Citation: Li Zhao, Wang Zhong, Ban Liqin, Wang Jiantao, Lu Shigang. Recent Advances on Surface Modification of Li- and Mn-Rich Cathode Materials[J]. Acta Chimica Sinica, ;2019, 77(11): 1115-1128. doi: 10.6023/A19070265 shu

Recent Advances on Surface Modification of Li- and Mn-Rich Cathode Materials

Li Zhao ^a,b,c ,
Wang Zhong ^a,b,c,, ,
Ban Liqin ^a,b,c ,
Wang Jiantao ^a,b,c ,
Lu Shigang ^a,b,c

a.
National Power Battery Innovation Center, GRINM Group Co., Ltd, Beijing 100088, China
b.
China Automotive Battery Research Institute Co., Ltd., Beijing 100088, China
c.
General Research Institute for Nonferrous Metals, Beijing 100088, China

Corresponding author: Wang Zhong, wzwz99@126.com
Received Date: 16 July 2019
Available Online: 4 November 2019
Fund Project: the Natural Science Foundation-the Joint Foundation of China U1764255Project supported by the National Key Research and Development Program of China (No. 2018YFB0104400) and the Natural Science Foundation-the Joint Foundation of China (No. U1764255)the National Key Research and Development Program of China 2018YFB0104400

Figures(7)

With the rapid development of electric cars and energy storage power stations, there is an increasing demand for lithium ion batteries with high energy density. Li- and Mn-rich (LMR) cathode materials with large specific capacity (>250 mAh·g^-1) are supposed to accomplish lithium ion batteries with high energy density (>350 Wh·kg^-1). The high capacity performance of LMR cathode materials are resulted from the lattice oxygen redox reaction induced by the electrochemical activation of the Li₂MnO₃ phase. However, the activation of the Li₂MnO₃ phase and oxygen redox reaction lead to lattice oxygen release and structure transformation, which cause some serious problems such as low initial columbic efficiency, poor rate capability, voltage and capacity degradation after subsequent cycles. The oxygen release and structure transformation always start from the surface, indicating that the surface stability is significant to LMR cathode materials. In this paper, surface modifications such as surface coating, surface doping and surface chemical treatment are reviewed and the mechanism of three surface modification methods for LMR cathode materials are discussed in further. Surface coating is one of the most widely surface modification methods, which can suppress the electrode/electrolyte side reaction and reduce the transition metal dissolution. The effect of surface coating on improving electrochemical performance of LMR cathode materials is always determined by the characteristic of coating layer materials including non-active coating layer, electrochemical active coating layer, Li⁺ conductive coating layer and electronic conductive coating layer. Surface doping has shown to be an effective method in suppressing oxygen release and structural transformation. Surface chemical treatment has resulted in reducing irreversible capacity loss by activating Li₂MnO₃ phase. On this basis, surface integrated strategies combined several surface modified methods are introduced and discussed in recent years. The surface intergrated strategies not only enhance the structural stability and suppress electrode/electrolyte surface-interface reaction, but also have an effective role on mitigating structure transformation and lattice oxygen release. Finally, we wish that our review would provide research directions for surface modified strategies of LMR cathode materials in future.
- Li- and Mn-rich cathode materials,
- surface coating,
- surface doping,
- surface chemical treatment,
- surface integrated strategies
1. [1]
  Goodenough, J. B. Energy Storage Mater. 2015, 1, 158. doi: 10.1016/j.ensm.2015.07.001
2. [2]
  Kalluri, S.; Yoon, M.; Jo, M.; Park, S.; Myeong, S.; Kim, J.; Dou, S. X.; Guo, Z.; Cho, J. Adv. Energy Mater. 2017, 7, 1601507. doi: 10.1002/aenm.201601507
3. [3]
  Deng, B.; Sun, W.; Wang, H.; Chen, T.; Li, X.; Qu, M.; Peng, G. Acta Chim. Sinica 2018, 76, 259(in Chinese).
