Citation: Qu Luping, Ren Tong, Wang Ning, Shi Yueli, Zhuang Quanchao. Electrochemical Impedance Spectroscopy Study on the First Sodium Insertion Process of Hard Carbon Material Electrode[J]. Acta Chimica Sinica, ;2019, 77(7): 634-640. doi: 10.6023/A19030103 shu

Electrochemical Impedance Spectroscopy Study on the First Sodium Insertion Process of Hard Carbon Material Electrode

Lithium Ion Battery Laboratory, Engineering Laboratory of High Efficiency Energy Storage Technology & Equipments, Jiangsu Provincial, School of Materials Science & Engineering, China University of Mining & Technology, Xuzhou 221116

Corresponding author: Zhuang Quanchao, zhuangquanchao@126.com
Received Date: 29 March 2019
Available Online: 12 July 2019

Figures(8)

In this study, electrochemical impedance spectroscopy (EIS) combined with cyclic volt-ampere (CV), charge-discharge measurement and scanning electron microscope were used. The electrode interface characteristics of hard carbon electrodes for sodium ion batteries in 1 mol/L NaClO₄-EC:DEC and 1 mol/L-NaClO₄-EC:DEC:PC electrolyte systems were discussed. The hard carbon material electrode is composed of 80 wt% active material, 10 wt% PVDF-HFP adhesive and 10 wt% conductive carbon black. The charge and discharge performance was tested with 2032 button battery and metal sodium sheet as counter electrode, the charge and discharge rate was 0.1 C, and the cut-off voltage was 0~3 V. The three-electrode glass cell system was used for CV and EIS test, and the metal sodium sheet was used as the reference and auxiliary electrode. In the CV test, the scanning speed is 1 mV/s, EIS and the frequency scanning range is 10⁵ to 10^-2 Hz. The amplitude of AC signal applied by 2 mV is 5 mV. The electrochemical impedance spectra obtained in the experiment were simulated by Zview software. The results of CV show that the intercalation process of sodium ion in hard carbon materials is mainly divided into two steps, that is, the filling process of sodium ion in nano-pores, the intercalation of sodium ion in graphene layer and the adsorption and desorption of sodium ion on the surface or defect. The filling process of sodium ion in the nanoporous is accompanied by the formation of solid electrolyte interface (SEI) film on the surface of the electrode. The results of electrochemical impedance spectroscopy show that the spectrum consists of two semicircles and a oblique line, which can be attributed to the contact impedance, the diffusion of sodium ions through SEI film and the process of charge transfer. The oblique domain reflects the oblique line related to the solid diffusion of sodium ion in the particles of hard carbon materials. By selecting the appropriate equivalent circuit and fitting the experimental results, we can get the variation of SEI film resistance and electron resistance with the electrode polarization potential in the process of sodium insertion in the first week of the hard carbon electrode.
- hard carbon,
- electrolyte system,
- sodium ion battery,
- electrochemical property
1. [1]
  Tarascon, J. M. Nat. Chem. 2010, 2, 510. doi: 10.1038/nchem.680
2. [2]
  Xiang, X. D.; Lu, Y. Y.; Chen, J. Acta Chim. Sinica 2017, 75, 154.
3. [3]
  Vikström, H.; Davidsson, S.; Höök, M. Appl. Energy 2013, 110, 252. doi: 10.1016/j.apenergy.2013.04.005
4. [4]
  Kundu, D.; Talaie, E.; Duffort, V.; Nazar, L. F. Angew. Chem., Int. Ed. 2015, 54, 3431. doi: 10.1002/anie.201410376
5. [5]
  Li, H.; Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593. doi: 10.1002/adma.v21:45
6. [6]
  Komaba, S.; Murata, W.; Ishikawa, T.; Yabuuchi, N.; Ozeki, T.; Nakayama, T.; Ogata, A.; Gotoh, K.; Fujiwara, K. Adv. Funct. Mater. 2011, 21, 3859. doi: 10.1002/adfm.v21.20
7. [7]
