 10.1039/b920539j
2. [2]
  Dreyer, D. R.; Park, S. J.; Bielawski, C. W.; Ruoff, R. S. Chem. Soc. Rev. 2010, 39, 228. doi: 10.1039/B917103G
3. [3]
  Chen, D.; Feng, H.; Li, J. Chem. Rev. 2012, 112, 6027. doi: 10.1021/cr300115g
4. [4]
  Stoller, M. D.; Park, S. J.; Zhu, Y. W.; An, j.; Ruoff, R. S. Nano Lett. 2008, 8, 3498. doi: 10.1021/nl802558y
5. [5]
  Zhao, K. L.; Hao, Y.; Zhu, M.; Cheng, G. S. Acta Chim. Sinica. 2018, 76, 168(in Chinese). doi: 10.3866/PKU.WHXB201707111
6. [6]
  Zhang, S. W.; Zhang, J.; Wu, S. D.; lv, W.; Kang, F. Y.; Yang, Q. H. Acta. Chim. Sinica. 2017, 75, 163(in Chinese). doi: 10.11862/CJIC.2017.023
7. [7]
  Zhong, G. Y.; Wang, H. J.; Yu, H.; Peng, F. Acta Chim. Sinica. 2017, 75, 943(in Chinese).
8. [8]
  Wang, X.; Li, Y. B.; Du, L. Y.; Gao, F. J.; Wu, Q.; Yang, L. J.; Chen, Q.; Wang, X. J.; Hu, Z. Acta Chim. Sinica. 2018, 76, 627(in Chinese). doi: 10.11862/CJIC.2018.081
9. [9]
  Lu, J. H.; Tan, S. Z.; Zhu, Y. Q.; Li, W.; Chen, T. X.; Wang, Y.; Liu, C. Acta Chim. Sinica. 2019, 77, 253(in Chinese).
10. [10]
  Ma, W. H.; Chang, Y. Z.; Han, G. Y.; Xiao, Y. M.; Fu, D. Y.; Chang, Y. H.; Chinese J. Chem. 2017, 35, 1844. doi: 10.1002/cjoc.201700398
11. [11]
  Yang, X. L.; Cai, H. Y.; Bao, M. Y.; Yu, J. Q.; Lu, J. R.; Li, Y. M. Chinese J. Chem. 2017, 35, 1549. doi: 10.1002/cjoc.201700202
12. [12]
  Li, M. Y.; Liu, R. Q.; Han, G. Y.; Tian, Y. N.; Chang, Y. Z.; Xiao, Y. M. Chinese J. Chem. 2017, 35, 1405. doi: 10.1002/cjoc.201700061
13. [13]
  Song, C. Y.; Sun, X.; Ye, K.; Zhu, K.; Cheng, H.; Yan, J.; Cao, D. X.; Wang, G. L. Acta. Chim. Sinica. 2017, 75, 1003(in Chinese).
14. [14]
  Liao, K. H.; Lin, Y. S.; Macosko, C. W.; Haynes, C. L. ACS Appl. Mater. Interfaces 2011, 3, 2607. doi: 10.1021/am200428v
15. [15]
  Gao, Y.; Chen, K.; Ren, X. M.; Ahmed, A.; Tasawar, H.; Chen, C. L. Environ. Sci. Technol. 2018, 52, 12208. doi: 10.1021/acs.est.8b02234
16. [16]
  Gao, Y; Wu, J. C.; Ren, X. M.; Tan X. L.; Tasawar, H.; Ahmed, A.; Cheng, C.; Chen, C. L. Environ. Sci.:Nano 2017, 4, 1016. doi: 10.1039/C7EN00052A
17. [17]
  Gao, Y.; Ren, X. M.; Wu, J. C.; Tasawar, H.; Ahmed, A.; Cheng, C.; Chen, C. l. Environ. Sci.:Nano 2018, 5, 362. doi: 10.1039/C7EN01012E
18. [18]
  Wang, J.; Yao, W.; Gu, P. C.; Yu, S. J.; Wang, X. X.; Du, Y.; Wang, H. Q.; Chen, Z. S.; Hayat, T.; Wang, X. K. Cellulose 2016, 24, 85.