4. [4]
  Zheng, Z.; Wu, Z.; Xiang, W.; Guo, X. Acta Chim. Sinica 2017, 75, 501(in Chinese). doi: 10.11862/CJIC.2017.053
5. [5]
  Hua, W.; Wang, Y.; Zhong, Y.; Wang, G.; Zhong, B.; Fang, B.; Guo, X.; Liao, S.; Wang, H. Chin. J. Chem. 2015, 33, 261. doi: 10.1002/cjoc.201400551
6. [6]
  Wen, L.; Pilgun, O.; Xien, L.; Min-Joon, L.; Woongrae, C.; Sujong, C.; Youngsik, K.; Jaephil, C. Angew. Chem. 2015, 54, 4440. doi: 10.1002/anie.201409262
7. [7]
  Hou, P.; Yin, J.; Ding, M.; Huang, J.; Xu, X. Small 2017, 13, 1701802. doi: 10.1002/smll.201701802
8. [8]
  Manthiram, A.; Knight, J. C.; Myung, S. T.; Oh, S. M.; Sun, Y. K. Adv. Energy Mater. 2016, 6, 1501010. doi: 10.1002/aenm.201501010
9. [9]
  Erickson, E. M.; Schipper, F.; Penki, T. R.; Shin, J. Y.; Erk, C.; Chesneau, F. F.; Markovsky, B.; Aurbach, D. J. Electrochem. Soc. 2017, 164, A6220. doi: 10.1149/2.0351701jes
10. [10]
  Kim, J.; Lee, H.; Cha, H.; Yoon, M.; Park, M.; Cho, J. Adv. Energy Mater. 2018, 8, 1702028. doi: 10.1002/aenm.201702028
11. [11]
  Numata, K.; Sakaki, C.; Yamanaka, S. Chem. Lett. 1997, 1997, 725.
12. [12]
  Numata, K.; Sakaki, C.; Yamanaka, S. Solid State Ionics 1999, 117, 257. doi: 10.1016/S0167-2738(98)00417-2
13. [13]
  Lu, Z. H.; Macneil, D. D.; Dahn, J. R. Electrochem. Solid-State Lett. 2001, 7, A503.
14. [14]
  Johnson, C. S.; Kim, J. S.; Lefief, C.; Li, N.; Vaughey, J. T.; Thackeray, M. M. Electrochem. Commun. 2004, 6, 1085. doi: 10.1016/j.elecom.2004.08.002
15. [15]
  Thackeray, M. M.; Johnson, C. S.; Vaughey, J. T.; Li, N.; Hackney, S. A. J. Mater. Chem. 2005, 15, 2257. doi: 10.1039/b417616m
16. [16]
  Thackeray, M. M.; Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Benedek, R.; Hackney, S. A. J. Mater. Chem. 2007, 17, 3112. doi: 10.1039/b702425h
17. [17]
  Wang, Z.; Yin, Y.; Ren, Y.; Wang, Z.; Gao, M.; Ma, T.; Zhuang, W.; Lu, S.; Fan, A.; Amine, K. Nano Energy 2017, 31, 247. doi: 10.1016/j.nanoen.2016.10.014
18. [18]
  Nayak, P. K.; Erickson, E. M.; Schipper, F.; Penki, T. R.; Munichandraiah, N.; Adelhelm, P.; Sclar, H.; Amalraj, F.; Markovsky, B.; Aurbach, D. Adv. Energy Mater. 2018, 8, 1702397. doi: 10.1002/aenm.201702397
19. [19]
  Li, M.; Lu, J.; Chen, Z.; Amine, K. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561
20. [20]
  Zuo, Y.; Li, B.; Jiang, N.; Chu, W.; Zhang, H.; Zou, R.; Xia, D. Adv. Mater. 2018, 30, 1707255. doi: 10.1002/adma.201707255
21. [21]
  Zheng, J.; Myeong, S.; Cho, W.; Yan, P.; Xiao, J.; Wang, C.; Cho, J.; Zhang, J. G. Adv. Energy Mater. 2016, 7, 1601284.