  Zhang, S. W.; Zhang, J.; Wu, S. D.; Lv, W.; Kang, F. Y.; Yang, Q. H. Acta Chim. Sinica 2017, 75, 163. doi: 10.11862/CJIC.2017.023
8. [8]
  Wang, L.; Yang, G. R.; Wang, J. N.; Wang, S. L.; Peng, S. J.; Yan, W. Acta Chim. Sinica 2018, 76, 666. doi: 10.3969/j.issn.0253-2409.2018.06.004
9. [9]
  Narayanrao, R.; Joglekar, M.; Inguva, S. J. Electrochem. Soc. 2013, 160, A125. doi: 10.1149/2.013302jes
10. [10]
  Lin, X.; Park, J.; Liu, L.; Lee, Y.; Sastry, A.; Lu, W. J. Electrochem. Soc. 2013, 160, A1701. doi: 10.1149/2.040310jes
11. [11]
  Pinson, M. B.; Bazant, M. Z. J. Electrochem. Soc. 2013, 160, A243. doi: 10.1149/2.044302jes
12. [12]
  Xu, K. Chem. Rev. 2014, 114, 11503. doi: 10.1021/cr500003w
13. [13]
  Zhuang, Q. C.; Xu, S. D.; Qiu, X. Y.; Cui, Y. L.; Fang, L.; Sun, S. G. Prog. Chem. 2010, 22, 1044.
14. [14]
  Qin, Y. P.; Zhuang, Q. C.; Shi, Y. L.; Jiang, L.; Sun, Z.; Sun, S. G. Prog. Chem. 2011, 23, 390.
15. [15]
  Qiu, X. Y.; Zhuang, Q. C.; Zhang, Q. Q.; Cao, R.; Ying, P. Z.; Qiang, Y. H.; Sun, S. G. Phys. Chem. Chem. Phys. 2012, 14, 2617. doi: 10.1039/c2cp23626e
16. [16]
  Zhuang, Q. C.; Wei, T.; Du, L. L.; Cui, Y. L.; Fang, L.; Sun, S. G. J. Phys. Chem. C 2010, 114, 8614. doi: 10.1021/jp9109157
17. [17]
  Qiu, X. Y.; Zhuang, Q. C.; Zhang, Q. Q.; Cao, R.; Qiang, Y. H.; Ying, P. Z.; Sun, S. G. J. Electroanal. Chem. 2012, 687, 35. doi: 10.1016/j.jelechem.2012.09.027
18. [18]
  Wei, T.; Zhuang, Q. C.; Wu, C.; Cui, Y. L.; Fang, L.; Sun, S. G. Acta Chim. Sinica 2010, 68, 1481. doi: 10.3866/PKU.WHXB20100621
19. [19]
  Zhuang, Q. C.; Wei, T.; Wei, G. Z.; Dong, Q. F.; Sun, S. G. Acta Chim. Sinica 2009, 67, 2184.
20. [20]
  Zheng, M.; Liu, Y.; Xiao, Y.; Zhu, Y.; Guan, Q.; Yuan, D.; Zhang, J. J. Phys. Chem. C 2009, 113, 8455. doi: 10.1021/jp811356a
21. [21]
  Cao, Y.; Xiao, L.; Sushko, M. L.; Wang, W.; Schwenzer, B.; Xiao, J.; Nie, Z.; Saraf, L. V.; Yang, Z.; Liu, J. Nano Lett. 2012, 12, 3783. doi: 10.1021/nl3016957
22. [22]
  Li, Y.; Hu, Y. S.; Titirici, M. M.; Chen, L.; Huang, X. Adv. Energy Mater. 2016, 6, 1600659. doi: 10.1002/aenm.201600659
23. [23]
  Liu, P.; Li, Y.; Hu, Y. S.; Li, H.; Chen, L.; Huang, X. J. Mater. Chem. A 2016, 4, 13046. doi: 10.1039/C6TA04877C
24. [24]
  Holzapfel, M.; Martinent, A.; Alloin, F.; Le Gorrec, B.; Yazami, R.; Montella, C. J. Electroanal. Chem. 2003, 546, 41. doi: 10.1016/S0022-0728(03)00144-X
25. [25]
  Chang, Y. C.; Sohn, H. J. J. Electrochem. Soc. 2000, 147, 50. doi: 10.1149/1.1393156
26. [26]
  Levi, M.; Aurbach, D. J. Phys. Chem. B 1997, 101, 4630. doi: 10.1021/jp9701909
27. [27]
  Xu, S. D.; Zhuang, Q. C.; Tian, L. L.; Qin, Y. P.; Fang, L.; Sun, S. G. J. Phys. Chem. C 2011, 115, 9210. doi: 10.1021/jp107406s
28. [28]
  Zhuang, Q. C.; Li, J.; Tian, L. L. J. Power Sources 2013, 222, 177. doi: 10.1016/j.jpowsour.2012.08.050
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
9. [9]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
10. [10]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
11. [11]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
12. [12]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
13. [13]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
14. [14]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
15. [15]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
16. [16]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
17. [17]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
18. [18]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
19. [19]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
20. [20]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093

Get Citation

PDF

XML

Metrics

PDF Downloads(51)
Abstract views(2097)
HTML views(501)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142