19. [19]
  Vallabani, N. V. S.; Mittal, S.; Shukla, R. K.; Pandey, A. K.; Dhakate, S. R.; Pasricha, R.; Dhawan, A. J. Biomed. Nanotechnol. 2011, 7, 106. doi: 10.1166/jbn.2011.1224
20. [20]
  Akhavan, O.; Ghaderi, E. ACS Nano 2010, 4, 5731. doi: 10.1021/nn101390x
21. [21]
  Hu, J.; Zhang, C. X.; Jiang, L.; Fang, S. D.; Zhang, X. D.; Wang, X. K.; Meng, Y. D. J. Power Sources 2014, 248, 831. doi: 10.1016/j.jpowsour.2013.09.099
22. [22]
  Zaghouane-Boudiaf, H.; Boutahala, M.; Arab, L. Chem. Eng. J. 2012, 187, 142. doi: 10.1016/j.cej.2012.01.112
23. [23]
  Wang, J.; Wang, X. X.; Tan, L. Q.; Chen, Y. T.; Hayat, T.; Hu, J.; Alsaedi, A.; Ahmad, B.; Guo, W.; Wang, X. K. Chem. Eng. J. 2016, 297, 106. doi: 10.1016/j.cej.2016.04.012
24. [24]
  Meunier, N.; Drogui, P.; Montane, C.; Hausler, R.; Mercier, G.; Blais, J. F. J. Hazard. Mater. 2006, 137, 581. doi: 10.1016/j.jhazmat.2006.02.050
25. [25]
  Qiang, S. R.; Wang, M. Y.; Liang, J. J.; Zhao, X. L.; Fan, Q. H.; Geng, R. Y.; Luo, D. X.; Li, Z. B.; Zhang, L. Mater. Chem. Phys. 2020, 239, 122016. doi: 10.1016/j.matchemphys.2019.122016
26. [26]
  Yang, K. J.; Chen, B. L.; Zhu, X. Y.; Xing, B. S. Environ. Sci. Technol. 2016, 50, 11066. doi: 10.1021/acs.est.6b04235
27. [27]
  Chowdhury, I.; Mansukhani, N. D.; Guiney, L. M.; Hersam, M. C.; Bouchard, D. Environ. Sci. Technol. 2015, 49, 10886. doi: 10.1021/acs.est.5b01866
28. [28]
  Zeng, Z. Y.; Wang, Y. L.; Zhou, Q. B.; Yang, K.; Lin, D. H. Environ. Pollut. 2019, 250, 366. doi: 10.1016/j.envpol.2019.03.112
29. [29]
  Zhao, J.; Liu, F. F.; Wang, Z. Y.; Cao, X. S.; Xing, B. S. Environ. Sci. Technol. 2015, 49:2849. doi: 10.1021/es505605w
30. [30]
  Liang, J. J.; Li, P.; Zhao, X. L.; Liu, Z. Y.; Fan, Q. H.; Li, Z.; Wang, D. Q. Nanoscale 2018, 3, 1383.
31. [31]
  Park, C. M.; Chu, K. H.; Heo, J.; Her, N.; Jang, M.; Son, A.; Yoon, Y. J. Hazard. Mater. 2016, 309, 133. doi: 10.1016/j.jhazmat.2016.02.006
32. [32]
  Li, N.; Ma, J. Z.; Bao, Y. Chem. Res. 2009, 20, 98(in Chinese).
33. [33]
  Huang, G. X.; Guo, H. Y.; Zhao, J.; Liu, Y. H.; Xing, B. S. Water Res. 2012, 102, 313.
34. [34]
  Anirudhan, T. S.; Ramachandran, M. Proc. Saf. Environ. Prot. 2015, 95, 215. doi: 10.1016/j.psep.2015.03.003
35. [35]
  Chowdhury, I.; Duch, M. C.; Mansukhani, N. D.; Hersam, M. C.; Bouchard, D. Environ. Sci. Technol. 2013, 47, 6288. doi: 10.1021/es400483k
36. [36]
  Wu, L.; Liu, L.; Gao, B.; Muñoz-Carpena, R.; Zhang, M.; Chen, H.; Zhou, Z. H.; Wang, H. Langmuir 2013, 29, 15174. doi: 10.1021/la404134x
37. [37]
  Ma, J. C.; Dougherty, D. A. Chem. Rev. 1997, 97, 1303. doi: 10.1021/cr9603744
38. [38]
  Trivedi, P.; Axe, L.; Dyer, J. Colloids Surf. A 2001, 191, 107. doi: 10.1016/S0927-7757(01)00768-3
39. [39]
  Raza, G.; Amjad, M.; Kaur, I.; Wen, D. Environ. Sci. Technol. 2016, 50, 8462. doi: 10.1021/acs.est.5b05746
40. [40]
  Volkov, A. G.; Paula, D. W.; Dreamer, D. W. Bioelectrochem. Bioenerg. 1997, 42, 153. doi: 10.1016/S0302-4598(96)05097-0
41. [41]
  Tansel, B.; Sager, J.; Rector, T.; Garland, J.; Strayer, R. F.; Levine, L. F.; Roberts, M.; Hummerick, M.; Bauer, J. Sep. Purif. Technol. 2006, 51, 40. doi: 10.1016/j.seppur.2005.12.020
42. [42]
  Abdelmeguid, A. E.; Aboelfetoh, E. F.; Ebeid, E. M. Chemosphere 2017, 181, 738. doi: 10.1016/j.chemosphere.2017.04.137
43. [43]
  Tahir, S. S.; Rauf, N. Chemosphere 2006, 63, 1842. doi: 10.1016/j.chemosphere.2005.10.033
44. [44]
  Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
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