22. [22]
  Assat, G.; Tarascon, J.-M. Nat. Energy 2018, 3, 373. doi: 10.1038/s41560-018-0097-0
23. [23]
  Yang, C.; Gong, Z.; Zhao, W.; Yang, Y. Acta Chim. Sinica 2017, 75, 212(in Chinese). doi: 10.7503/cjcu20160458
24. [24]
  Gauthier, M.; Carney, T. J.; Grimaud, A.; Giordano, L.; Pour, N.; Chang, H. H.; Fenning, D. P.; Lux, S. F.; Paschos, O.; Bauer, C. J. Phys. Chem. Lett. 2015, 6, 4653. doi: 10.1021/acs.jpclett.5b01727
25. [25]
  Xu, B.; Fell, C. R.; Chi, M.; Meng, Y. S. Energy Environ. Sci. 2011, 4, 2223. doi: 10.1039/c1ee01131f
26. [26]
  Oh, P.; Ko, M.; Myeong, S.; Kim, Y.; Cho, J. Adv. Energy Mater. 2014, 4, 1400631. doi: 10.1002/aenm.201400631
27. [27]
  Yan, P.; Nie, A.; Zheng, J.; Zhou, Y.; Lu, D.; Zhang, X.; Xu, R.; Belharouak, I.; Zu, X.; Xiao, J. Nano Lett. 2015, 15, 514. doi: 10.1021/nl5038598
28. [28]
  Croy, J. R.; Balasubramanian, M.; Gallagher, K. G.; Burrell, A. K. Acc. Chem. Res. 2015, 48, 2813. doi: 10.1021/acs.accounts.5b00277
29. [29]
  Kim, J.-S.; Johnson, C. S.; Vaughey, J. T.; Thackeray, M. M.; Hackney, S. A.; Yoon, W.; Grey, C. P. Chem. Mater. 2004, 16, 1996. doi: 10.1021/cm0306461
30. [30]
  Kang, S. H.; Kempgens, P.; Greenbaum, S.; Kropf, A. J.; Amine, K.; Thackeray, M. M. J. Mater. Chem. 2007, 17, 2069. doi: 10.1039/B618715C
31. [31]
  Jarvis, K. A.; Deng, Z.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Chem. Mater. 2011, 23, 3614. doi: 10.1021/cm200831c
32. [32]
  Mccalla, E.; Lowartz, C. M.; Brown, C. R.; Dahn, J. R. Chem. Mater. 2013, 25, 912. doi: 10.1021/cm304002b
33. [33]
  Shunmugasundaram, R.; Senthil Arumugam, R.; Dahn, J. R. Chem. Mater. 2015, 27, 757. doi: 10.1021/cm504583y
34. [34]
  Shunmugasundaram, R.; Senthil Arumugam, R.; Harris, K. J.; Goward, G. R.; Dahn, J. R. Chem. Mater. 2016, 28, 55. doi: 10.1021/acs.chemmater.5b02104
35. [35]
  Zheng, J.; Xu, P.; Gu, M.; Xiao, J.; Browning, N. D.; Yan, P.; Wang, C.; Zhang, J.-G. Chem. Mater. 2015, 27, 1381. doi: 10.1021/cm5045978
36. [36]
  Gu, M.; Belharouak, I.; Zheng, J.; Wu, H.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J.-G. ACS Nano 2013, 7, 760. doi: 10.1021/nn305065u
37. [37]
  Hong, J.; Seo, D. H.; Kim, S. W.; Gwon, H.; Oh, S. T.; Kang, K. J. Mater. Chem. 2010, 20, 10179. doi: 10.1039/c0jm01971b
38. [38]
  Xiao, B.; Sun, X. Adv. Energy Mater. 2018, 8, 1802057. doi: 10.1002/aenm.201802057
39. [39]
  Hu, E.; Yu, X.; Lin, R.; Bi, X.; Lu, J.; Bak, S.; Nam, K.-W.; Xin, H. L.; Jaye, C.; Fischer, D. A.; Amine, K.; Yang, X.-Q. Nat. Energy 2018, 3, 690. doi: 10.1038/s41560-018-0207-z
40. [40]
  Dai, K.; Wu, J.; Zhuo, Z.; Li, Q.; Sallis, S.; Mao, J.; Ai, G.; Sun, C.; Li, Z.; Gent, W. E.; Chueh, W. C.; Chuang, Y.-d.; Zeng, R.; Shen, Z.-x.; Pan, F.; Yan, S.; Piper, L. F. J.; Hussain, Z.; Liu, G.; Yang, W. Joule 2019, 3, 518. doi: 10.1016/j.joule.2018.11.014
41. [41]
  Zheng, J.; Myeong, S.; Cho, W.; Yan, P.; Xiao, J.; Wang, C.; Cho, J.; Zhang, J. G. Adv. Energy Mater. 2017, 7, 1601284. doi: 10.1002/aenm.201601284
42. [42]
  Shi, S. J.; Tu, J. P.; Tang, Y. Y.; Liu, X. Y.; Zhang, Y. Q.; Wang, X. L.; Gu, C. D. Electrochim. Acta 2013, 88, 671. doi: 10.1016/j.electacta.2012.10.111
43. [43]
  Han, E.; Li, Y.; Zhu, L.; Zhao, L. Solid State Ionics 2014, 255, 113. doi: 10.1016/j.ssi.2013.12.018
44. [44]
  Yan, P.; Zheng, J.; Zhang, X.; Xu, R.; Amine, K.; Xiao, J.; Zhang, J.-G.; Wang, C.-M. Chem. Mater. 2016, 28, 857. doi: 10.1021/acs.chemmater.5b04301
45. [45]
  Kobayashi, G.; Irii, Y.; Matsumoto, F.; Ito, A.; Ohsawa, Y.; Yamamoto, S.; Cui, Y.; Son, J. Y.; Sato, Y. J. Power Sources 2016, 303, 250. doi: 10.1016/j.jpowsour.2015.11.014
46. [46]
  Lee, G.-H.; Choi, I. H.; Oh, M. Y.; Park, S. H.; Nahm, K. S.; Aravindan, V.; Lee, Y.-S. Electrochim. Acta 2016, 194, 454. doi: 10.1016/j.electacta.2016.02.129
47. [47]
  Xie, Y.; Chen, S.; Lin, Z.; Yang, W.; Zou, H.; Sun, R. W.-Y. Electrochem. Commun. 2019, 99, 65. doi: 10.1016/j.elecom.2019.01.005
48. [48]
  Mu, K.; Cao, Y.; Hu, G.; Du, K.; Yang, H.; Gan, Z.; Peng, Z. Electrochim. Acta 2018, 273, 88. doi: 10.1016/j.electacta.2018.04.027
49. [49]
  Chen, C.; Geng, T.; Du, C.; Zuo, P.; Cheng, X.; Ma, Y.; Yin, G. J. Power Sources 2016, 331, 91. doi: 10.1016/j.jpowsour.2016.09.051
50. [50]
  Rastgoo-Deylami, M.; Javanbakht, M.; Omidvar, H. Solid State Ionics 2019, 331, 74. doi: 10.1016/j.ssi.2018.12.025
51. [51]
  Zheng, J. M.; Zhang, Z. R.; Wu, X. B.; Dong, Z. X.; Zhu, Z.; Yang, Y. J. Electrochem. Soc. 2008, 155, A775. doi: 10.1149/1.2966694
52. [52]
  Zheng, J.; Gu, M.; Xiao, J.; Polzin, B. J.; Yan, P.; Chen, X.; Wang, C.; Zhang, J.-G. Chem. Mater. 2014, 26, 6320. doi: 10.1021/cm502071h
53. [53]
  Pang, S.; Wang, Y.; Chen, T.; Shen, X.; Xi, X.; Liao, D. Ceram. Int. 2016, 42, 5397. doi: 10.1016/j.ceramint.2015.12.076
54. [54]
  Hu, G.; Qi, X.; Hu, K.; Lai, X.; Zhang, X.; Du, K.; Peng, Z.; Cao, Y. Electrochim. Acta 2018, 265, 391. doi: 10.1016/j.electacta.2018.01.176
55. [55]
  Sun, S.; Wan, N.; Wu, Q.; Zhang, X.; Pan, D.; Bai, Y.; Lu, X. Solid State Ionics 2015, 278, 85. doi: 10.1016/j.ssi.2015.05.021
56. [56]
  Liu, X.; Huang, T.; Yu, A. Electrochim. Acta 2015, 163, 82. doi: 10.1016/j.electacta.2015.02.155
57. [57]
  Liu, H.; Qian, D.; Verde, M. G.; Zhang, M.; Baggetto, L.; An, K.; Chen, Y.; Carroll, K. J.; Lau, D.; Chi, M.; Veith, G. M.; Meng, Y. S. ACS Appl. Mater. Interfaces 2015, 7, 19189. doi: 10.1021/acsami.5b04932
58. [58]
  Lu, C.; Wu, H.; Zhang, Y.; Liu, H.; Chen, B.; Wu, N.; Wang, S. J. Power Sources 2014, 267, 682. doi: 10.1016/j.jpowsour.2014.05.122
59. [59]
  Wu, Y.; Murugan, A. V.; Manthiram, A. J. Electrochem. Soc. 2008, 155, A635. doi: 10.1149/1.2948350
60. [60]
  Ma, J.; Li, B.; An, L.; Wei, H.; Wang, X.; Yu, P.; Xia, D. J. Power Sources 2015, 277, 393. doi: 10.1016/j.jpowsour.2014.11.133
61. [61]
  Xiao, B.; Wang, B.; Liu, J.; Kaliyappan, K.; Sun, Q.; Liu, Y.; Dadheech, G.; Balogh, M. P.; Yang, L.; Sham, T.-K. Nano Energy 2017, 34, 120. doi: 10.1016/j.nanoen.2017.02.015
62. [62]
  Xie, Q.; Zhao, C.; Hu, Z.; Huang, Q.; Chen, C.; Liu, K. RSC Adv. 2015, 5, 77324. doi: 10.1039/C5RA13233A
63. [63]
  Chen, J.; Li, Z.; Xiang, H.; Wu, W.; Cheng, S.; Zhang, L.; Wang, Q.; Wu, Y. RSC Adv. 2015, 5, 3031. doi: 10.1039/C4RA11370E
64. [64]
  Wu, F.; Li, N.; Su, Y.; Lu, H.; Zhang, L.; An, R.; Wang, Z.; Bao, L.; Chen, S. J. Mater. Chem. 2012, 22, 1489. doi: 10.1039/C1JM14459F
65. [65]
  Liu, Y.; Liu, S.; Wang, Y.; Chen, L.; Chen, X. J. Power Sources 2013, 222, 455. doi: 10.1016/j.jpowsour.2012.09.014
66. [66]
  Guo, S.; Yu, H.; Liu, P.; Liu, X.; Li, D.; Chen, M.; Ishida, M.; Zhou, H. J. Mater. Chem. A 2014, 2, 4422. doi: 10.1039/c3ta15206e
67. [67]
  Jin, Y.; Xu, Y.; Sun, X.; Xiong, L.; Mao, S. Appl. Surf. Sci. 2016, 384, 125. doi: 10.1016/j.apsusc.2016.04.136
68. [68]
  He, H.; Zan, L.; Zhang, Y. J. Alloys Compd. 2016, 680, 95. doi: 10.1016/j.jallcom.2016.04.115
69. [69]
  Jin, Y.; Xu, Y.; Xiong, L.; Sun, X.; Li, L.; Li, L. Solid State Ionics 2017, 310, 62. doi: 10.1016/j.ssi.2017.07.012
70. [70]
  Li, Y.; Huang, H.; Yu, J.; Xia, Y.; Liang, C.; Gan, Y.; Zhang, J.; Zhang, W. J. Alloys Compd. 2019, 783, 349. doi: 10.1016/j.jallcom.2018.12.357
71. [71]
  Wang, Z.; Liu, E.; He, C.; Shi, C.; Li, J.; Zhao, N. J. Power Sources 2013, 236, 25. doi: 10.1016/j.jpowsour.2013.02.022
72. [72]
  Wang, Z.; Lu, H.-Q.; Yin, Y.-P.; Sun, X.-Y.; Bai, X.-T.; Shen, X.-L.; Zhuang, W.-D.; Lu, S.-G. Rare Metals 2017, 36, 899. doi: 10.1007/s12598-015-0647-6
73. [73]
  Zhao, T.; Li, L.; Chen, R.; Wu, H.; Zhang, X.; Chen, S.; Xie, M.; Wu, F.; Lu, J.; Amine, K. Nano Energy 2015, 15, 164. doi: 10.1016/j.nanoen.2015.04.013
74. [74]
  Bian, X.; Fu, Q.; Bie, X.; Yang, P.; Qiu, H.; Pang, Q.; Chen, G.; Du, F.; Wei, Y. Electrochim. Acta 2015, 174, 875. doi: 10.1016/j.electacta.2015.06.085
75. [75]
  Chen, D.; Zheng, F.; Li, L.; Chen, M.; Zhong, X.; Li, W.; Lu, L. J. Power Sources 2017, 341, 147. doi: 10.1016/j.jpowsour.2016.11.020
76. [76]
  Lee, Y.; Lee, J.; Lee, K. Y.; Mun, J.; Lee, J. K.; Choi, W. J. Power Sources 2016, 315, 284. doi: 10.1016/j.jpowsour.2016.03.024
77. [77]
  Zhou, L.; Yin, Z.; Tian, H.; Ding, Z.; Li, X.; Wang, Z.; Guo, H. Appl. Surf. Sci. 2018, 456, 763. doi: 10.1016/j.apsusc.2018.06.114
78. [78]
  Martha, S. K.; Nanda, J.; Kim, Y.; Unocic, R. R.; Pannala, S.; Dudney, N. J. J. Mater. Chem. A 2013, 1, 5587. doi: 10.1039/c3ta10586e
79. [79]
  Kang, S. H.; Thackeray, M. M. Electrochem. Commun. 2009, 11, 748. doi: 10.1016/j.elecom.2009.01.025
80. [80]
  Qiao, Q. Q.; Zhang, H. Z.; Li, G. R.; Ye, S. H.; Wang, C. W.; Gao, X. P. J. Mater. Chem. A 2013, 1, 5262. doi: 10.1039/c3ta00028a
81. [81]
  Zheng, F.; Yang, C.; Xiong, X.; Xiong, J.; Hu, R.; Chen, Y.; Liu, M. Angew. Chem. Int. Ed. 2015, 54, 13058. doi: 10.1002/anie.201506408
82. [82]
  Chen, Y.; Xie, K.; Zheng, C.; Ma, Z.; Chen, Z. ACS Appl. Mater. Interfaces 2014, 6, 16888. doi: 10.1021/am504412n
83. [83]
  Li, H.; Zhou, H. Chem. Commun. 2012, 48, 1201. doi: 10.1039/C1CC14764A
84. [84]
  Xia, Q.; Zhao, X.; Xu, M.; Ding, Z.; Liu, J.; Chen, L.; Ivey, D. G.; Wei, W. J. Mater. Chem. A 2015, 3, 3995. doi: 10.1039/C4TA05848H
85. [85]
  Pang, S.; Xu, K.; Wang, Y.; Shen, X.; Wang, W.; Su, Y.; Zhu, M.; Xi, X. J. Power Sources 2017, 365, 68. doi: 10.1016/j.jpowsour.2017.08.077
86. [86]
  Park, K.; Kim, J.; Park, J.-H.; Hwang, Y.; Han, D. J. Power Sources 2018, 408, 105. doi: 10.1016/j.jpowsour.2018.10.001
87. [87]
  Ma, Y.; Liu, P.; Xie, Q.; Zhang, G.; Zheng, H.; Cai, Y.; Li, Z.; Wang, L.; Zhu, Z.-Z.; Mai, L. Nano Energy 2019, 59, 184. doi: 10.1016/j.nanoen.2019.02.040
88. [88]
  Wu, F.; Li, N.; Su, Y.; Shou, H.; Bao, L.; Yang, W.; Zhang, L.; An, R.; Chen, S. Adv. Mater. 2013, 25, 3722. doi: 10.1002/adma.201300598
89. [89]
  Wang, L.; Zhao, D.; Liu, X.; Yu, P.; Fu, H. Acta Chim. Sinica 2017, 75, 231(in Chinese). doi: 10.7503/cjcu20160577
90. [90]
  Li, Z.; Wang, Z.; Li, Q.; Ban, L.; Zhuang, W.; Lu, S. Chinese J. Inorg. Chem. 2019, 35, 1561(in Chinese). doi: 10.11862/CJIC.2019.192
91. [91]
  Song, B.; Lai, M. O.; Liu, Z.; Liu, H.; Lu, L. J. Mater. Chem. A 2013, 1, 9954. doi: 10.1039/c3ta11580a
92. [92]
  Zhang, J.; Lu, Q.; Fang, J.; Wang, J.; Yang, J.; Nuli, Y. ACS Appl. Mater. Interfaces 2014, 6, 17965. doi: 10.1021/am504796n
93. [93]
  Wu, C.; Fang, X.; Guo, X.; Mao, Y.; Ma, J.; Zhao, C.; Wang, Z.; Chen, L. J. Power Sources 2013, 231, 44. doi: 10.1016/j.jpowsour.2012.11.138
94. [94]
  Wang, D.; Wang, X.; Yang, X.; Yu, R.; Ge, L.; Shu, H. J. Power Sources 2015, 293, 89. doi: 10.1016/j.jpowsour.2015.05.058
95. [95]
  Wu, F.; Liu, J.; Li, L.; Zhang, X.; Luo, R.; Ye, Y.; Chen, R. ACS Appl. Mater. Interfaces 2016, 8, 23095. doi: 10.1021/acsami.6b07431
96. [96]
  Kim, I. T.; Knight, J. C.; Celio, H.; Manthiram, A. J. Mater. Chem. A 2014, 2, 8696. doi: 10.1039/c4ta00898g
97. [97]
  Chen, D.; Tu, W.; Chen, M.; Hong, P.; Zhong, X.; Zhu, Y.; Yu, Q.; Li, W. Electrochim. Acta 2016, 193, 45. doi: 10.1016/j.electacta.2016.02.043
98. [98]
  Liu, H.; Chen, C.; Du, C.; He, X.; Yin, G.; Song, B.; Zuo, P.; Cheng, X.; Ma, Y.; Gao, Y. J. Mater. Chem. A 2015, 3, 2634. doi: 10.1039/C4TA04823G
99. [99]
  Nayak, P. K.; Grinblat, J.; Levi, M.; Levi, E.; Kim, S.; Choi, J. W.; Aurbach, D. Adv. Energy Mater. 2016, 6, 1502398. doi: 10.1002/aenm.201502398
100. [100]
  Su, X.; Wang, X.; Chen, H.; Yu, Z.; Qi, J.; Tao, S.; Chu, W.; Song, L. Chin. J. Chem. 2017, 35, 1853. doi: 10.1002/cjoc.201700265
101. [101]
  Qing, R. P.; Shi, J. L.; Xiao, D. D.; Zhang, X. D.; Yin, Y. X.; Zhai, Y. B.; Gu, L.; Guo, Y. G. Adv. Energy Mater. 2016, 6, 1501914. doi: 10.1002/aenm.201501914
102. [102]
  Liu, S.; Liu, Z.; Shen, X.; Li, W.; Gao, Y.; Banis, M. N.; Li, M.; Chen, K.; Zhu, L.; Yu, R. Adv. Energy Mater. 2018, 8, 1802105. doi: 10.1002/aenm.201802105
103. [103]
  Zhang, X.; Cao, S.; Yu, R.; Li, C.; Huang, Y.; Wang, Y.; Wang, X.; Gairong, C. ACS Appl. Energy Mater. 2019, 2, 1563. doi: 10.1021/acsaem.8b02178
104. [104]
  Huang, J.; Liu, H.; Hu, T.; Meng, Y. S.; Luo, J. J. Power Sources 2018, 375, 21. doi: 10.1016/j.jpowsour.2017.11.048
105. [105]
  Zhao, Y.; Liu, J.; Wang, S.; Ji, R.; Xia, Q.; Ding, Z.; Wei, W.; Liu, Y.; Wang, P.; Ivey, D. G. Adv. Funct. Mater. 2016, 26, 4760. doi: 10.1002/adfm.201600576
106. [106]
  Shang, H.; Ning, F.; Li, B.; Zuo, Y.; Lu, S.; Xia, D. ACS Appl. Mater. Interfaces 2018, 10, 21349. doi: 10.1021/acsami.8b06271
107. [107]
  Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Amine, K.; Thackeray, M. M. J. Electrochem. Soc. 2006, 153.
108. [108]
  Paik, Y.; Grey, C. P.; Johnson, C. S.; Kim, J.-S.; Thackeray, M. M. Chem. Mater. 2002, 14, 5109. doi: 10.1021/cm0206385
109. [109]
  Benedek, R.; Thackeray, M. M.; Van De Walle, A. Chem. Mater. 2008, 20, 5485. doi: 10.1021/cm703042r
110. [110]
  Denis, Y.; Yanagida, K.; Nakamura, H. J. Electrochem. Soc. 2010, 157, A1177. doi: 10.1149/1.3479382
111. [111]
  Oh, P.; Myeong, S.; Cho, W.; Lee, M.-J.; Ko, M.; Jeong, H. Y.; Cho, J. Nano Lett. 2014, 14, 5965. doi: 10.1021/nl502980k
112. [112]
  Zhang, J.; Lei, Z.; Wang, J.; Nuli, Y.; Yang, J. ACS Appl. Mater. Interfaces 2015, 7, 15821. doi: 10.1021/acsami.5b02937
113. [113]
  Erickson, E. M.; Sclar, H.; Schipper, F.; Liu, J.; Tian, R.; Ghanty, C.; Burstein, L.; Leifer, N.; Grinblat, J.; Talianker, M. Adv. Energy Mater. 2017, 7, 1700708. doi: 10.1002/aenm.201700708
114. [114]
  Qiu, B.; Zhang, M.; Wu, L.; Wang, J.; Xia, Y.; Qian, D.; Liu, H.; Hy, S.; Chen, Y.; An, K.; Zhu, Y.; Liu, Z.; Meng, Y. S. Nat. Commun. 2016, 7, 12108. doi: 10.1038/ncomms12108
115. [115]
  Danna, Q.; Bo, X.; Miaofang, C.; Shirley, M. Y. Phys. Chem. Chem. Phys. 2014, 16, 14665. doi: 10.1039/C4CP01799D
116. [116]
  James, C.; Wu, Y.; Sheldon, B. W.; Qi, Y. Solid State Ionics 2016, 289, 87. doi: 10.1016/j.ssi.2016.02.019
117. [117]
  Huang, Z.; Xiong, T.; Lin, X.; Tian, M.; Zeng, W.; He, J.; Shi, M.; Li, J.; Zhang, G.; Mai, L. J. Power Sources 2019, 432, 8. doi: 10.1016/j.jpowsour.2019.05.069
118. [118]
  Liu, W.; Oh, P.; Liu, X.; Myeong, S.; Cho, W.; Cho, J. Adv. Energy Mater. 2015, 5, 1500274. doi: 10.1002/aenm.201500274
119. [119]
  Zhang, X. D.; Shi, J. L.; Liang, J. Y.; Yin, Y. X.; Zhang, J. N.; Yu, X. Q.; Guo, Y. G. Adv. Mater. 2018, 30, 1801751. doi: 10.1002/adma.201801751
120. [120]
  Cui, H.; Li, H.; Liu, J.; Zhang, Y.; Cheng, F.; Chen, J. Inorg. Chem. Front. 2019, 6, 1694. doi: 10.1039/C9QI00333A
121. [121]
  Guo, H.; Jia, K.; Han, S.; Zhao, H.; Qiu, B.; Xia, Y.; Liu, Z. Adv. Mater. Interfaces 2018, 5, 1701465. doi: 10.1002/admi.201701465
122. [122]
  Li, Q.; Zhou, D.; Zhang, L.; Ning, D.; Chen, Z.; Xu, Z.; Gao, R.; Liu, X.; Xie, D.; Schumacher, G. Adv. Funct. Mater. 2019, 29, 1806706. doi: 10.1002/adfm.201806706
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
3. [3]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
4. [4]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Yuan Chun , Yongmei Liu , Fuping Tian , Hong Yuan , Shu'e Song , Wanchun Zhu , Yunchao Li , Zhongyun Wu , Xiaokui Wang , Yunshan Bai , Li Wang , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Colloidal and Surface Chemical Properties, Molecular Structure and Properties. University Chemistry, 2025, 40(5): 178-188. doi: 10.12461/PKU.DXHX202503053
7. [7]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
8. [8]
  Meng Lin , Heng Zhang , Shiling Yuan . Exploring a Combined Theory-Practice-Simulation Teaching Model in Physical Chemistry: A Case Study of Surface Tension. University Chemistry, 2025, 40(4): 189-194. doi: 10.12461/PKU.DXHX202407053
9. [9]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
10. [10]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
11. [11]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073
12. [12]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
13. [13]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
14. [14]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
15. [15]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . NH₂-UIO-66 Based Hydrophobic Porous Liquid with High Mass Transfer and Affinity Surface for Enhancing CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-0. doi: 10.3866/PKU.WHXB202403032
16. [16]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
17. [17]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
18. [18]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
19. [19]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
20. [20]
  Xia Shu , Longtian Sima , Jiali Wang , Jiacheng Chu , Xieyidai·Yusunjiang , Mubareke·Maimaitijiang , Yingwei Lu , Yan Wang . Analysis of the Report Generated by the QuadraSorb evo BET Surface Area Analyzer. University Chemistry, 2025, 40(5): 391-400. doi: 10.12461/PKU.DXHX202411013

Get Citation

PDF

XML

Metrics

PDF Downloads(70)
Abstract views(3846)
HTML views(1253)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142